خيارات البحث
النتائج 1131 - 1140 من 3,208
Interpretation of coastal sediment quality based on trace metal and PAH analysis, benthic foraminifera, and toxicity tests (Sardinia, Western Mediterranean) النص الكامل
2015
Schintu, Marco | Buosi, Carla | Galgani, François | Marrucci, Alessandro | Marras, Barbara | Ibba, Angelo | Cherchi, A. (Antonietta)
An integrated approach for the assessment of coastal sediment quality was utilised in three areas of Sardinia (Western Mediterranean, Italy). Sediments were analysed for trace metals and polycyclic aromatic hydrocarbons (PAHs), while benthic foraminifera were used as bioindicators. Furthermore, the embryo-toxicity test was used to provide ecologically relevant information using rapid and cost-effective screening tools. The aim was to evaluate the usefulness of coupling different analytical tools. The results revealed the presence of polluted sediments in areas exposed to petrochemical industries, smelters or military settlements. However, while foraminifera have presented similar indications for chemical analysis of contamination levels in the different areas, the toxicity test exhibited a poor relationship with the contaminants measured individually. The results raise questions concerning the bioavailability of contaminants released by sediments in the water column. Overall, the toxicity rate was significant in many samples in comparison with other sites studied in other Mediterranean regions.
اظهر المزيد [+] اقل [-]Pyrolysis–gas chromatography–mass spectrometry with electron-ionization or resonance-enhanced-multi-photon-ionization for characterization of polycyclic aromatic hydrocarbons in the Baltic Sea النص الكامل
2015
Otto, Stefan | Streibel, Thorsten | Erdmann, Sabrina | Klingbeil, Sophie | Schulz-Bull, Detlef | Zimmermann, Ralf
Polycyclic aromatic hydrocarbons (PAH), as a part of dissolved organic matter (DOM), are environmental pollutants of the marine compartment. This study investigates the origin of PAH, which is supposed to derive mainly from anthropogenic activities, and their alteration along the salinity gradient of the Baltic Sea. Pyrolysis in combination with gas chromatography and two mass selective detectors in one measurement cycle are utilized as a tool for an efficient trace analysis of such complex samples, by which it is possible to detect degradation products of high molecular structures. Along the north–south transect of the Baltic Sea a slightly rising trend for PAH is visible. Their concentration profiles correspond to the ship traffic as a known anthropogenic source, underlined by the value of special isomer ratios such as phenanthrene and anthracene (0.31–0.45) or pyrene and fluoranthene (0.44–0.53). The detection of naphthalene and the distribution of its alkylated representatives support this statement.
اظهر المزيد [+] اقل [-]Histopathology and contaminant concentrations in fish from Kuwait’s marine environment النص الكامل
2015
Al-Zaidan, A.S. | Al-Sarawi, H.A. | Massoud, M.S. | Al-Enezi, M. | Smith, A.J. | Bignell, J.P. | Green, M.J. | Askem, C. | Bolam, T.P.C. | Barber, J.L. | Bersuder, P. | Lyons, B.P.
Kuwait has witnessed major socioeconomic and industrial development in recent decades. Consequently, a variety of contaminants related to these activities have been discharged directly into the marine environment. This paper describes the application of a histopathology baseline survey in two potential sentinel species, the Giant sea catfish (Arius thalassinus) and the Fourlined terapon (Pelates quadrilineatus) to assess the health of biota inhabiting Kuwait’s marine environment. Histological analysis revealed several lesion types in both species, although the prevalence was generally considered low with no discernible differences between sampling locations. The analysis of contaminant burdens (metals, PCBs, PBDEs, HBCDD) in A. thalassinus, along with the analysis of bile for PAH metabolites in both species, indicated that levels of contaminant exposure was low. Overall the data show that both species appear to be susceptible to pathologies associated with environmental contaminants and therefore suitable for further investigation as sentinel organisms for biological effects monitoring.
اظهر المزيد [+] اقل [-]Distribution and ecotoxicology of bioavailable metals and As in surface sediments of Paraguaçu estuary, Todos os Santos Bay, Brazil النص الكامل
2015
Pereira, Taís de S. | Moreira, Ícaro T.A. | de Oliveira, Olívia M.C. | Rios, Mariana C. | Filho, Wilton A.C.S. | de Almeida, Marcos | de Carvalho, Gilson Correia
Surface sediments collected in the intertidal zone of Paraguaçu estuary in July, 2013, were analyzed for organic matter, nitrogen, phosphorus, grain size fractions and partial concentrations of 16 metals. The USEPA 3051A method and ICP-OES and CV-AAS techniques were chosen to metal analysis. Pollution indices (EF, Igeo and PIN) and a comparison with sediment quality guidelines (UET, ERL, ERM, TEL and PEL of NOAA) were conducted in order to evaluate the potential metal impacts over the area. Principal Component Analysis (PCA) and Pearson correlation results showed the importance of organic matter content and the fine-grained fraction of sediments on the control of the bioavailable metals distribution. The Paraguaçu estuary already has anthropogenic enrichment relative to the background level, especially for Mn, whose values exceeded almost 30 times the background at one site (Mn: 1197.30mgkg−1). However, metal levels are still below the reference values with the exception of Hg at one site (Hg: 0.25mgkg−1, exceeded TEL and ERL).
اظهر المزيد [+] اقل [-]Dissecting the distribution of brittle stars along a sewage pollution gradient indicated by organic markers النص الكامل
2015
Barboza, Carlos Alberto de Moura | Martins, César C. | Lana, Paulo da Cunha
We have assessed variation in brittle star distribution patterns along a contamination gradient identified by fecal steroids and aliphatic hydrocarbons in Paranaguá Bay, southern Brazil. A hierarchical design using multiple spatial scales (centimeters-kilometers) was applied. Generalized linear mixed models (GLMMs) were used to investigate the spatial and temporal variability of brittle stars. Main principal components from the contamination and environmental matrices were used to investigate the best explanatory dataset. The abundance of brittle stars was significantly lower in sites with high concentrations of fecal steroids and aliphatic hydrocarbons. The best model fitting always included components from the contamination gradients, which precludes a purely environmental driving of brittle star abundance. Variability in spatial scales lower than kilometers was probably driven by sediment characteristics. We highlighted the importance of a robust multi-scale sampling design for a better biological indication of coastal contamination.
اظهر المزيد [+] اقل [-]Assessment of bioavailability and potential toxicity of Cu, Zn and Pb, a case study in Jurujuba Sound, Rio de Janeiro, Brazil النص الكامل
2015
Abuchacra, P.F.F. | Aguiar, V.M.C. | Abuchacra, R.C. | Baptista Neto, J.A. | Oliveira, A.S.
Potential toxicity of sedimentary Cu, Zn and Pb were evaluated based on their fractionation at the inner part of Jurujuba, a small sound at the eastern margin of Guanabara Bay, Rio de Janeiro. Biogeochemical composition revealed an environment extremely enriched with anthropic organic matter and characterized as a detrital heterotrophic system. The fractionation analysis showed that Pb exhibited more affinity with the residual fraction followed by the amorphous Fe/Mn fraction. Cu and Zn were more expressive in the amorphous Fe/Mn fraction followed by the organic one and crystalline Fe/Mn fraction, respectively. According to Igeo index, sediments proved to be highly polluted by Zn and Cu and moderated polluted by Pb. Despite the actual contamination of Jurujuba sediments, the mobility of these elements seems to be limited since the most excessive concentrations were found in the less available fractions, depending on extreme physico-chemical variations to be released.
اظهر المزيد [+] اقل [-]Variations in macrobenthic community structures in relation to environmental variables in the Seto Inland Sea, Japan النص الكامل
2015
Nishijima, Wataru | Umehara, Akira | Okuda, Tetsuji | Nakai, Satoshi
A data set of 425 sites investigated by the Ministry of the Environment in 2001–2005 was used to evaluate the current sediment situation and its effect on macrobenthic community structure in the Seto Inland Sea, Japan. Cluster analysis and principle component analysis of sediments using physico-chemical parameters revealed that total organic carbon, mud, sulfide contents, and oxidation–reduction potential were important parameters influencing macrobenthic population size and biodiversity. A total organic carbon of 1mgg−1 interval was highly negatively correlated with two biodiversity indices in the range of 1–20mgg−1. Overall, 42% of total sites were organically enriched with much lower macrobenthic population sizes and biodiversity, while 26% were characterized by sandy sediment with a high population size and high proportion of Arthropoda. Nemertea sp., Glycera sp., Notomastus sp. and Ophiophragmus japonicus were common macrobenthos, while Theora fragilis and Ptychoderidae were typical macrobenthos in organically enriched sediments.
اظهر المزيد [+] اقل [-]Heavy metals in red crabs, Chaceon quinquedens, from the Gulf of Mexico النص الكامل
2015
Perry, Harriet | Isphording, Wayne | Trigg, Christine | Riedel, Ralf
The red crab, Chaceon quinquedens, is distributed in deep waters of the Gulf of Mexico (GOM) and is most abundant in an area associated with sediment deposition from the Mississippi River. Sediment geochemistry and biological and ecological traits of red crabs favor accumulation of contaminants. Red crabs, sediment, and bottom water samples were taken from three distinct geographic locations representing areas with differing exposure to contaminant laden effluents from the Mississippi River. Inductively coupled plasma spectrophotometry and atomic absorption spectrophotometry were employed to determine levels of heavy metals in red crab muscle tissue. Ion site partitioning was used to determine metal speciation in sediments. Red crabs showed evidence of heavy metal bioaccumulation in all sample areas with high variability in contaminant levels in individual crabs for some metals. Bioavailability of metals in sediment did not always result in accumulation in muscle tissue.
اظهر المزيد [+] اقل [-]Environmental assessment of coastal surface sediments at Tarut Island, Arabian Gulf (Saudi Arabia) النص الكامل
2015
Youssef, Mohamed | El-Sorogy, Abdelbaset | Al Kahtany, Khaled | Al Otiaby, Naif
Thirty eight surface sediments samples have been collected in the area around Tarut Island, Saudi Arabian Gulf to determine the spatial distribution of metals, and to assess the magnitude of pollution. Total concentrations of Fe, Mn, As, B, Cd, Co, Cr, Cu, Hg, Mo, Pb, Se, and Zn in the sediments were measured using ICP-MS (Inductively Coupled Plasma-Mass Spectrometer). Nature of sediments and heavy metals distribution reflect marked changes in lithology, biological activities in Tarut bay. Very high arsenic concentrations were reported in all studied locations from Tarut Island. The concentrations of Mercury are generally high comparing to the reported values from the Gulf of Oman, Red Sea. The concentrations of As and Hg exceeded the wet threshold safety values (MEC, PEC) indicating possible As and Hg contamination. Dredging and land filling, sewage, and oil pollution are the most important sources of pollution in the study area.
اظهر المزيد [+] اقل [-]Optimization of biostimulant for bioremediation of contaminated coastal sediment by response surface methodology (RSM) and evaluation of microbial diversity by pyrosequencing النص الكامل
2015
Subha, Bakthavachallam | Song, Young Chae | Woo, Jung Hui
The present study aims to optimize the slow release biostimulant ball (BSB) for bioremediation of contaminated coastal sediment using response surface methodology (RSM). Different bacterial communities were evaluated using a pyrosequencing-based approach in contaminated coastal sediments. The effects of BSB size (1–5cm), distance (1–10cm) and time (1–4months) on changes in chemical oxygen demand (COD) and volatile solid (VS) reduction were determined. Maximum reductions of COD and VS, 89.7% and 78.8%, respectively, were observed at a 3cm ball size, 5.5cm distance and 4months; these values are the optimum conditions for effective treatment of contaminated coastal sediment. Most of the variance in COD and VS (0.9291 and 0.9369, respectively) was explained in our chosen models. BSB is a promising method for COD and VS reduction and enhancement of SRB diversity.
اظهر المزيد [+] اقل [-]