This study reports a new approach of alga amendment in a live mode. The Caulerpa sertularioides alga was modified with sulfur-containing materials of methionine (C₅H₁₁NO₂S) and sodium sulfate (Na₂SO₄) to more concentrate the sulfur content of the yielded biomass (adsorbent). The simple and amended C. sertularioides alga was fully characterized with FTIR, SEM, EDX, BET, BJH, and pHzₚc techniques. The copper adsorption from aqueous media was done by three adsorbents of C. sertularioides-simple (CSS), C. sertularioides-Na₂SO₄ (CSN), and C. sertularioides-C₅H₁₁NO₂S (CSC). The parameters of pH (2–6), adsorbent dosage (2–10 g/L), and contact time (3–80 min) were optimized at 5, 5 g/L, and 60 min, respectively. According to Langmuir isotherm (the best-fitted model), the maximum adsorption capacity of CSN (98.04 mg/g) was obtained 2.4 times higher than CSC (40.73 mg/g) and 9.5 times higher than CSS (10.29 mg/g). The Cu adsorption process by the adsorbents was best-fitted pseudo-second-order kinetic model. The CSN, CSC, and CSS biomasses were successfully reused 5, 4, and 4 times, respectively. The thermodynamic study revealed that the copper adsorption process by CSN is exothermic and non-spontaneous. Finally, the suitability of adsorbents prepared from algae was tested by cleaning a simulated wastewater.

Previous studies have shown that plant diversity can enhance methane (CH₄) emission and nitrogen purification efficiency in constructed wetlands (CWs), but effect of plant diversity on carbon dioxide (CO₂) flux and carbon removal efficiency in CWs is unknown. Therefore, we established four plant diversity levels (each level containing 4, 3, 2, and 1 species, respectively) in laboratory-scale wetland microcosms fed with simulated wastewater. Results showed that plant species richness enhanced CO₂ emissions (84.7–124.7 mg CO₂ m⁻² h⁻¹, P < 0.01), carbon fixation rate (P < 0.05), and microbial biomass carbon (P < 0.001), but did not improve carbon removal (P > 0.05). The presence of Pontederia cordata increased CO₂ emissions, carbon fixation rate of belowground, and microbial biomass carbon (P < 0.05), whereas the presence of Phragmites australis only enhanced CO₂ emission (P < 0.05). However, the presence of Typha orientalis or Lythrum salicaria did not show an influence on CO₂ emissions and carbon removal (P > 0.05). Hence, our study highlights the importance of plant diversity in mediating CO₂ emission intensity and carbon processes but not carbon removal in CWs.

This study aimed at investigating the degradation of fungicide carbendazim (CBZ) via photo-Fenton reactions in artificially and solar irradiated photoreactors at laboratory scale and in a semi-pilot scale Raceway Pond Reactor (RPR), respectively. Acute toxicity was monitored by assessing the sensibility of bioluminescent bacteria (Aliivibrio fischeri) to samples taken during reactions. In addition, by-products formed during solar photo-Fenton were identified by liquid chromatography coupled to mass spectrometry (UFLC-MS). For tests performed in lab-scale, two artificial irradiation sources were compared (UVλ > ₂₅₄ₙₘ and UV-Visλ > ₃₂₀ₙₘ). A complete design of experiments was performed in the semi-pilot scale RPR in order to optimize reaction conditions (Fe²⁺ and H₂O₂ concentrations, and water depth). Efficient degradation of carbendazim (> 96%) and toxicity removal were achieved via artificially irradiated photo-Fenton under both irradiation sources. Control experiments (UV photolysis and UV-Vis peroxidation) were also efficient but led to increased acute toxicity. In addition, H₂O₂/UVλ > ₂₅₄ₙₘ required longer reaction time (60 minutes) when compared to the photo-Fenton process (less than 1 min). While Fenton’s reagent achieved high CBZ and acute toxicity removal, its efficiency demands higher concentration of reagents in comparison to irradiated processes. Solar photo-Fenton removed carbendazim within 15 min of reaction (96%, 0.75 kJ L⁻¹), and monocarbomethoxyguanidine, benzimidazole isocyanate, and 2-aminobenzimidazole were identified as transformation products. Results suggest that both solar photo-Fenton and artificially irradiated systems are promising routes for carbendazim degradation.

Long-term agricultural development has led to agricultural non-point source (NPS) pollution. Ecological ditches (eco-ditch), as specific wetland systems, can be used to manage agricultural NPS water and achieve both ecological and environmental benefits. In order to understand which type of eco-ditch systems (Es, soil eco-ditch; Ec, concrete eco-ditch; Eh, concrete eco-ditch with holes on double-sided wall) is more suitable for plant nutrient balance meanwhile reducing NPS water (total nitrogen [TN], about 10 mg/L; total phosphorus [TP], about 1 mg/L), it is essential to evaluate the plant (Vallisneria natans) stoichiometry response to water in different types of eco-ditches under static experiment. The results indicated that there were no significant differences in TP removal efficiency among three eco-ditches, yet Eh systems had the best TN removal efficiency during the earlier experimental time. Addition of agricultural NPS water had varying effects on plants living in different types of eco-ditch systems. Plant organ stoichiometry of V. natans varied in relation to eco-ditch types. Plant stoichiometry (C:N, C:P, and N:P) of V. natans in Eh systems could maintain the homeostasis of nutrients and was not greatly affected by external changing environment. V. natans in Es systems can more easily modify the nutrient contents of organs with regard to nutrient availability in the environment. Our findings provide useful plant stoichiometry information for ecologists studying other specific ecosystems.

Heavy metals including copper (Cu), zinc (Zn), cadmium (Cd), chromium (Cr), lead (Pb), and arsenic (As) were investigated in 89 pairs of rice plant and paddy soils around Dongting Lake area, China. Rice plants and soils were collected with GPS device, and heavy metal contents in different rice plant tissues and soils were measured. The aim of the present study was to assess the heavy metal pollution and translocation in the whole soil-rice system, including the consequent human health risk for residents. According to the indices of average geoaccumulation (Igₑₒ) of the studied elements, paddy soils in study area were moderately polluted by Cd, lowly polluted by Pb, and not polluted by Cu, Zn, Cr, and As. Considering the much higher concentrations of studied elements in roots than in other tissues of rice plants, a great mass of these elements was assumed to be confined in the roots. The low translocation factors from root to shoot (Tfᵣₒₒₜ₋ₛₕₒₒₜ) of all the studied heavy metals (0.04–0.74) underpinned this. The high translocation factors from soil to root (Tfₛₒᵢₗ₋ᵣₒₒₜ) of Cd (9.12), As (4.38), and Zn (2.05) indicated the high bioavailability of these heavy metals for rice plant. The health risk assessment using target hazard quotients (THQs) model indicated that Cd (5.17 for adults and 4.49 for children respectively) and As (3.61 for adults and 3.14 for children respectively) could cause human health risk both for adults and children. Further, given the rate of individual THQ values exceeding one, Cu might also be considered as a potential human health dangerous element in the study area. It was worth noting that as one of the main pollutants, Pb did not show human health risk through rice grain consumption due to its low Tf values in soil-rice system. However, the risk identification of As using comparisons of measured concentrations with risk screening value in Chinese paddy soil standard (GB15618-2018) was not consistent with the human health risk assessment result. This might indicate that site-specific risk screening values of As in China is in demand.

The transport sector is the fourth largest industrial CO₂ emitter in China, next to power sector, iron and steel industries, and nonmetallic mineral product industry, and plays an important role in reducing China’s CO₂ emissions. In this study, a temporal decomposition analysis model, i.e., Logistic Mean Division Index (LMDI), is developed to analyze the influencing factors of CO₂ emissions in China’s transport sector during 2000–2015. Then, a multi-regional spatial decomposition model is employed to identify the key factors to induce the differences in CO₂ emissions of China’s 30 regional transport sectors in 2000, 2005, 2010, and 2015. Based on the empirical results, we find that both in the temporal and spatial perspectives, the main factors that affect CO₂ emissions in the transport sector are the same ones. From the temporal perspective, the income effect is the dominant factor increasing CO₂ emissions of transport sector, while energy intensity effect and transportation structure effect are the key influencing factors that curb the CO₂ emissions of China’s transport sector, during the whole study period. From the spatial perspective, the income effect, energy intensity effect, and transportation structure effect are the key influencing factors that enlarge the gap of CO₂ emissions of various transport sectors in the key study years. More importantly, the less-developed regions and high energy intensity regions (i.e., the lower energy efficiency regions) are identified to have the great potential to reduce CO₂ emissions of transport sector. Therefore, differentiated mitigation measures and interregional collaborations are encouraged to reduce transport sector’s CO₂ emissions in China.

The latest research focused on the analysis of algal growth and the dynamics of their growth use the laser diffraction technique, enabling determination of the volume fraction of suspended particles with specific diameters in aqueous solution as well as their fractal dimensions. This study focuses on the possibility of using a laser granulometer to assess the growth dynamics of algae growing in treated wastewater in a hydroponic system, supported by artificial lighting with the use of light-emitting diodes (LEDs). On the basis of the measurements, the fractal dimension (Df) of algae was determined. An attempt was made to apply the modified Avrami equation describing the crystallization process for the analysis of algae growth dynamics in wastewater. Presented results show that the fractal dimension of suspended matter, largely created by algae, in the case of additional lighting of the hydroponic system at night, takes lower values (Df ~ 1.0) than in sewage without additional light source (Df ~ 2.0). In each measurement series, the fractal dimension of particles in the tank with lighting in the end of the experiment was about 33–43% lower than in the tank without LEDs. The analysis of changes in particle diameters calculated on the basis of Avrami equation largely corresponds with the stages of algae growth. During the measurement series with lower air temperatures, the growth of algae in the tank with additional light was faster than in the tank without LEDs. The obtained information can be the basis for determining the effective method of removing algae from wastewater treated in the hydroponic system, before they are discharged to the receiver in order to prevent the outflow of increased concentrations of total suspended solids.

In order to enhance the removal of Sb(III) in wastewater, hyperbranched polyamide–functionalized sodium alginate (HA@SA) microsphere was prepared by grafting of hyperbranched polyamide (HA) on the surface of sodium alginate (SA) microsphere. Adsorption properties of Sb(III) were investigated via static and dynamic adsorption tests. The cycling reusability of HA@SA microspheres was explored through adsorption-desorption tests. The changes of HA@SA microspheres before and after adsorption were characterized by FT-IR, SEM-EDS, and XPS. Results showed that the maximum Sb(III) adsorption capacity of HA@SA microspheres reached up to 195.7 mg/g, improved by 1.16 times in comparison with SA microspheres. The Sb(III) adsorption processes of HA@SA microspheres were depicted by pseudo-second-order kinetics and the Langmuir isotherm models with accuracy. It covered a homogeneous single-layer adsorption controlled by chemisorption along with exotherm spontaneously. After recycling for 8 times, the adsorption capacity of HA@SA microspheres still retained higher than 90% of the original value.

The synthetic hormone sodium levothyroxine (LTX) is one of the most prescribed drugs in the world and the most effective in hypothyroidism treatment. The presence of LTX in the environment has become a matter of major concern due to the widespread use of this hormone and by the fact that it is only partially removed in conventional water and sewage treatment plants. However, information regarding the photochemical fate of this hormone in environmental or engineered systems is scarce in the literature. In this work, the sunlight-driven direct and indirect LTX degradation was investigated by determining the photolysis quantum yield, ΦLTX = 3.80 (± 0.02) × 10⁻⁵, as well as the second-order kinetic constants of the reactions with hydroxyl radicals, kLTX,•OH = 1.50 (± 0.01) × 10¹⁰ L mol⁻¹ s⁻¹ and singlet oxygen, kLTX,₁O₂ = 1.47 (± 0.66) × 10⁸ L mol⁻¹ s⁻¹. Mathematical simulations indicate that LTX photodegradation is favored in shallow, nitrite-rich, and dissolved organic matter (DOM)-poor environments, with LTX half-life times varying from less than 10 days to about 80 days. LTX removals of 85 and 95% were achieved by UVC photolysis and UVC/H₂O₂ after 120 min, respectively. Three transformation products, triiodothyronine, diiodothyronine, and diiodotyrosine, were identified during LTX degradation by the UVC-based processes studied. The results herein regarding photo-induced kinetics coupled with environmental fate simulations may help evaluate LTX persistence and also the design of water and wastewater treatment processes.

There is insufficient evidence on the relationship between air pollution and mortality from cardiovascular disease (CVD) in northeast China. Here, we explored the short-term effects of air pollution on CVD mortality and preliminarily investigated differences in population susceptibility to air pollution in Shenyang, China. CVD mortality, air pollution, and meteorological data during 2013–2016 were obtained. Time-series analysis was applied to evaluate the association between air pollution and daily CVD mortality with different lag structures. In the single-pollutant model, each 10 μg/m³ increase in PM₂.₅, PM₁₀, SO₂, NO₂, and O₃ concentrations and 1 mg/m³ increase in CO concentrations at lag0 (same day) was significantly associated with an increase of 0.40% (95% confidence interval, 0.22–0.59%), 0.26% (0.12–0.40%), 0.43% (0.16–0.70%), 0.90% (0.14–1.67%), 0.76% (0.21–1.32%), and 3.33% (0.97–5.75%), respectively, in overall CVD mortality. Susceptibility to air pollutants was higher among females, elderly people, and ischemic heart disease patients. Furthermore, air pollution effects on CVD mortality were 2–8 times greater during the non-heating period. In conclusion, the air pollutants PM₂.₅, PM₁₀, SO₂, NO₂, O₃, and CO showed significant positive effects on CVD mortality in Shenyang, China. These findings highlight the adverse effects of air pollution and suggest the need for personal protective equipment and reduction of air pollution sources.