Environmental magnetic and geochemical analyses combined with 210Pb dating were carried out on a sediment core off Goa from Arabian Sea to reconstruct the sedimentation history of last three and a half centuries and to investigate the impact of onshore iron ore mining on the offshore sedimentation. A drastic increase in sedimentation rate and mineral magnetic concentration parameters divides the core into two units (1 & 2) at a depth of 41cm (1982CE). The high magnetic susceptibility values in Unit 1 sediments are coeval with increased iron ore production on land and illustrate the role of terrestrial mining on the increased offshore sedimentation. The early diagenetic signals were observed in Unit 2 of the core with low concentration parameters, coarse magnetic grain size and magnetically hard mineralogy. The geochemical data of the core also record the Little Ice Age (LIA) climatic events of Dalton and Maunder solar minima.

The effects of increasing CO2 concentrations and temperature on microalgal assemblages were examined in Taiwan using mesocosms that simulate coral reef ecosystem. We assessed changes in abundance and diversity of benthic algae grown at 25°C and 28°C, under ambient (~400μatm) and at high CO2 conditions (800–1000μatm). Total alkalinity, pCO2, and the aragonite saturation state, were all significantly different between control and high CO2 treatments in both temperature treatments. Chl a concentration increased significantly in CO2-treated groups at 25°C, but benthic microalgal abundance was not significantly different. The number of microalgal species and the microalgal community structure did not differ between control and CO2-treated groups at both temperatures. Our results suggest that increasing CO2 may boost benthic microalgal primary productivity if sufficient nutrients are available, although site-specific responses are difficult to predict.

Plastic debris is ubiquitous in the marine environment and the world's shores represent a major sink. However, knowledge about plastic abundance in remote areas is scarce. Therefore, plastic abundance was investigated on a small island of the Maldives. Plastic debris (>1mm) was sampled once in natural long-term accumulation zones at the north shore and at the high tide drift line of the south shore on seven consecutive days to quantify daily plastic accumulation. Reliable identification of plastic debris was ensured by FTIR spectroscopy. Despite the remoteness of the island a considerable amount of plastic debris was present. At both sites a high variability in plastic abundance on a spatial and temporal scale was observed, which may be best explained by environmental factors. In addition, our results show that snapshot sampling may deliver biased results and indicate that future monitoring programs should consider spatial and temporal variation of plastic deposition.

In this study the online meteorological and chemical transport model “Weather Research and Forecasting coupled with Chemistry” (WRF/Chem) is implemented over Cyprus and evaluated against ground-based air quality and meteorological observations. Hourly O3 concentrations are strongly overestimated and a reduction in the lateral boundaries of ozone by 30% improved model agreement with observations. Utilization of grid spacing closer to the resolution of the emission data leads to an improvement in the simulation of air pollutants, while further reduction of the grid spacing mostly impacts the model performance related to meteorological parameters. The method of speciation of volatile organic compounds can also affect model results. Reduction of NOx emissions can reduce fine particulate (PM2.5) levels relatively effectively due to the important role of nitrate over Cyprus. The present case study indicates that the performance of the WRF/Chem model is reasonable for air quality and meteorological variables over Cyprus when boundary conditions are cautiously adjusted or improved, while there is a need to pursue a high-resolution local emission inventory.

The distribution and sources of PAHs and n-alkanes were determined in the surface sediments from 202 locations in Shadegan international wetland with 537,700ha. The concentrations of total n-alkanes and PAHs ranged from 395.3 to 14933.46μgg−1dw and 593.74 to 53393.86ngg−1dw, respectively. Compared with other worldwide surveys, the concentration and contamination of sedimentary hydrocarbons were classified very high. A common petrogenic hydrocarbon source was strongly suggested in all sites by n-alkanes' profile with a Cmax at n-C20, Pr/Ph and CPI ratios<1 in all sites, and high percentage of UCM. Typical profile of petrogenic PAHs with alkyl-substituted naphthalenes and phenanthrenes predominance, various PAH ratios and multivariate analysis indicated that PAHs were mainly derived from petrogenic source. Naphthalene-derived compounds in all sites were significantly above their ERL, and adversely affected benthic biota. 92% of the sites had mean ERM values<0.1, indicating high ecological risk on the wildlife of the wetland.

Dinoflagellate cysts (dinocysts), biogenic elements and metals were analyzed from sediment cores collected from Zhelin Bay of the South China Sea in December 2008 to understand the environmental changes over the past 50years. Dinocyst concentrations ranged from 0cysts/g to 770cysts/g, and they were dominated by heterotrophic taxa. There was a clear increase trend upcore for biogenic elements, except for biogenic silica. Metals originated from both the lithogenic source and human activities, and significantly increased after 1985–1995. Environmental changes in the past 50years can be divided into three stages: (1) before 1985, during which biogenic elements, cyst flux and metals were low; (2) from 1985 to the early 2000s, characterized by an obvious increase of dinocysts, TOC, TN and most metals, while TOC/TN and BSi decreased; and (3) after 2000, the period of rapid increase of dinocysts, TOC and TN but decrease of certain contamination metals.

New particle formation (NPF) has been expected to be less favored in the polluted atmosphere than in the clean atmosphere. However, highly polluted regions in developing countries like China and India are becoming hot spots of NPF. Understanding nucleation and growth mechanisms of aerosol particles in polluted environments have important implications in their global climate impact and health effect. This paper reviewed recent publications from atmospheric field and laboratory measurements under conditions relevant to the polluted atmosphere. NPF probability in polluted environments was discussed by exploring the uncertainties in coagulation sink and growth rate estimations. Future directions and challenges in understanding NPF in highly polluted environments are presented.

This paper presents a novel operational oil spill modelling system based on HF radar currents, implemented in a northwest European shelf sea. The system integrates Open Modal Analysis (OMA), Short Term Prediction algorithms (STPS) and an oil spill model to simulate oil spill trajectories. A set of 18 buoys was used to assess the accuracy of the system for trajectory forecast and to evaluate the benefits of HF radar data compared to the use of currents from a hydrodynamic model (HDM). The results showed that simulated trajectories using OMA currents were more accurate than those obtained using a HDM. After 48h the mean error was reduced by 40%. The forecast skill of the STPS method was valid up to 6h ahead. The analysis performed shows the benefits of HF radar data for operational oil spill modelling, which could be easily implemented in other regions with HF radar coverage.

Coastal ecosystems are receiving elevated loads of nitrogen (N) from anthropogenic sources. Understanding how excessive N loading affects bacterioplankton communities is critical to predict the biodiversity of marine ecosystems under conditions of eutrophic disturbance. In this study, oligotrophic coastal water microcosms were perturbed with nitrate in two loading modes: 1) one-off loading at the beginning of the incubation period; and 2) periodic loading every two days for 16days. Turnover in the bacterioplankton community was investigated by 16S rDNA gene amplicon sequencing. The alpha diversity of the bacterioplankton community showed great temporal variability and similar responses to the different treatments. Bacterioplankton community composition was influenced remarkably by time and N loading mode. The effects of N loading on bacterioplankton community structure showed obvious temporal variation, probably because of the great temporal variation in environmental parameters. This study provides insights into the effects of N pollution in anthropogenically perturbed marine environments.

Marine coastal ecosystems are affected by a vast array of human-induced disturbances and stresses, which are often capable of overwhelming the effects of natural changes. Despite the conceptual and practical difficulty in differentiating between disturbance and stress, which are often used interchangeably, the two terms bear different ecological meanings. Both are external agents, but the former causes mortality or physical damage (subtraction of biomass), whereas the latter causes physiological alteration (reduction in productivity). Sensitivity of marine organisms may thus have a dual connotation, being influenced in different ways by disturbance and by stress following major environmental change. Coralligenous assemblages, which shape unique biogenic formations in the Mediterranean Sea, are considered highly sensitive to change. In this paper, we propose a method to differentiate between disturbance and stress to assess the ecological status of the coralligenous assemblages. Disturbance sensitivity level (DSL) and stress sensitivity level (SSL) of the sessile organisms thriving in the coralligenous assemblages were combined into the integrated sensitivity level of coralligenous assemblages (ISLA) index. Changes in the coralligenous status were assessed in space, along a gradient of stress (human-induced pressures) at several sites of the western Mediterranean, and in time, from a long-term series (1961–2008) at Mesco Reef (Ligurian Sea) that encompasses a mass mortality event in the 1990s. The quality of the coralligenous assemblages was lower in highly urbanised sites than that in sites in both marine protected areas and areas with low levels of urbanisation; moreover, the quality of the assemblages at Mesco Reef decreased during the last 50years. Reduction in quality was mainly due to the increase in stress-tolerant and/or opportunist species (e.g. algal turfs, hydroids and encrusting sponges), the disappearance of the most sensitive macroalgae (e.g. Udoteaceae and erect Rhodophyta) and macro-invertebrates (e.g. Savalia savaglia, Alcyonium coralloides and Smittina cervicornis), and the appearance of invasive alien algal species. Although the specific indices of SSL or DSL well illustrated the changes in the spatial or temporal datasets, respectively, their integration in the ISLA index was more effective in measuring the change experienced by the coralligenous assemblages in both space and time.