High levels of trace elements in aquatic environments can affect the quality of seafood. We analyzed the concentrations of As, Cd, Co, Hg, Mn, Ni and Pb, in the edible muscles of Hemiculter leucisculus and A. brama orientalis caught in four different areas of southwest of the Caspian Sea. We estimated the potential risks for human health deriving by the oral consumption of these two species, and the Target Hazard Quotient (THQ) according to the US-EPA approach. THQ by adults and children was always below 1 for all stations. The greater contribution was given by Co, followed by Cd, Hg, Pb, Ni, As and Mn. Total-THQ was 0.538 and 0.246 for children and adults, respectively. Trace elements detected by our study were not elevated, highlighting a positive picture of the studied area and a lower risk of developing chronic systemic effects deriving from the consumption of local fish products.

Sentinel-2 (S2) images have been used in several projects to detect large accumulations of marine litter and plastic targets. Their limited spatial resolution though hinders the detection of relatively small floating accumulations of marine debris. Thus, this study aims at overcoming this limit through the exploration of fusion with very high-resolution WorldView-2/3 (WV-2/3) images. Various state-of-the-art approaches (component substitution, spectral unmixing, deep learning) were applied on data collected in synchronized acquisitions of plastic targets of various sizes and materials in seawater. The fused images were evaluated for spectral and spatial distortions, as well as their ability to spectrally discriminate plastics from water. Several WV-2/3 band combinations were investigated and five litter indexes were applied. Results showed that: a) the VNIR combination is the optimal one, b) the smallest observable plastic target is 0.6 × 0.6 m² and c) SWIR bands are important for marine litter detection.

Movement of marine debris is transboundary and complex, travelling vast distances and accumulating on shorelines. These marine debris wash ashore as stranded beach litter. The objective of this work is to identify release sources of marine debris accumulated along the Singapore coastlines collected by applying a time-backward adjoint marginal sensitivity method and citizen science data of stranded beach litter by a voluntary beach clean-up group. A popular tourist hotspot on the opposite shore was estimated as a possible release source contributing to the marine debris accumulation. This analytical result was validated by population density, industry types, rainfall, and inference from product packaging labels. The use of the citizen science data also illustrated potential as a data source for baseline monitoring and long-term cross-border research that influence policymaking. Future research can be conducted in an expanded domain, considering monsoon effects and instantaneous release events.

This work presents preliminary results about abundance, distribution, characteristics, sources, and fate of microplastics (MPs) in the Central Atlantic Ocean (CAO) of Morocco. The investigation was conducted into three subsections, each characterized by different types of human activities and covering rural, village, and urban areas. MPs were detected in 100 % of the sampling sites. The abundances varied from 0.048 to 3.305 items/m³, with a mean abundance of 0.987 ± 1.081 items/m³. MPs abundance was higher in surface seawater linked to urban areas compared to village and rural areas. The dominant polymer type was polyester (PET-53.8 %) followed by polypropylene (PP-24.36 %), polyamide (PA-7.56 %), polystyrene (PS-6.88 %), polyvinyl chloride (PVC-2.64 %), ethylene vinyl acetate (EVA-2.60 %), polyetherurethane (PUR-1.36 %), and acrylic (AC-0.8 %). Fibers were the most dominant shapes accounting for over 50 %. MPs were mainly smaller than 2 mm in size (71 %) and characterized by colorful aspects. These findings suggested that wastewater treatment plant (WWTP) effluents and anthropogenic activities (industry, tourism, sanitation, and fishing) are the major pollution sources of MPs in the study area. SEM/EDX micrographs showed different weathering degrees and chemical elements adhered to the MPs surface.

This study investigated the nutrient removal efficiency of a constructed wetland (CW) piloted to treat urban runoff before entering an estuary. Physico-chemical, dissolved inorganic nutrient (DIN and DIP), and stormwater inflow volume data were measured. The CW removal efficiency of DIN was negligible (5% uptake), while it acted as a consistent source of DIP (68% efflux) to the receiving estuarine waters. There was low water residency within the small CW (0.8 ha) that has been compounded by a 10-fold increase in flow volume since 2016. The surface area of the CW would need to be increased to 46 ha to cope with current daily inputs (ca. 6300 m³ d⁻¹). The lack of maintenance (e.g., macrophyte harvesting, sediment desludging) has reduced nutrient uptake and increased autochthonous inputs. The conversion of an abandoned saltpan into an extension of the CW has been considered to manage the high flow volume and remove nutrients.

A copepod bioassay with Tigriopus japonicus was applied to evaluate the relative ecotoxicity of sediments in the Yellow and Bohai seas, and contributions of individual PAHs to copepod toxicity were evaluated. Mean toxicity was greatest in the Yellow Sea of China, followed by the Bohai Sea and Yellow Sea of Korea. Elevated concentrations of sedimentary PAHs, alkylphenols, and styrene oligomers back-supported the significant toxicities observed in bioassay. Copepod toxicity in relation to PAHs indicated the greatest contribution by indeno[1,2,3-c,d]pyrene. However, lacked contribution by PAHs, viz., 2.4 and 3.0 % for the total immobilization and mortality, respectively, indicated a large proportion of unknown toxicants being widely distributed along the Yellow Sea Large Marine Ecosystem (YSLME) coastline. Overall, the present study provides useful baseline information for evaluating the potential sedimentary toxicants, with emphasizing further investigation to identify the unknown toxicants at an LME scale, and elsewhere.

The effects of marine litter pose ecological, economic and optional value threats to the countries and territories on the margins of the Atlantic Basin. As the abundance of transboundary marine litter increases, this in turn has triggered the development of marine litter policy action plans and inter-regional collaboration. The OSPAR Commission and Cartagena Convention of North-East Atlantic (NEA) and the Wider Caribbean Region (WCR) respectively, have established a memorandum of understanding to facilitate collaboration for enhanced marine litter management. In light of this development, this paper conducts a scoping review of management measures of marine litter within these regions as well as a coherence analysis between their regional action plans (RAPs). The analysis uses a proactive framework based on a modified categorization by Chen (2015) and Williams and Rangel-Buitrago (2019) for comparatively analyse management measures. The analytical categorizations include legislation and enforcement measures, prevention, removal, monitoring, research, information management and exchange and education and outreach. Although specific approaches differed among the regions depending upon geographical and individual situations, each categorization included detailed management activities except for prevention in NEA and removal in the WCR. The comparative analysis demonstrates that there are opportunities for inter-regional cooperation, knowledge sharing and overall enhanced and informed marine litter management.

It's a new perspective to explore the influences of chromophoric dissolved organic matter (CDOM) components and environmental factors on the removal of sulfisoxazole (SIX) from the water matrix. Reactive intermediates (RIs) trapping experiments demonstrated that excited triplet-state CDOM (³CDOM⁎) played a dominant promoting role (54.11%) in the CDOM-mediated SIX indirect photodegradation. Additionally, terrestrial humic-like (C1, C3 and C4) and marine humic-like (C2) fluorescent components were identified by parallel factor (PARAFAC) analysis of CDOM excitation-emission matrix spectroscopy (EEMs). C1 and C4 were significantly correlated (R² > 0.91) with the SIX degradation rate owing to their higher productivity of RIs and a greater contribution to the production of ³CDOM⁎ compared to others. Salinity, pH and HCO₃⁻ were conducive to the SIX indirect photodegradation, while metal ions (Fe³⁺ and Cu²⁺), halogen ions (Cl⁻ and Br⁻) and NO₃⁻ were opposite. These findings are essential for understanding the environmental fate of SIX in coastal waters.

Accidental oil spills from pipelines or tankers have posed a big threat to marine life and natural resources. This paper presents a novel lightweight bilateral segmentation network for detecting oil spills on the sea surface. A novel deep-learning semantic-segmentation algorithm is firstly created for analyzing the characteristics of oil spill images. A Bilateral Segmentation Network (BiSeNetV2) is then selected as the basic network architecture and evaluated by using experimental comparison of the current mainstream networks on detection accuracy and real-time performances for oil samples. Furthermore, the Gather-and-Expansion (GE) layer of the semantic branch in the traditional network is redesigned and the parameter complexity is reduced. A dual attention mechanism is deployed in the two branches of the BiSeNetV2 to solve the problem of inter-class similarity. Finally, experimental results are given to show the good detection accuracy of the proposed network.