The Ixtoc-I oil spill occurred in 1979 in shallow waters (50m) of the Bay of Campeche, Mexico. Although it is known that a large portion of the released oil from this second largest accidental marine oil spill in history reached the surface, to date there has been no attempt to document the surface footprint and trajectory of the released oil. Our study attempts to fill this knowledge gap using remote sensing data collected by Landsat/MSS and CZCS. Both showed the same general patterns of oil trajectory to the northwest and north, nearly parallel to the coastline of the western Gulf of Mexico (GoM) with possible oil landing on Mexican and Texas beaches. Field observations at selected beaches and islands along the coast of the western and southern GoM during and after the spill confirmed these satellite-based findings, which were also used to help in planning a recent field campaign to collect sediment samples in the southern GoM.

Posidonia oceanica is a marine angiosperm endemic from the Mediterranean. Despite their protection, its meadows are regressing. The economic valuation of ecosystem services (ES) assesses the contribution of ecosystems to human well-being and may provide local policy makers help in territorial development. To estimate the economic value of P. oceanica seagrass and the meadows that it forms to better account its presence in coastal development, identification and assessment of ES provided are first performed. Then goods and benefits (GB) and their economical values are estimated. In total, 25ES are identified and 7GB are economically evaluated. The economic value of GB provided by P. oceanica ranges between 25.3 million and 45.9 million€/year which means 283–513€/ha/year. Because of the lack of existing available data, only 7GB linked to 11/25ES have been estimated. Despite this overall undervaluation, this study offers a value for coastal development policies to take into account.

The distribution of different forms of phosphorus in surface sediment from 17 sites were investigated by SEDEX method. The sites were divided into three sectors: Santos Channel (SC – influenced by harbour, fertilizers plants and phosphogypsum mountains), São Vicente Channel (SVC– domestic waste) and Santos Bay (SB – sewage outfall). The average percentage of each P fraction of the surface sediments in this region followed the sequence P–Fe (38%)>Porg (27%)>Pexch (13%)>Detrital – P (12%)>Auth – P (10%). Ptotal varied from 3.57 to 74.11μmolg−1 in both seasons. In SVC, Pexch ranged from 13% to 27% and Porg varied from 12% to 56%. These high percentages of Pexch/Ptotal (greater than 20%) may be related to low oxygen resulting from oxygen consumed by intensive organic matter decomposition as well as the salty water that leads to cation and anion flocculation. Also, the possibility of an influence related to the industrial source of Pexch is not ruled out. No significant seasonal differences were found among sites, except for sewage outfall, with changing in the grain size and hence, the P geochemistry. During the summer in the sewage outfall station, Porg represented 37% of Ptotal, which decreased to 13% in the winter. These results suggest that high percentages of organic phosphorus cannot be attributed only to autochthonous and allochthonous organic matter, but also to detergents and/or domestic waste. In contrast, spatial differences among sectors were observed, with the highest values of each fraction associated with sites near industrial and domestic waste activities.

Air barriers have been recently developed and employed as a new type of oil containment boom. This paper presents systematic investigations on the reliability of air barriers on oil containments with the involvement of flowing water, which represents the commonly-seen shearing current in reality, by using both laboratory experiments and numerical simulations. Both the numerical and experimental investigations are carried out in a model scale. In the investigations, a submerged pipe with apertures is installed near the bottom of a tank to generate the air bubbles forming the air curtain; and, the shearing water flow is introduced by a narrow inlet near the mean free surface. The effects of the aperture configurations (including the size and the spacing of the aperture) and the location of the pipe on the effectiveness of the air barrier on preventing oil spreading are discussed in details with consideration of different air discharges and velocities of the flowing water. The research outcome provides a foundation for evaluating and/or improve the reliability of a air barrier on preventing spilled oil from further spreading.

Distributions of trace metals (TM), organic carbon, SPM and physico-chemical parameters were studied in the highly stratified Krka River estuary in winter/summer periods. The non-conservative behaviour of Zn, Cd, Pb and Cu in the brackish layer (plume), easily spotted due to very low inputs by the river, was mainly caused by their inputs from the pleasure boats, nautical marinas and harbour (e.g. release from antifouling paints). Contrarily, Ni and Co followed near-conservative behaviour. The extremely low SPM discharged by the river, resulted in a predominant dissolved fraction (>80%) of all TM, except Pb. Vertical scavenging, coupled with the long residence time, caused accumulation and progressive upstream increase of TM and SPM in the bottom seawater. Decrease of distribution coefficient (KD) in the brackish layer for winter period was ascribed to the change of SPM nature (terrestrial vs. biogenic), whereas a variable and increased biogenic component of SPM caused scattered KDs in summer.

The integrated microwave with Mn/zeolite and ozone (MCO) and combined microwave with Mn/zeolite (MC) was employed to oxidize elemental mercury (Hg0) in simulated flue gas. The results show that mercury removal efficiency attained 35.3% in the MC, over 92% of Hg0 removal efficiency could be obtained in the MCO. The optimal microwave power and empty bed residence time (EBRT) in the microwave plasma catalytic oxidation were 264 W and 0.41 s, respectively. The effect of Hg0 oxidation in the MCO was much higher than that in the MC. Microwave accentuated catalytic oxidation of mercury, and increased mercury removal efficiency. The additional use of ozone to the microwave–catalysis over Mn/zeolite led to the enhancement of mercury oxidation. Mn/zeolite catalyst was characterized by X–ray diffraction (XRD), X–ray photoelectron spectroscopy (XPS), Fourier transform infrared spectra (FT–IR), scanning electron microscopy (SEM) and the Brunauer Emmett Teller (BET) method. Microwave catalytic mercury over Mn/zeolite was dominated by a free radical oxidation route. Ozone molecules in air could enhance free radical formation. The coupling role between ozone and radicals on mercury oxidation in the MCO was formed. The MCO appears to be a promising method for emission control of elemental mercury.

Dust storms, as extreme environmental events, are one of the Earth’s major natural hazards. Their impact on socio-economics can range from local urban to (trans-) continental and from minutes to decades, such as the dust bowl of the 1930s in the United States. Research on dust storms can be traced back for several decades as a meteorological extension. Latest technology developments have enabled comprehensive studies on dust storms, including sampling improvement, analytic studies, and numerical modeling. However, inhomogeneity of the data has hampered and sometimes even misguided research on comprehensive understanding of dust storms and exploring their feedbacks with climate. This review will focus on currently available observations of dust activities, which include routine meteorological records, in situ air chemistry observations, and satellite remote sensing. The aim is to show data sources and the status of their usage in a common framework for global dust regions. Emphasis is placed on data continuity and the spatial and temporal coverage of dust storms, since it is anticipated that this brief summary of dust data will benefit modeling and climate studies. Therefore, it must be noted that field campaign data are outside of the scope of the current review, although they play an important role in research and understanding.

Chlorinated pesticides and chlorinated organics can be transformed or partially degraded in sediments under appropriate environmental conditions. Although 1,1,1-trichloro-2,2-bis[p-chlorophenyl]ethane (DDT) is very persistent in the environment, 1,1-dichloro-2,2-bis(p-chlorophenyl)ethylene (DDE), a degradation product of DDT, is generally the constituent most widely detected in the environment and DDE is also resistant to further biotransformation. DDT and its degradation products (DDTR) may be transported from one medium to another by sorption, bioaccumulation, dissolution, or volatilization. In sediments, DDT strongly adheres to suspended particles, but once metabolized, DDE, the primary product, is slightly soluble in water. The major migration process for DDTR in sediment-water systems is sorption to sediment or other organic matter and the primary distribution route is the transportation of the particulates to which the compound is bound. Understanding the fate and transport of DDTR in the natural environment based on its specific characteristics is important in determining appropriate remediation option. Common DDT-contaminated sediment remediation options include dredging, capping, and natural attenuation. Sediment washing and phytoremediation have also been used in contaminated sites. Dredging is the most common sediment remediation option to remove the contaminated benthic sediments but often suffers from technical limitations like incomplete removal, unfavorable site conditions, sediment resuspension, and disposal issues. Capping is an in situ, low-cost remediation option for immobilization of DDT in several contaminated sediment sites. Natural or anthropogenic materials containing reactive ingredients, as distinct from a conventional sand or gravel cap, involve placing reactive materials as part of the cap matrix to increase sorption, and to enhance chemical reactivity with DDTR, or accelerate degradation. Natural attenuation can treat the DDT-contaminated sediment, but the time frame for complete remediation may be relatively long. Addition of suitable co-metabolites and acclimatized microorganisms to DDTR-contaminated sediment and alteration of sediment-water micro-environment by manipulating soil pH, moisture content, and other chemical conditions may result in degradation of DDTR associated with sediments at rates faster than the natural attenuation rate.

Heavy metals are subjected to monitoring in estuarine and marine water by the European Union Water Framework Directive, which requires water body health to be achieved by 2021. This is the first survey of heavy metals content in five estuaries of Marche, a region in central Italy. Results showed that total Pb and Cu concentrations decreased by 70–80%, from 1000–2000 to 100–200ngL−1 (Pb) and from 2000–3000 to 500–1000ngL−1 (Cu) from river to sea. Cd was consistently 20–40ngL−1. Dissolved Pb and Cu concentrations declined by 50% and 70% respectively passing from oligohaline to euhaline water, from 150 to 70ngL−1 and from 2000–1000 to 600–400ngL−1. Cd decreased slightly from ∼20 to ∼10ngL−1. Although such concentrations are in the range allowed by the Water Framework Directive, they far exceed (up to 10×) the ground content ceiling set for 2021.