Remediation of residually contaminated soils remains a widespread problem. Biochar can immobilize polycyclic aromatic hydrocarbons (PAH). However, studies on its ability to immobilize PAH and N, S, and O substituted PAH (hetero-PAH) in real soils, and benchmarking with commercial activated carbon are missing. Here, we compared the ability of pristine biochar (BC), steam-activated biochar (SABC), and commercial activated carbon (AC) to immobilize PAH and hetero-PAH. The three carbons were tested on soils from four different contaminated sites in Austria. Different amendment rates (w/w) of the carbons were investigated (BC: 1.0, 2.5, and 5%; SABC: 0.5, 1.0, and 2.0%; AC: 1%) in batch experiments to cover meaningful ranges in relation to their performance. SABC performed better than AC, removing at least 80% PAH with the lowest application rate of 0.5%, and achieving a complete removal at an application rate of 1.0%. BC performed slightly worse but still acceptable in residually contaminated soils (40 and 100% removal at 1 and 5% amendment, respectively). The ability of BC and SABC to immobilize PAH decreased as the PAH-molar volume increased. PAH with three or more rings were preferentially removed by AC compared to SABC or BC. This can be explained by the difference in pore size distribution of the carbons which could limit the accessibility of PAH and hetero-PAH to reach sorption sites for π- π electron donor-acceptor interactions, which drive PAH and hetero-PAH sorption to carbons. Column percolation tests confirmed the results obtained in batch tests, indicating, that decisions for soil remediation can be derived from simpler batch experiments. In soil samples with 1% BC, a reduction of over 90% in the total concentration of PAH in the leached water was observed. Overall, BC and SABC were demonstrated to be valid substitutes for AC for stabilizing residually contaminated soils.

International audience | The use of biochars (BCs) and activated carbons as a way of sequestering soil-bound pollutants such as chlordecone (CLD) is increasingly being studied. This study aims at assessing the impact of Sargassum BC/AC particle size and Sargassum BC amendment rate on CLD adsorption in Nitisol and in Andosol. Four different types of carbonaceous matrices were tested: Sargasso carbon activated by phosphoric acid (SargH3PO4), Sargasso carbon activated by steam (SargH2O), biochar of Sargasso (Ch Sarg700), and a commercial activated carbon (ORBO™). In a first experiment, CLD contaminated Andosol and Nitisol were amended with 2% of each carbonaceous matrix divided into four particles size classes (< 50 µm, 50–150 µm, 150–200 µm, and > 200 µm). In a second experiment, the contaminated soils were amended with the biochar of Sargasso at five application rates (0, 0.25, 0.5, 1, and 2% (w/w)). After a 4-month aging, environmental availability tests were carried out on the soils of both experiments. The results of the first experiment showed that the best reductions of CLD environmental availability were obtained in both soils with the biochar of Sargasso and the ORBO™. More specifically, in nitisol, particle size under 50 µm of biochar of Sargasso and AC ORBO™ showed a CLD environmental availability reduction up to 72 ± 2.6% and 79 ± 2.6%. In Andosol, there was no significant difference between the three particle sizes (< 50 µm, 50–150 µm, and 150–200 µm) of the biochar of Sargasso on the reduction of environmental availability (average reduction of 43 ± 2.5%). The results of the second experiment showed that an amendment rate increase improves the immobilization of CLD. When the amendment rate was increased from 0.25 to 2%, the environmental availability was reduced by 43% in Nitisol and 50% in Andosol.

Oxidative coupling of thiols to the corresponding symmetrical disulfides were performed in the presence of silica gel supported tributylammonium fluorochromate(VI), (TriBAFC), and tributylammonium chlorochromate(VI), (TriBACC). Silica gel supported TriBAFC and TriBACC are versatile reagents for the effective and selective oxidation of organic substrates, in particular of thiol, under mild conditions. Disulfides are also key intermediates in a wide variety of organic synthetic routes. Considerable improvements are observed in the presence of the absorbent and making the work-up much more convenient. The nature of the solvent does not appear to be particularly critical. Hydrocarbons, benzene, ethers and chlorinated hydrocarbons are equally effective, the practical choice being oriented by the solubility of the products and the desired reaction temperature. The IR spectra of TriBAFC and TriBACC are similar to that of other fluoro and chlorochromates, TriBAFC and TriBACC are soluble in water, dimethylformamide, acetonitrile, acetone and dichloromethane; they are only sparingly soluble in benzene, carbon tetrachloride, chloroform and hexane.

The purpose of this research is to analyze the risk of ammonia release in the cold storage of one of the large food companies in Mashhad. This is an applied research that was done using FTA technique and fuzzy logic. Fuzzy logic was used to weight experts' opinions (Delphi panel). In this study, to model the consequences and calculate the collective risk using the DNV PHAST 7.2 software, the most critical conditions that have the greatest possible contribution to the release of ammonia were, respectively: lack of proper and planned maintenance; Pressure increase and failure and defects in gaskets. Also, the results showed that the rate of death, toxicity and explosion is directly related to the distance. On the other hand, the maximum amount of possible losses in the event of an explosion will be in the winter season and at a distance of 14.26 meters, and finally, 95% of the losses due to the blast wave will occur at a distance of 13.54 meters and 99% of deaths of people up to a radius of 38.89 meters, also 50% of the deaths of people from the radius of 38.89 meters to the radius of 124.93 meters, and 10% of the deaths of people from the radius of 124.93 meters to the radius of 178.53 meters, also 1 percent of deaths from the radius of 178.53 meters to the radius of 234.05 meters.

This study provides a practical solution to manage non-hazardous waste and aid the environment. The largest group of non-hazardous waste is called municipal solid waste (MSW) which can be effectively used as an alternative material in civil projects. In this research, as an alternative to traditional modification methods of soil which causes global warming, the soft clay (Clay) was chemically modified by four different percentages of MSW in soil dimensions (15%, 25%, 35%, 45%) in 28 and 120 days. The optimum percentage of MSW addition (15%) to the Clay at the curing age of 28 days increased the unconfined compressive strength (UCS) and California bearing ratio (CBR) by 1.28 and 3.34 times, respectively. Given that higher percentages of MSW reduce the UCS and CBR in the specimens, four percentages of Nano-MgO, i.e., 0.25, 0.5, 0.75, and 1% were used for stabilization. The specimens containing optimum percentages of MSW (15%, 25%) and stabilized with 1% Nano-MgO could improve UCS and CBR 2.34 and 5.59 times, respectively that results had better durability over 120-days which can be attributed to the CBR testing condition. The cause of the increase in UCS and CBR was investigated using microstructural analysis for 120 days of curing. The specimen with high durability approved the cement bond formation with Anorthite & Dolomite minerals. In conclusion, using optimum MSW and Nano-MgO effectively solved the Clay problems in suitable conditions and allowed higher percentages of MSW to be removed from the environment.

The present descriptive cross-sectional study was conducted by altering the type of blowers in the wastewater treatment system of Abuzar hospital in Ahvaz during the first and second quarters (6 months). In every month, inlet raw wastewater, aeration tank one, and effluent were sampled in one week (Saturday-Friday), which resulted in harvesting a total of 42 samples. Then, they were assessed based on the techniques provided in the book entitled "standard methods for evaluating water and wastewater", and data were evaluated through employing statistical analyses. The average removal efficiency of total and organic phosphorus, phosphate, and ammonia in the effluent was respectively determined 46.47, 34.45, 18.14, and 68.49 before starting up a new aeration system, which reached 69.36, 76.21, 65.09, and 96.53 during the second period, respectively. In addition, the average concentration of nitrate varied from 21.79 to 44.11 mg/l, while that of nitrite changed from 0.04 to 0.03 mg/l. Further, an increase (39.19 to 67.19%) was observed in the average nitrogen removal efficiency in effluent. Based on the results, EAAS process was efficient in eliminating nitrogen and phosphorus by using the helicoidal pumps of aeration blowers and regulating aeration rate. Thus, aeration plays an effective role in activated sludge systems despite the microorganism diversity in aeration tank sludge. The produced effluent was consistent with Iran national standards in terms of the parameters under study, especially phosphorus and nitrogen, and can be discharged into the environment.

The purpose of this study is to achieve the effective components and criteria in the design of green residential settlements with an environmental protection approach in Mashhad. The research method is applied and in terms of implementation is descriptive-analytical. Using the TM sensor and LANDSAT satellite, satellite images of the study area were prepared and modeled by superimposing data related to energy consumption through GIS tools and Arcview software to final synthesis and mapping. Then, using the opinions of experts to extract and prioritize the appropriate components and criteria from each of the mentioned systems. Data were analyzed by structural equation method with least squares approach and Smart - PLS2 software was used for final analysis. Then, after explaining the components and criteria, according to the available data, the optimal limit (10% -20%) for 10 components was proposed as a scenario. Then modeling was done through Design Builder software. The results showed that a total of 4 categories of macro variables have been identified as the main components affecting energy consumption, which are: "management", "environmental performance", "economic performance" and "social performance" variables, all of which have divergent validity. Also, 11 topics and 61 criteria were extracted and explained as components for assessing the sustainability of residential buildings. Finally, it was found that with the implementation of energy optimization strategies, the heating system will be reduced by 36%, the cooling system energy by 41% and the total cooling and heating energy by 38% compared to the base state.

The most important objectives of the present study include finding a legal solution to prevent the spread of coronavirus, compensation for damages caused by the negligence of human factors, determining the basis for this responsibility, and the rate of compensation for these damages. The present study, through library and field studies, made it possible to compensate for the damage caused by the spread of coronavirus infections. Pollution caused by a human is one of the most important environmental law challenges. Neglect of the human factor has caused losses due to the spread of this disease. In the present study by preparing a researcher-made questionnaire, the opinion of lawyers specializing in the field of civil responsibility was also inquired. The results of the research show that by resorting to the "risk theory" and the "fault assumption" basis, the rights of the victims of the Coronavirus can be better secured. At present, legal systems are not sufficiently determined to compensate the victims of the Coronavirus. While environmental jurists believe that strict rules and regulations should be applied to combat the spread of coronavirus infection and to impose compensation for damages caused by negligence in observing health standards on its human factors. In Iran, several juridical and legal rules are a good basis for preventing the spread of coronavirus and human infections.

Sound pollution is known as one of the main disturbances in urban environments. The purpose of this study is to measure the sound level during sports competitions in the vicinity of settlements. For this purpose, Azadi Sports Complex was selected as the largest sports space in the IRAN and the measurements were performed cross-sectional and in two different times, which included days without sports competition and after the end of the sports competition. Measurements were used 5 times by KIMO-DB100. All measurements were made to determine the sound pressure level in network A. The mean data (Leq) was the basis for drawing the maps. To do this, the pattern of changes was entered into the Arc map software and based on the Inverse Distance Weighting method. The results showed that the minimum sound level on the day without exercise was 50 dB and the maximum sound level measured at this time was 80 dB. On the day of the race, the minimum and maximum sound levels were 55 dB and 95 dB, respectively. On a non-racing day, large sections of the study range have sound levels of 50-65 dB, indicating relative calm and compliance with outdoor sound standards. However, on the day of the match and after the spectators left the stadium, none of the sound level stations showed less than 75 dB. This situation continues for about 3 hours after the end of the game and until the study area of spectators and their cars is completely emptied.

Industrial dust has a significant effect on the environment of mines, which leads to an increase in illness among workers. To decrease the impact of dust on the climate, a wet spraying system is useful for controlling dust in mining companies. In this paper, by using the wet (water) spraying system, dust control in the area of the crusher and pellet plant (discharge tower) has been investigated by Goharzamin Iron Ore company. Goharzamin Iron Ore company has an essential role producing of steel in Iran. There are a 15 million tons gyratory crusher, three iron concentrate plants with an annual capacity of 6 million tons, and a pelletizing plant with annual capacity of 5 million tons. The dust was controlled in the gyratory crusher area of Goharzamin Iron Ore company by using a wetting spraying system. Results showed that the rates of PM10 for the east, west, north and south sides of the gyratory crusher and also the center of this system are equal 851.2, 647.5, 643.9 and 781.2, and 1116.3 μg/m3, respectively. Foremore, after turning on the wet spraying system in this area, these values are reduced to 128.3, 112.8, 115.9, 123.7, and 189.9 μg/m3, respectively. The results showed that the water spray system in the gyratory crusher area reduced the PM2.5 (Particulate matter) and PM10 particles by 67% and 80%, respectively.