This study performs an environmental risk assessment (ERA) of the anthelmintic medicine albendazole (ABZ) in the eastern African region. A systematic literature search strategy was applied to obtain quantitative information on the physicochemical characteristics, the metabolization-fate, the ecotoxicity and the environmental occurrence in different countries worldwide serving as model regions. In addition, insilico tools were employed to obtain data on physicochemical characteristics and toxic hazards of ABZ and its metabolites. Moreover, ERA models were used to predict environmental concentrations in different compartments and compare them with the measured environmental concentrations. Finally, the environmental risk of ABZ in the eastern Africa was estimated by calculating the risk quotient (RQ), and its uncertainty estimated by Monte Carlo simulation. The predicted environmental concentrations of ABZ in surface water in the model region based on consumption (1.6–267 ng/L) were within the range of values obtained from the measured environmental concentrations of the same region (0.05–101,000 ng/L). Using these models with adapted input variables for eastern Africa, the predicted surface water concentration in that region was 19,600 ± 150 ng/L (95% CI). The calculated soil concentrations of ABZ in the model regions and the eastern Africa were found to be 0.057 ± 0.0 μg/kg and 0.022 ± 0.0 μg/kg, respectively. The environmental risk expressed as risk quotient of ABZ in eastern Africa estimated for the aquatic compartment (146 ± 1) indicated a significant environmental risk calling on appropriate actions from the competent authorities to reduce this risk in this region.

Microplastic (MP) pollution poses a huge threat to agroecosystems, but the distribution characteristics of MPs in different types of farmland are still largely unknown. In this work, samples from six land-use types were collected from Chinese farmlands in five provinces. It was found that MP abundances were in the range of 2783–6366 items/kg in all samples. MP distribution results showed that over 80% of particles were less than 1 mm, and that MP sizes ranging between 0.02 and 0.2 mm represented the greatest proportion. The particle shape classified as fragment (with edges and angular) was the most frequent shape, with an abundance of approximately 54.05%. Polyethylene (PE) and polyamides (PA) were the most abundant polymers in cropped lands; 20.88% and 20.31%, respectively. Statistical analyses showed that lands used for plastic mulching (mulch film and greenhouse crops) had a significantly higher particle abundance, hence identifying plastic mulching as a major contributor to MP pollution in agricultural lands. Furthermore, paddy lands had a significantly higher MP abundance than wheat lands. Variation analyses of MP characteristics revealed that cereal crop farmlands (wheat, paddy land) were more likely to contain fibrous shapes and large MP particles (1–5 mm). Economically important tree lands (orchards, woodlands) were likely to contain fragment shapes and pony-size MPs (0.02–0.2 mm). Discrepancies among farmlands may depend on various reasons, such as mulching plastic application, irrigation, atmospheric fallout, etc. This study provides firsthand evidences about the characteristics of MP pollution in farmlands and explores some predominant MP sources in agroecosystems.

The performance of the radon (²²²Rn)-deficit technique has been evaluated at a site in which a complex DNAPL mixture (mostly hexachlorocyclohexanes and chlorobenzenes) has contaminated all four layers (from top to bottom: anthropic backfill, silt, gravel and marl) of the soil profile. Soil gas samples were collected at two depths (0.8 m and 1.7 m) in seven field campaigns and a total of 186 ²²²Rn measurements were performed with a pulse ionization detector. A statistical assessment of the influence of field parameters on the results revealed that sampling depth and atmospheric pressure did not significantly affect the measurements, while the location of the sampling point and ground-level atmospheric temperature did. In order to remove the bias introduced by varying field temperatures and hence to be able to jointly interpret ²²²Rn measurements from different campaigns, ²²²Rn concentrations were rescaled by dividing each individual datum by the mean ²²²Rn concentration of its corresponding field campaign. Rescaled ²²²Rn maps showed a high spatial correlation between ²²²Rn minima and maximum contaminant concentrations in the top two layers of the soil profile, successfully delineating the surface trace of DNAPL accumulation in the anthropic backfill and silt layers. However, no correlation could be established between ²²²Rn concentrations in superficial soil gas and contaminant concentration in the deeper two layers of the soil profile. These results indicate that the ²²²Rn-deficit technique is unable to describe the vertical variation of contamination processes with depth but can be an effective tool for the preliminary characterization of sites in which the distance between the inlet point of the sampling probe and the contaminant accumulation falls within the effective diffusion length of ²²²Rn in the affected soil profile.

Aquaculture impacts on aquatic organic matter and ecosystem integrity are poorly understood, especially in tropical regions. Here, we investigated the impacts of Nile tilapia net cage farming on the elemental stoichiometry, fluorescence components, and stable isotopes of dissolved organic matter (DOM) of the large, tropical Furnas Reservoir (SE Brazil). Early-stage fish farming, i.e., relatively small and recently implemented farms, had detectable incipient effects on DOM characteristics, and these effects differed between reservoir branches. In the less eutrophic Rio Grande branch of the reservoir, we found a reduction in natural humic-like DOM components and an increase in a protein-like DOM component as far as 100 m away from fish farms. Further, we observed a decrease in δ¹⁵N-TDN due to fish farming. In the more eutrophic Rio Sapucaí branch, there were only local decreases in C:N ratios, as well as rises in C:P and N:P of DOM due to fish farming. These results suggest that early-stage fish farming had local but detectable effects on aquatic DOM that depended on previous eutrophication levels and highlight the need to assess the early impacts of fish farming on tropical reservoirs by combining different monitoring strategies.

Microorganisms comprise the bulk of biodiversity and biomass in Antarctic terrestrial ecosystems. To effectively protect and manage the Antarctic environment from anthropogenic impacts including contamination, the response and recovery of microbial communities should be included in soil remediation efficacy and environmental risk assessments. This is the first investigation into the microbial dynamics associated with large scale bioremediation of hydrocarbon contaminated soil in Antarctica. Over five years of active management, two significant shifts in the microbial community were observed. The initial shift at 12–24 months was significantly correlated with the highest hydrocarbon degradation rates, increased microbial loads, and significant increases in alkB gene abundances. ANCOM analysis identified bacterial genera most likely responsible for the bulk of degradation including Alkanindiges, Arthrobacter, Dietzia and Rhodococcus. The second microbial community shift occurring from 36 to 60 months was associated with further reductions in hydrocarbons and a recovery of amoA nitrification genes, but also increasing pH, accumulation of nitrite and a reduction of oligotrophic bacterial species. Over time, the addition of inorganic fertilisers altered the soil chemistry and led to a disruption of the nitrogen cycle, most likely decoupling ammonia oxidisers from nitrite oxidisers, resulting in nitrite accumulation. The results from this study provide key insights to the long-term management of hydrocarbon bioremediation in Antarctic soils.

As a common health indicator in physical examinations, fasting blood glucose (FBG) level measurements are widely applied as a diagnostic method for diabetes mellitus. Uncertain conclusions remained regarding the relationship between PM₂.₅ exposure and FBG levels. We enrolled 47,471 subjects who participated in annual physical examinations between 2017 and 2019. We collected their general characteristics and FBG levels, and environmental factors simultaneously. We applied the generalized additive model to evaluate the impact of short-term outdoor PM₂.₅ exposure on FBG levels. Among the entire population, the single-pollutant models showed that a 10 μg/m³ increase in PM₂.₅ significantly contributed to 0.0030, 0.0233, and 0.0325 mmol/L increases in FBG at lag 0–7 days, lag 0–21 days, and lag 0–28 days, respectively. Accordingly, in multipollutant models, when PM₂.₅ increased by 10 μg/m³, there was an elevation of 0.0361, 0.0315, 0.0357, and 0.0387 mmol/L in FBG for 8-day, 15-day, 22-day, and 29-day moving averages, respectively. Similarly, we observed a significant positive association between them in the normal population. Moreover, the effects could be modified by age in both the entire and normal populations. Decreasing the ambient PM₂.₅ concentrations can alleviate the elevation of FBG, which may significantly impact the burden of diabetes mellitus.

The continuously increasing presence of micro- and nanoplastics contamination in numerous food products for human consumption is threatening and their potential health effects towards humans remain uncertain. At present, investigations on packaged beverages (e.g. bottled drinking water, beer, milk and refreshments) have received scientific attention and represent an important part of microplastic research as humans are orally exposed to these anthropogenic contaminants every day. Rapid and effective detection methods are important to quantify micro- and nanoplastic particles with a great accuracy as well as to identify their sources and characteristics. A number of methods are currently in use to assess microplastics in packaged beverages; however, the great variations in methods and data acquisition render difficulties when comparing the results and developing the protocols. Based on the challenges, this paper aims to provide a comprehensive understanding of emerging technological approaches, points out the current limitations from sample preparation to quantification and present recommendations. From the results of our analysis, we postulate an example framework that can be applied to different types of drinking products for investigating micro- and nanoplastics. Overall, this review will serve as a first step towards harmonization of micro- and nanoplastic monitoring efforts and a point of reference to help direct future researches focusing on drinking products intended for human consumption.

The Clean Air Action implemented by the Chinese government in 2013 has greatly improved air quality in the North China Plain (NCP). In this work, we report changes in the chemical components of atmospheric fine particulate matter (PM₂.₅) at four NCP sampling sites from 2012/2013 to 2017 to investigate the impacts and drivers of the Clean Air Action on aerosol chemistry, especially for secondary inorganic aerosols (SIA). During the observation period, the concentrations of PM₂.₅ and its chemical components (especially SIA, organic carbon (OC), and elemental carbon (EC)) and the frequency of polluted days (daily PM₂.₅ concentration ≥ 75 μg m⁻³) in the NCP, declined significantly at all four sites. Asynchronized reduction in SIA components (large decreases in SO₄²⁻ with stable or even increased NO₃⁻ and NH₄⁺) was observed in urban Beijing, revealing a shift of the primary form of SIA, which suggested the fractions of NO₃⁻ increased more rapidly than SO₄²⁻ during PM₂.₅ pollution episodes, especially in 2016 and 2017. In addition, unexpected increases in the sulfur oxidation ratio (SOR) and the nitrogen oxidation ratio (NOR) were observed among sites and across years in the substantially decreased PM₂.₅ levels. They were largely determined by secondary aerosol precursors (i.e. decreased SO₂ and NO₂), photochemical oxidants (e.g. increased O₃), temperature, and relative humidity via gas-phase and heterogeneous reactions. Our results not only highlight the effectiveness of the Action Plan for improving air quality in the NCP, but also suggest an increasing importance of SIA in determining PM₂.₅ concentration and composition.

Ubiquitous human exposure to organophosphorus tri-esters (tri-OPEs) has been reported worldwide. Previous studies investigated the feasibility of using house dust and wristbands to assess human OPE exposure. We hypothesized that these two approaches could differ in relative effectiveness in the characterization of children and adult exposure. In the participants recruited from Guangzhou, South China, urinary levels of major OPE metabolites, including diphenyl phosphate (DPHP) and bis(butoxyethyl) phosphate (BBOEP), were significantly higher in children than their mothers (median 6.6 versus 3.7 ng/mL and 0.11 versus 0.06 ng/mL, respectively). The associations of dust or wristband-associated OPEs with urinary metabolites exhibited chemical-specific patterns, which also differed between children and mothers. Significant and marginally significant associations were determined between dust concentrations of triphenyl phosphate (TPHP), tris(2-butoxyethyl) phosphate (TBOEP), trimethylphenyl phosphate (TMPP), or tris(1-chloro-2-propyl) phosphate (TCIPP) and their metabolites in children urine and between dust tris(1,3-dichloroisopropyl) phosphate (TDCIPP), TPHP or TMPP and urinary metabolites in mothers. By contrast, wristbands exhibited better efficiency of predicting internal exposure to TDCIPP. While both house dust and wristbands exhibited the potential as a convenient approach for assessing long-term OPE exposure, their feasibility requires better investigations via larger-scale studies and standardized sampling protocols.

Surface modified lipopeptide biosurfactant (BS) with enhancement of amino acids was produced using Bacillus Malacitensis. The aromatic hydrocarbons from contaminated soil were removed by BS soil washing process and bioremediation using activated functionalized carbon-BS matrix (AFC-BS). The Central Composite Design (CCD) showed the optimum time100 h; pH 7; temperature 30°C on maximum yield of BS. The amino acid profiling of BS reveals the enhancement of amino acids especially polar amino acids and its importance in the formation of micellar structure for the tight packing of aromatic hydrocarbons from industrial contaminated soil. AFC-BS matrix was implanted directly into the contaminated soil for 28 days and found 61.80 % of Total Petroleum Hydrocarbon (TPH) removal efficiency which is high compared to the AFC treated soil. The compounds were extracted from contaminated soil and AFC-BS matrix, found similar peaks in high performance liquid chromatography, which reveals the ability of BS to remove aromatic contaminants. The soil toxicity was also analyzed by seed germination and found improvement in the growth of seeds. The germination of seeds increased from 60 % to 100 % and the phytotoxicity of root and shoot was reduced from 89.50 %, 88.45 % to12.55 %, 11.87 % respectively.