The thermal conditions of soil are important in practical agricultural production. The characteristics of heat flux, moisture content, thermal conductivity, and other soil parameters vary with temperature. This study uses VADOSE/W to create a model of heat transmission between soil and atmosphere, simulating daily changes in soil temperature using sand mulching. By using the published data to verify the model, the results show that the fitting effect is good and the reliability of the model is verified. We also used this model to determine the temporal and spatial distributions of soil temperature, temperature differences, and a temperature gradient for sand mulching and bare soil during the growing season of spring wheat. These results indicated that the sand mulching preserved heat at night. The difference in temperature at each depth and the temperature gradient became negative with the gradual increase in solar altitude. The difference in soil temperature at each depth and the temperature gradient tended to become positive by 22:00. These results indicated that the sand mulch effectively maintained the soil temperature in the morning and night during the growing season and impeded the transfer of heat at mid-day. This study provides a new method for determining the transfer of heat in sand-mulched soil, which can guide the effective regulation of soil temperature.

Considerable uncertainty exists with regard to the effects of thinning and harvesting on N₂O emissions as a result of changes caused in the belowground environment by tree cutting. To evaluate on the effects of changes in the belowground environment on N₂O emissions from soils, we conducted a tree manipulation experiment in a Japanese cedar (Cryptomeria japonica) stand without soil compaction or slash falling near measurement chambers and measured N₂O emission at distances of 50 and 150 cm from the tree stem (stump) before and after cutting. In addition, we inferred the effects of logging on the emission using a hierarchical Bayesian (HB) model. Our results showed that tree cutting stimulated N₂O emission from soil and that the increase in N₂O emission depended on the distance from the stem (stump); increase in N₂O emission was greater at 50 than at 150 cm from the stem. Tree cutting caused the estimated N₂O emission at 0–40 cm from the stem to double (the % increase in N₂O emission by tree cutting was 54%–213%, 95% predictive credible interval) when soil temperature was 25 °C and WFPS was 60%. Posterior simulation of the HB model predicted that 30% logging would cause a 57% (47%–67%) increase in N₂O emission at our study site (2000 trees ha⁻¹) considering only the effects of belowground changes by tree cutting during the measurement period.

Urban turfgrass ecosystems are expected to increase at unprecedented rates in upcoming decades, due to the increasing population density and urban sprawl worldwide. However, so far urban turfgrasses are among the least understood of all terrestrial ecosystems concerning their impact on biogeochemical N cycling and associated nitrous oxide (N₂O) and nitric oxide (NO) fluxes. In this study, we aimed to characterize and quantify annual N₂O and NO fluxes from urban turfgrasses dominated by either C4, warm-season species or C3, cool-season and shade-enduring species, based on year-round field measurements in Beijing, China. Our results showed that soil N₂O and NO fluxes varied substantially within the studied year, characterizing by higher emissions during the growing season and lower fluxes during the non-growing season. The regression model fitted by soil temperature and soil water content explained approximately 50%–70% and 31%–38% of the variance in N₂O and NO fluxes, respectively. Annual cumulative emissions for all urban turfgrasses ranged from 0.75 to 1.27 kg N ha⁻¹ yr⁻¹ for N₂O and from 0.30 to 0.46 kg N ha⁻¹ yr⁻¹ for NO, both are generally higher than those of Chinese natural grasslands. Non-growing season fluxes contributed 17%–37% and 23%–30% to the annual budgets of N₂O and NO, respectively. Our results also showed that compared to the cool-season turfgrass, annual N₂O and NO emissions were greatly reduced by the warm-season turfgrass, with the high root system limiting the availability of inorganic N substrates to soil microbial processes of nitrification and denitrification. This study indicates the importance of enhanced N retention of urban turfgrasses through the management of effective species for alleviating the potential environmental impacts of these rapidly expanding ecosystems.

Mining activities have contaminated many riverine floodplains with arsenic (As). When floodplain soils become anoxic under water-saturated conditions, As can be released from the solid phase. Several microbially-driven As solubilization processes and numerous influential factors were recognized in the past. However, the interplay and relative importance of soil properties and the influence of environmental factors such as temperature remain poorly understood, especially considering the (co)variation of soil properties in a floodplain. We conducted anoxic microcosm experiments at 10, 17.5, and 25 °C using 65 representative soils from the mining-impacted Ogosta River floodplain in Bulgaria. To investigate the processes of As solubilization and its quantitative variation we followed the As and Fe redox dynamics in the solid and the dissolved phase and monitored a range of other solution parameters including pH, Eh, dissolved organic C, and dissolved Mn. We related soil properties to dissolved As observed after 20 days of microcosm incubation to identify key soil properties for As solubilization. Our results evidenced reductive dissolution of As-bearing Fe(III)-oxyhydroxides as the main cause for high solubilization. The availability of nutrients, most likely organic C as the source of energy for microorganisms, was found to limit this process. Following the vertical nutrient gradient common in vegetated soil, we observed several hundred μM dissolved As after 1–2 weeks for some topsoils (0–20 cm), while for subsoils (20–40 cm) with comparable total As levels only minor solubilization was observed. While high Mn contents were found to inhibit As solubilization, the opposite applied for higher temperature (Q10 2.3–6.1 for range 10–25 °C). Our results suggest that flooding of nutrient-rich surface layers might be more problematic than water-saturation of nutrient-poor subsoil layers, especially in summer floodings when soil temperature is higher than in winter or spring.

The effects of experimentally elevated O3 on soil respiration rates, standing fine-root biomass, fine-root production and δ13C signature of newly produced fine roots were investigated in an adult European beech/Norway spruce forest in Germany during two subsequent years with contrasting rainfall patterns. During humid 2002, soil respiration rate was enhanced under elevated O3 under beech and spruce, and was related to O3-stimulated fine-root production only in beech. During dry 2003, the stimulating effect of O3 on soil respiration rate vanished under spruce, which was correlated with decreased fine-root production in spruce under drought, irrespective of the O3 regime. δ13C signature of newly formed fine-roots was consistent with the differing gs of beech and spruce, and indicated stomatal limitation by O3 in beech and by drought in spruce. Our study showed that drought can override the stimulating O3 effects on fine-root dynamics and soil respiration in mature beech and spruce forests. Drought has the capacity to override the stimulating ozone effect on soil respiration in adult European beech/Norway spruce forest.

Mercury (Hg) emissions from the soils taken from two different sites (deciduous and coniferous forests) in the Adirondacks were measured in outdoor and laboratory experiments. Some of the soil samples were irradiated to eliminate biological activity. The result from the outdoor measurements with different soils suggests the Hg emission from the soils is partly limited by fallen leaves covering the soils which helps maintain relatively high soil moisture and limits the amount of heat and solar radiation reaching the soil surface. In laboratory experiments exposure to UV-A (365 nm) had no significant effect on the Hg emissions while the Hg emissions increased dramatically during exposure to UV-B (302 nm) light suggesting UV-B directly reduced soil-associated Hg. Overall these results indicate that for these soils biotic processes have a relatively constant and smaller influence on the Hg emission from the soil than the more variable abiotic processes. Hg emission measurements from soils indicate that abiotic processes were more important than biotic processes in reducing Hg and controlling emissions.

This study estimates the effect of environmental parameters on the mobility of four inorganic contaminants (As, Zn, Pb and Cd) in soils from three areas in the Ebro and Meuse River basins, within the context of global change. An experimental method, applicable to various soil systems, is used to measure the effect of four global-change-sensitive parameters (temperature, gas phase composition, pH and microbial activity). The aqueous phase of batch incubations was sampled regularly to monitor toxic element concentrations in water. Statistical processing enabled discrimination of the most relevant variations in dissolved concentrations measured at different incubation times and under different experimental conditions. Gas phase composition was identified as the most sensitive parameter for toxic element solubilization. This study confirms that total soil concentrations of inorganic pollutants are irrelevant when assessing the hazard for ecosystems or water resource quality. An experimental method applicable for different soil systems enables the determination of the effect of environmental parameters, potentially affected by global change, on the mobilization of inorganic pollutants.

Urbanization alters land use, increasing the rate of greenhouse gas (GHG) emissions and hence atmospheric compositions. Nitrous oxide (N₂O) is a major GHG that contributes substantially to global warming. N₂O emissions are sensitive to changes in substrate availabilities, such as litter and N input, as well as micro-environmental factors caused by land-use change upon urbanization. However, the potential impacts of changing litter and N on soil N₂O emissions along urban-rural gradients is not well understood. Here, we conducted an in situ study over 19 months in Cinnamomum camphora plantations along an urban-rural gradient, to examine the effects of the urban-rural gradient, N and litter input on N₂O emissions from C. camphora plantation soils and the underlying mechanisms via N, litter and microbial communities. The results showed that urban soil N₂O emissions were 105% and 196% higher than those from suburban and rural soil, respectively, and co-occurred with a higher abundance of AOA, nirS and nirK genes. Litter removal increased cumulative N₂O emissions by 59.7%, 50.9% and 43.3% from urban, suburban and rural soils, respectively. Compared with litter kept treatment, increases in AOA and nirK abundance were observed in urban soil, and higher rural nirS abundance occurred following litter removal. Additionally, the relatively higher soil temperature and available N content in the urban soil increased N₂O emissions compared with the suburban and rural soil. Therefore, in addition to changes in microbial communities and abiotic environmental factors, litter kept in C. camphora plantations along an urban-rural gradient is also important in mitigating N₂O emissions, providing a potential strategy for the mitigation of N₂O emissions.

Soils have been widely acknowledged as important natural sources of nitric oxide (NO) and meanwhile sinks of nitric dioxide (NO₂). High nitrogen deposition across South China could potentially result in large NO emissions from subtropical forests soils there. In this study, the dynamic chamber method was applied to monitor NO and NO₂ fluxes at two subtropical forest sites in South China, namely “Qianyanzhou” (QYZ) and “Tieshanping” (TSP). Chronically higher N deposition occurred at TSP than that at QYZ. Besides soil water filled pore spaces (WFPS) and temperature, ambient NO concentration could also possibly be important in regulating temporal NO emissions, especially in the winter. For both sites, the optimum soil temperature was above 25 °C, while the optimum WFPS for NO release at QYZ was higher (65–70%) than that at TSP (<23%). Moreover, heavy rainfall could trigger NO emission pulses from moist soils at QYZ, while rainfall-induced NO pulses were only observed after a long drying period at TSP. Distinctly different contents of mineral nitrogen and soil moisture conditions between the two sites might induce the divergent preference of WFPS and responses to rainfall. The cumulative soil emission of NO reached 0.41 ± 0.01 and 0.76 ± 0.01 kg N ha⁻¹ yr⁻¹ at QYZ and TSP, contributing to 2.5% and 1.4% of the annual throughfall N input, respectively. At both sites, NO₂ were mainly deposited to soils, accounting for 2% and 21% of soil-emitted NO at QYZ and TSP, respectively. The observed annual NO emissions at these two sites were larger than the median values observed for tropical and temperate forests and unfertilized croplands. Higher N deposition could induce larger NO emission potential, while soil temperature and pH might also be important in regulating regional soil NO emissions as N-loss from subtropical forests.

Agricultural tillage practices have a significant impact on the generation and consumption of greenhouse gases (GHGs), the primary causes of global warming. Two tillage systems, conventional tillage (CT) and no-tillage (NT), were compared to evaluate their effects on GHG emissions in this study. Averaged from 2018 to 2020, significant decreases of CO₂ and N₂O emissions by 7.4% and 51.1% were observed in NT as compared to those of CT. NT was also found to inhibit the soil CH₄ uptake. In this study, soil was a source of CO₂ and N₂O but a sink for CH₄. The effect of soil temperature on the fluxes of CO₂ was more pronounced than that of soil moisture. However, soil temperature and soil moisture had a weak correlation with CH₄ and N₂O flux variations. As compared to CT, NT did not affect maize yields but significantly reduced global warming potential (GWP) by 8.07%. For yield-scaled GWP, no significant difference was observed in NT (9.63) and CT (10.71). Taken together, NT was an environment-friendly tillage practice to mitigate GHG emissions in the soil under the tested conditions.