In this work, we developed a method based on ultrasound-assisted emulsification microextraction (USAEME) for the determination of nickel by flame atomic absorption spectrometry (FAAS). The method is based on the use of the organic solvent trichloroethylene and 2,2′-thiazolylazo-p-cresol (TAC) as a chelating reagent in a solution containing nickel ions. After ultrasonic emulsification, the mixture is centrifuged to separate the phases. Subsequently, the supernatant is discarded, and the enriched phase is diluted with nitric acid. The nickel content in this new mixture is quantified by FAAS. The following variables were optimized: type of solvent (trichloroethylene), type of chelating reagent (TAC), volume of extraction solvent (100 mL), concentration of chelating reagent (0.015 % w/v), pH (8.0), time of sonication (5.0 min), and time of centrifugation (4.0 min). The limits of detection and quantification were calculated under optimum conditions (0.23 and 0.77 μg L⁻¹, respectively). The enrichment factor obtained was 190. The relative standard deviation (RSD%) of the method (10.0 μg L⁻¹) was 2.3–4.1 %. The proposed method is simple, economical, fast, and efficient for the determination of nickel by FAAS. The procedure was applied to the determination of nickel in certified reference material (BCR-713, wastewater) and water samples.

Saplings of alder (Alnus glutinosa), birch (Betula pendula), hazel (Corylus avellana), beech (Fagus sylvatica), ash (Fraxinus excelsior) and oak (Quercus robur) were exposed to five episodic ozone regimes in solardomes, with treatment means between 16 and 72 ppb. All trees were kept fully watered for the first 5 weeks of exposure, after which half the trees continued to be well-watered, whereas the other half were subjected to a moderate drought by applying approximately 45 % of the amount of water. Species-specific reductions in growth in response to both ozone and drought were found, which could result in reduced potential carbon sequestration in future ozone climates. In well watered conditions, the ozone treatments resulted in total biomass reductions for oak (18 %), alder (16 %), beech (15 %), ash (14 %), birch (14 %) and hazel (7 %) in the 72 ppb compared with the 32 ppb treatment. For beech, there was a reduction in growth in response to ozone in the well-watered treatment, but an increase in growth in response to ozone in the drought treatment, in contrast to the decreased growth that would occur as a result of stomatal closure in response to either the ozone or drought treatment, and therefore assumed to result from changes in hormonal signalling which could result in stomatal opening in combined ozone and drought conditions. For alder, in addition to a decrease in root biomass, there was reduced biomass of root nodules with high compared with low ozone for both drought-treated and well-watered trees. There was also a large reduction in the biomass of nodules from drought trees compared with well-watered. It is therefore possible that changes in the nitrogen dynamics of alder could occur due to reduced nodulation in both drought and elevated ozone conditions.

Despite the decreased emission loads of mercury, historical deposits of this metal in various compartments of the environment may become an additional diffuse source in the future. Global climate change manifests itself in the temperate zone in several ways: warmer winters, shorter icing periods, increased precipitation and heightened frequency of extreme events such as strong gales and floods, all of which cause disturbances in the rate and direction of mercury biogeochemical cycling. The present study was conducted at two sites, Oslonino and Gdynia Orlowo (both in the coastal zone of the Gulf of Gdansk), from which samples were collected once a month between January 2012 and December 2012. In the Southern Baltic region, climate changes can certainly enhance coast to basin fluxes of mercury and the transfer of bioavailable forms of this metal to the food web. They may also, in the future, contribute to uncontrollable increases of mercury in the seawater.

Fe₃O₄and Fe₃O₄/bentonite were prepared by chemical co-precipitation method. They were characterized by X-ray powder diffraction (XRD), Fourier infrared spectroscopy (FTIR), and transmission electron microscope (TEM). Adsorption of cobalt(II) on the bentonite, Fe₃O₄, and Fe₃O₄/bentonite nanocomposite was studied. The results indicated that the metal oxides mainly occurred in the form of spinel structure of Fe₃O₄and the presence of Fe₃O₄significantly affect the surface area and pore structure of the bentonite. The specific surface area (Brunauer–Emmett–Teller (BET) method) of bentonite, Fe₃O₄, and Fe₃O₄/bentonite were determined to be 34.44, 98.44, and 140.5 m² g⁻¹, respectively. TEM image of Fe₃O₄/bentonite shows the particle diameter at 10 nm. The maximum adsorption capacity of cobalt(II) by Fe₃O₄/bentonite nanocomposite was determined to be 18.76 mg g⁻¹. The adsorption strongly depends on pH, where the removal efficiency increases as the pH turns to alkaline range (pH 9). The results suggest that higher adsorption capacity of composite than bentonite is attributed to the presence of Fe₃O₄. The adsorption process follows pseudo-second-order kinetics. The equilibrium data was analyzed by Langmuir model showing high correlation coefficient. The thermodynamic study of adsorption process showed that the adsorption of Co(II) onto Fe₃O₄/bentonite was carried out spontaneously.

Tropical coastal areas are sensitive ecosystems to climate change, mainly due to sea level rise and increasing water temperatures. Furthermore, they may be subject to numerous stresses, including heat releases from energy production. The Urias coastal lagoon (SE Gulf of California), a subtropical tidal estuary, receives cooling water releases from a thermoelectric power plant, urban and industrial wastes, and shrimp farm discharges. In order to evaluate the plant thermal impact, we measured synchronous temperature time series close to and far from the plant. Furthermore, in order to discriminate the thermal pollution impact from natural variability, we used a high-resolution hydrodynamic model forced by, amongst others, cooling water release as a continuous flow (7.78 m³ s⁻¹) at 6 °C overheating temperature. Model results and field data indicated that the main thermal impact was temporally restricted to the warmest months, spatially restricted to the surface layers (above 0.6 m) and distributed along the shoreline within ∼100 m of the release point. The methodology and results of this study can be extrapolated to tropical coastal lagoons that receive heat discharges.

As the use of dangerous substances in consumer products increases, these substances may also be found in society’s end products, among them sewage sludge. Measuring concentrations in sewage sludge can be a way to reflect the consumption of a substance. By using substance flow analysis, the inflow, stock and outflow of the specific substance to, e.g. a city region, may be analysed. Bismuth is a heavy metal that is found in increasing levels in sewage sludge in Swedish wastewater treatment plants (WWTPs) and a similar increase cannot be excluded for WWTPs around the world. This study aims to examine possible sources that could explain the amounts measured in one Swedish WWTP. Household products such as cosmetics (24 %) and plastics (14 %) are found to be major sources of Bi measured in sewage sludge. The remaining unidentified amounts in this study (approximately 50 %) are most likely found in effluent waters from industries or sources outside the household. There is, however, no information on measurements of Bi released by industry available and there is no legislation in place that may encourage industry to conduct such measurements.

Recent droughts in the southwestern United States have heightened the interest in using more reclaimed water for agricultural irrigation. Treated wastewater effluent is a source of irrigation water and contains many pharmaceutical microcontaminants. Currently, there is little knowledge on if these microconstituents will enter food crops and if so where they will be found within the plant. For this experiment, the uptake of 17α-ethynylestradiol, fluoxetine HCl (Prozac®), and ibuprofen within different sections of a celery stalk over a 24-h time period was examined. Results found that all of these pharmaceuticals were taken up into the celery stalks within 24 h. Ibuprofen was found to have reached concentrations of 1 μg/g within the leaves in just 1 h. Metabolites of the ibuprofen were also detected at all locations within the stalk for all time periods. The concentration of EE2 in the submerged section of the stalk was found to increase from 0.031 to 0.911 μg/g of celery in just 23 h. The EE2 began to rise higher within the stalk to reach a concentration of 8.94 ng/g about 6 in above the base after 24 h. Fluoxetine HCl concentrations rose to 0.832 μg/g of celery within the submerged section of the stalk during the 24 h. After 12 h, fluoxetine HCl was detected within the bottom 4 in of the stalk. EE2, fluoxetine HCl, and ibuprofen all exhibit potential for uptake within food crops. Further studies on additional food crops and pharmaceuticals would be required to assess the full risk posed to human eating food crops irrigated with treated wastewater effluent.

In this work, the recovery of mercury from spent fluorescent lamps by oxidative leaching followed by cementation process was studied. Two different reactive solutions (NaOCl/NaCl and KI/I₂) during oxidative leaching were investigated whereas at the cementation process, metallic powders of iron (Fe), copper (Cu), and zinc (Zn) were used as reducing agents to capture mercury in solid phase. Mercury could be transferred to the solution with an efficiency of 96 % from the spent lamp samples through the NaOCl/NaCl reagent. The optimal leaching conditions were determined as 2-h contact time, 120 rpm agitation speed, pH 7.5, and 50 °C of temperature. The reducing agent, Zn, provided 99 % of the cementation. The optimal process conditions were observed to be as 5-min contact time, pH 1, and 5 g L⁻¹ of reducing agent concentration. This combined approach appears to be technically effective for the recovery of mercury from spent fluorescent lamps.

Because of the low energy costs in the absence of the need for aeration, the non-requirement of a carbon source and alkali, and the reduced production of excess sludge, anaerobic ammonia oxidation (Anammox) has been extensively studied as an alternative to the conventional nitrification–denitrification pathway for biological nitrogen removal from wastewater. However, many challenges remain which need to be overcome to prepare the process for engineering application. These include the long doubling time of Anammox bacteria/autotrophic ammonia-oxidizing bacteria (AAOB), the low tolerance capacity to substrate concentration, and high sensitivity to various environmental factors. This review article focuses on the main drawbacks of the Anammox process and evaluates the progress made to date with regard to the enrichment of AAOB and the treatment performance of the Anammox process itself. The factors affecting the nitrogen removal performance of the Anammox process, such as substrate concentration, organic matters, and variation of temperature, are also reviewed and discussed. Finally, the need for the development of long-term storage methods for AAOB is addressed.

Electric arc furnace (EAF) dust and slag, materials which contain high metals in their composition, were improperly disposed in an industrial steel mill site between 1963 and 1999. Previous environmental investigations identified anomalous concentrations of metals in local groundwater but failed to relate these abnormalities to the disposed material or to natural geochemical processes. Aiming to identify the origin of such abnormalities, exploratory and spatial data analysis (EDA-SDA) method was applied on a hydrogeochemical data set obtained through 5 sampling campaigns in 32 groundwater monitoring wells installed upstream and downstream of the area impacted by the steel mill activities. Boxplot class-based and Eh vs. pH maps of physicochemical log-transformed data identified that wells located under the influence of EAF slag deposits in topographic hollows had lower Eh potential and increased electrical conductivity and pH, when compared to wells in the topographical nose of the surveyed area. Metal distribution maps showed that Al, Ca, K, Mg, Na, and Sr were consistently higher in topographic hollows while concentrations of Co, Cu, Cr, and Li were higher near the former steel-making plant, located in the topographical nose. Ba, Fe, Mn, and Zn, important indicators of EAF slag and dust, were observed in both topographic settings. Variable clustering was able to capture the relations among metals and thus validate the log-normalized data structure to be used into wells clustering. Clustering through the mclust algorithm carried out for two and three clusters allowed the distinction among localities that received an input of metals from dust or slag and those not influenced by either residue. This paper demonstrates that EDA-SDA is an effective method to identify areas under the influence of contamination from industrial activities from areas not affected by anthropogenic contamination.