خيارات البحث
النتائج 1 - 10 من 11
Pruning residues and sewage sludge co-composting
1993
Arbiol, M. | Benito, P. | Soliva, M. | Villalba, D. | Molina, N. (JARFELS SA, Castelldefels (Spain))
Economic and Environmental Benefits of Using Hardwood Sawmill Waste as a Raw Material for Particleboard Production
2009
Setunge, Sujeeva | Wong, Kee Kong | Jollands, Margaret
Annually, sawmills and other wood-processing factories generate a significant amount of scrap materials which are sent to landfills or incinerated. The amount of residue generated in Australia annually is estimated at 200,000 tonnes. A research project conducted at RMIT University explored utilizing these waste materials as particleboard furnish. The research team has now established a methodology for making particleboard in the laboratory using 100% hardwood sawmill residues, developing a particleboard product made in the laboratory which has acceptable mechanical properties and density profiles in accordance with the Australian Standards. However, this board product has some perceived issues which have been hindering ready commercial uptake. The current product requires a 10% higher resin load, has a 10% higher board density, and requires 10% longer pressing times compared to normal softwood particleboard. The paper presents an analysis of the current production process of particleboard to investigate the economic feasibility of particleboard production using hardwood sawmill residues. A major challenge in the analysis is converting the environmental benefit of utilizing large quantities of sawmill residue to a monetary term. Investigation of the global impact of particleboard by considering emission of carbon dioxide to the atmosphere is also included. A comparison is presented between different methods of disposing wood residues to understand the environmental benefit of using hardwood residue in particleboard.
اظهر المزيد [+] اقل [-]Performance of Physically and Chemically Activated Biochars in Copper Removal from Contaminated Mine Effluents
2019
The increasing global demand for metals and minerals justifies the intensive study of treatment options for contaminated mine effluents. The present study evaluated the conversion of wood residues into physically and chemically activated biochars and their subsequent use in the treatment of Cu in synthetic and actual contaminated mine drainage. First, wood residues were converted into biochar by fast pyrolysis. Then, physical (using steam or CO₂) or chemical (using KOH) activation was carried out in a homemade pilot-scale furnace. After activation, highly microporous (KOH materials) and micro/mesoporous activated biochars (CO₂ and steam materials) were obtained. Batch adsorption testing was first conducted with synthetic effluents. Results showed that CO₂-activated biochar was the most Cu effective adsorbent (99% removal) at low concentrations (5–20 mg L⁻¹). The mechanisms of Cu²⁺ adsorption involved physical and chemisorption for biochars and CO₂-activated biochar, while chemisorption for KOH-activated biochars was probably due to the high proportion of functional groups connected to their surface. In multi-metal acid mine drainage, metal adsorption capacities deteriorated for most of the materials, probably due to the effects of ion competition. However, KOH-activated biochar decreased Cu²⁺ concentrations to below the authorized monthly mean allowed by Canadian law (0.3 mg L⁻¹) and decreased Co, Pb, and Mn concentrations up to 95%. These findings indicate that high porosity and oxygenated functional groups connected to the surface of activated biochars are important properties for the enhancement of interactions between carbon materials and metals from mine effluents, as well as for their performance improvement in mine drainage treatment.
اظهر المزيد [+] اقل [-]Possibilities for the combustion of biomass in pulverized fuel units
1993
Kicherer, A. (Stuttgart Univ. (Germany). Inst. fuer Verfahrenstechnik und Dampfkesselwesen) | Hein, K.R.G.
Pollutant emissions of commercial and industrial wood furnaces. Determination of emissions reducing techniques
1993
Baumbach, G. (Stuttgart Univ. (Germany). Inst. fuer Verfahrenstechnik und Dampfkesselwesen) | Angerer, M.
Mineralogical, chemical and leaching characteristics of ashes from residential biomass combustion
2019
Alves, Célia A. | Font, Oriol | Moreno, Natalia | Vicente, Estela D. | Duarte, Márcio | Tarelho, Luís A.C. | Querol, X. (Xavier)
Four types of pellets and three agro-fuels were chemically characterised and burned in a pellet stove. To assess the influence of the material composing the firebox and the combustion efficiency of distinct biomass heating devices in the composition of the bottom ashes, three of the pellets were also burned in a conventional woodstove and in a fireplace. Ashes were analysed for their C, H and N contents by an elemental analyser, whilst major and trace elements were quantified by inductively coupled plasma atomic-emission spectrometry and inductively coupled plasma mass spectrometry, respectively. The mineralogy of ashes was determined by X-ray powder diffraction. The European standard test was applied to samples to determine the leaching potential of major, minor and trace elements. The contents of major and trace elements in the different types of biomass presented enormous variations, which are reflected in dissimilar mineralogical and chemical compositions of the respective ashes. The leachable potential of several elements of environmental concern present in oxy-anionic form at the alkaline pH of biomass ashes were generally high in all samples. Concentrations of some elements in the leachates were in the range of values with classification of “hazardous materials” by the European legislation in what respects the acceptance of these wastes at landfills. Pellets made up of wood wastes and containing preservatives (chromated copper arsenate and ammoniacal copper arsenate) are of concern. Due to lower combustion efficiencies, the leachable potential for most of the trace elements in ashes from the woodstove, and especially from the fireplace, was lower than that of the pellet stove.
اظهر المزيد [+] اقل [-]Carbon footprint associated with four disposal scenarios for urban pruning waste
2018
Araújo, YuriRommel Vieira | de Góis, MonijanyLins | Junior, LuizMoreira Coelho | Carvalho, Mônica
The inadequate disposal of urban pruning residues can cause significant environmental impacts. The objective of the study presented herein was to quantify the carbon footprint and analyze four disposal scenarios for the urban pruning waste of the city of Joao Pessoa (Northeast Brazil). Software SimaPro was utilized for the quantification of the carbon footprint, with the IPCC 2013 GWP 100y impact evaluation method. The end-of-life treatments considered were sanitary landfilling (with and without collection of methane), simple municipal incineration, and reutilization of wood (transformation into briquettes). The results indicated that simple disposal in sanitary landfill generated 136.34 kg CO₂/t urban pruning waste collected (highest carbon footprint), sanitary landfill with methane collection emitted 113.43 kg CO₂/t waste, municipal incineration generated 71.31 kg CO₂/t waste, and reutilization of woody residues was the scenario with the lowest carbon footprint, with 27.82 kg CO₂/t waste. This study demonstrated that reutilization of biomass, besides being environmentally viable, presents the potential to contribute to the city’s environmental quality, including the possibility of being used to obtain carbon credits.
اظهر المزيد [+] اقل [-]Removal of azo dye from water via adsorption on biochar produced by the gasification of wood wastes
2019
Kelm, Miguel Antônio Pires | da Silva Júnior, Mário José | de Barros Holanda, Sávio Henrique | de Araujo, Caroline Maria Bezerra | de Assis Filho, Romero Barbosa | Freitas, Emerson Jaguaribe | dos Santos, Diogo Rafael | da Motta Sobrinho, Maurício Alves
It was the aim of this work to evaluate the adsorptive performance of the biochar obtained from the gasification of wood residues onto a solution of Indosol Black NF1200 dye. The study was performed by means of factorial design 2², having as control variables: pH and adsorbent’s granulometry. Batch tests were carried out at 200 rpm for 3 h (T = 28 °C). As output variable, the percentage removal of dye was determined. The best operating conditions were pH = 2 and 100 mesh granulometry. Also, adsorbent dosage studies were carried out, as well as equilibrium and adsorption kinetics. Both kinetics and equilibrium of adsorption tests were proceeded in basic and acid medium. For a basic pH value (pH = 12), it was concluded the equilibrium was reached in about 3 h of experiment, the experimental qₘₐₓ value was near 12 mg g⁻¹, and the equilibrium data fitted the Langmuir model. On the other hand, for tests with pH = 2, the equilibrium was reached after 5 min of experiment, the experimental qₘₐₓ value was over 185 mg g⁻¹, and the equilibrium data fitted both the Langmuir and Freundlich models. Thus, the biochar produced via gasification of wood wastes appears to be a promising adsorbent for the removal of azo dyes from textile wastewater, especially when working at lower pH values. Also, for a 10-kg/h consumption of wood residue, approximately 10 kW of energy is generated and 1 kg of biochar is produced, which represents another advantage from the environmentally friendly point of view. Graphical abstract
اظهر المزيد [+] اقل [-]Production, characterization, and potential of activated biochar as adsorbent for phenolic compounds from leachates in a lumber industry site
2018
Braghiroli, Flavia Lega | Bouafif, Hassine | Hamza, Nesrine | Neculita, Carmen Mihaela | Koubaa, Ahmed
There is growing interest in low-cost, efficient materials for the removal of organic contaminants in municipal and industrial effluents. In this study, the efficiency of biochar and activated biochar, as promising adsorbents for phenol removal, was investigated at high (up to 1500 mg L⁻¹) and low concentrations (0.54 mg L⁻¹) in synthetic and real effluents (from wood-residue deposits in Québec), respectively. The performance of both materials was then evaluated in batch adsorption experiments, which were conducted using a low solid/liquid ratio (0.1 g:100 mL) at different phenol concentrations (C₀ = 5–1500 mg L⁻¹), and at 20 °C. Activated biochars presented higher phenol adsorption capacity compared to biochars due to their improved textural properties, higher micropore volume, and proportion of oxygenated carbonyl groups connected to their surface. The sorption equilibrium was reached within less than 4 h for all of materials, while the Langmuir model best described their sorption process. The maximum sorption capacity of activated biochars for phenol was found to be twofold relative to biochars (303 vs. 159 mg g⁻¹). Results also showed that activated biochars were more effective than biochars in removing low phenol concentrations in real effluents. In addition, 95% of phenol removal was attained within 96 h (although 85% was removed after 4 h), thus reaching below the maximum authorized concentration allowed by Québec’s discharge criteria (0.05 mg L⁻¹). These results show that activated biochars made from wood residues are promising potential adsorbent materials for the efficient treatment of phenol in synthetic and real effluents.
اظهر المزيد [+] اقل [-]Conditioning sulfidic mine waste for growth of Agrostis capillaris—impact on solution chemistry
2014
Sjöberg, Viktor | Karlsson, Stefan | Grandin, Anna | Allard, Bert
Contamination of the environment due to mining and mineral processing is an urgent problem worldwide. It is often desirable to establish a grass cover on old mine waste since it significantly decreases the production of leachates. To obtain sustainable growth, it is often necessary to improve several properties of the waste such as water-holding capacity, nutrient status, and toxicity. This can be done by addition of organic materials such as wood residues, e.g., compost. In this study, we focus on the solution chemistry of the leachates when a substrate containing historic sulfidic mine waste mixed with 30 % (volume) bark compost is overgrown by Agrostis capillaris. The pot experiments also included other growth-promoting additives (alkaline material, mycorrhiza, and metabolizable carbon) to examine whether a more sustainable growth could be obtained. Significant changes in the plant growth and in the leachates composition were observed during 8 weeks of growth. It was concluded that in this time span, the growth of A. capillaris did not affect the composition of the leachates from the pots. Instead, the composition of the leachates was determined by interactions between the bark compost and the mine waste. Best growth of A. capillaris was obtained when alkaline material and mycorrhiza or metabolizable carbon was added to the substrate.
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