The new design of internal flotation components and the use of biogas were employed to develop a novel anaerobic self-flotation (ASF) reactor. Compared with the upflow anaerobic sludge blanket (UASB) reactor, the removal efficiencies of total chemical oxygen demand (COD) and suspended solids (SS) of the ASF reactor were higher than 90% under high SS concentration and high volumetric organic loading rate (OLR). The biogas flotation, sludge bed retention, and effluent washout accounted for 60%, 30%, and 10% of SS mass, respectively, proving that the biogas flotation was the main mechanism of SS removal in the ASF reactor. Extracellular polymer substance, mainly consisting of polysaccharide (PS) and protein (PN), was found to promote the SS removal by biogas flotation via the scum formation at the ratio of 294.12 g-VS/g-PS and 103.09 g-VS/g-PN. The EPS yield was determined as 2.3 ± 0.6 g-PS/g-COD and 11.5 ± 2.6 g-PN/g-COD at the OLR of 60 kg/(m³ day). The biogas production was revealed to enhance the SS removal by providing flotation driving force and by decreasing the scum density. A model was established to describe the quantitative relationship between flotation scum and OLR. This work would shed light on the high SS wastewater treatment challenge of high-rate anaerobic processes by using biogas flotation.

Persistent organic pollutants (POPs) constitute a wide range of chemicals. Their release into the environment has raised great concern due to their potentially harmful impact in humans and wildlife species. The aim of this current study was to detect selected POPs in hair samples of wild terrestrial mammals from Primorsky Krai, Russia, so as to assess potential environmental exposure. The tested wild species were leopard cat, musk deer, wolf, amur hedgehog, and raccoon dog. The targeted organochlorines were hexachlorobenzene (HCB) and DDTs (opDDE, ppDDE, and opDDD), polychlorinated biphenyl (PCB) congeners (28, 52, 101, 118, 138, 153, and 180), and polycyclic aromatic hydrocarbons (PAHs) (acenaphylene (ACEN), fluorene (FLU), anthracene (ANTH) phenathrene (PHEN), and pyrene (PYR)). The detection of POPs was conducted in hair samples by a one-step hair extraction method, by using a headspace solid-phase microextraction technique (HS-SPME) and analyzed then by GC-MS. The majority of the wild animal hair samples were found positive in all tested pollutants. More specifically, the percentage of positive hair samples for HCB was 93.3% and for DDTs, PCBs, and PAHs, 20.0 to 100.0%, 6.7 to 100.0%, and 75.0 to 100.0%, respectively. DDT, PCB, and PAH detection ranged from 1.26 to 52.06 pg mg⁻¹, 0.73 to 31.34 pg mg⁻¹, and 2.59 to 35.00 pg mg⁻¹, respectively. The highest mean concentration levels of all tested pollutants were found for musk deer (PCBs 12.41 pg mg⁻¹, DDTs 21.87 pg mg⁻¹, PAHs 22.12 pg mg⁻¹) compared to the other wild species. To the best of our knowledge, this is the first study that provides results regarding contamination in different terrestrial mammals by POP exposure. The use of hair as a matrix is proven to be an effective tool for nondestructive biological monitoring of POP contamination in terrestrial ecosystems.

Surveys of extended-spectrum β-lactamase-producing Enterobacteriaceae (ESBL-pE) in stream water and untreated wastewater were carried out in Okinawa Prefecture, Japan. Thirty-six samples of water were collected from 18 streams in Okinawa Prefecture, as well as ten samples of wastewater flowing into four wastewater treatment plants (WWTPs). We investigated bacterial species, Escherichia coli O antigen, ESBL phenotype, ESBL genotype, and pulsed-field gel electrophoresis (PFGE) type of isolates, and total viable count and fecal coliforms as indicator organisms. The relation between indicator organisms and ESBL-pE was also validated using the same samples. A total of 141 ESBL-pE including 107 E. coli, 15 Klebsiella pneumoniae, 2 Proteus mirabilis, and 17 other species was isolated from stream water and wastewater. Of the 141 ESBL-pE, 14.9% and 54.6% were found to be blaCTX-M-15 and blaCTX-M-14-like types, respectively, which have been found in hospital isolates in Okinawa. Two pairs of possibly related patterns according to PFGE criteria were isolated from stream water and wastewater in two districts. When ESBL-pE was significantly isolated, total viable count and fecal coliform boundaries were ≥ 6.0 × 10³ CFU/ml and ≥ 4.3 × 10² most probable number/100 ml, respectively. These results suggested that ESBL-pE isolated from stream water is human derived, and that total viable count and fecal coliforms will be useful as indicators for confirming the spread of ESBL-pE to the environment by means of simple hygiene surveys.

Petroleum hydrocarbons are potentially toxic for organisms due to the inherent properties, such as solubility, volatility, and biodegradability. The petroleum materials released from corroded old pipelines would pollute soils, shallow groundwater and air as a consequence, and threat the health of human and environment. Therefore, the removal of these compounds from environment is vital. The stability of these pollutants at the soil and their gradual accumulation over time would disrupt the normal function of the soil, such as reduced agricultural capability. In this research, the influence of two plant species (Bromus tectorum L. and Festuca arundinacea) with different amendments including arbuscular mycorrhizal fungi, alfalfa residues, and nutrient solution on the degradation rate of petroleum hydrocarbons in soil was studied. The results showed that the most effective treatment for petroleum remediation was related to B. tectorum L. plant when treated with mycorrhizal fungi and nutrient solution. The degradation rate during 40 days was about 83.27% when compared to the control. Arbuscular mycorrhizal associations are important in the restoration of degraded ecosystems because of the benefits to their symbiotic partners. This fungal phytotechnological mechanism is still in its infancy and there has been little research on aged-contaminated soils.

In last decades, the biosorption process has become one of the main alternative treatment technologies for the removal of pollutants from dilute aqueous solution. Among these pollutants, toxic metals have drawn attention due to their negative effects in human body and food chain. Even though biosorption is considered a cost-effective and eco-friendly technology to remove toxic metals from dilute wastewaters, there are still obstacles that restrain its commercialization. For this reason, various scientific articles and patents have been published each year to make more effective and economical this technology. This review reports an overview of past achievements, current research of biosorption studies, and future trends for the development of the biosorption as sustainable cleaner technology. Mechanisms of metal uptake, recovery and biosorbent regeneration, process design, commercial application of biosorbents, and patents registered are presented. Finally, future aspects in biosorption research and suggestions for its application will be discussed.

The feedstock from cinnamon (CI) and cannabis (CA) were used for providing biochar at different temperatures using the pyrolysis method (300, 400, and 600 °C) as appropriate adsorbents for removing Pb(II) ions. The properties of materials were examined with varied techniques. The BET surface area of CI600 and CA600 was higher compared with others. The adsorption efficiency of Pb(II) ions relies on initial Pb(II) concentration, pH, adsorbent dose, equilibrium time, and temperature. The adsorption isotherms of Pb(II) ions were assessed via Langmuir adsorption isotherm and the pseudo-second-order model and electrostatic interaction became visible to play the main role in the adsorption process.

The successful establishment of China’s emission trading scheme (ETS) could lead the next generation of global climate carbon markets in industrializing and developing countries. The allocation of ETS revenue from auctioning carbon emission allowance is important for the achievement of China’s joint targets of economic growth, mitigation, and welfare improvement. This study develops a dynamic CGE model to evaluate the effects of different ETS revenue allocation mechanisms and identifies the proper mechanism for China’s ETS design. Ten scenarios including business as usual (BAU), no ETS revenue allocation incentive (NA) and other eight ETS revenue allocation scenarios are designed. Simulation results indicate that the tradeoff between economic cost and environmental benefit exists under different ETS revenue allocation mechanisms. ETS revenue is suggested to allocate to household sector through reducing indirect tax and, after 2020, a certain proportion of ETS revenue could be allocated to production sector for improving energy-saving technology (i.e., STP mechanism). This study provides references for policymakers in China to design effective and realistic ETS-related policies. A similar study could be conducted to explore the proper ETS and the revenue allocation policies in other countries that have similar national conditions to China, such as other BRICS countries.

Financial development is often expressed as a private sector initiative earmarked towards motivating economic growth and mitigating poverty. Nonetheless, the need for economic development accompanied by high industrialisation and commercialisation strategies has generated natural environmental effects which have raised enormous concern to green interest groups about whether all the seventeen sustainable development goals will be achieved. This paper investigated the environmental effects of financial development in OECD countries from 2001 to 2012 by employing static models and system GMM analysis. The study utilised foreign direct investments, domestic credit to private sector by banks and domestic credit to private sector as the three proxies of financial development. The effects of these measures of financial development were examined on carbon emissions and greenhouse gases (indicators of environmental quality) and environmental sustainability. In this setting, the findings of the research spotlight that domestic credit to private sector by banks shows a negative and significant relationship with carbon emissions, greenhouse gases and sustainability. Conversely, domestic credit to private sector and economic growth indicates a positive and statistically significant relationship with carbon emissions, greenhouse gases and sustainability. Foreign direct investment is positive and significantly connected with carbon emissions and sustainability but only shows a positive and not significant link with greenhouse gases. The evidence suggested by this analysis adds that the financial system should continue to add more initiatives which consider natural environmental perspectives in their current operations. This present study also confirms the existence of the environmental Kuznets curve (EKC) in carbon emissions (turning point, $109,820), total greenhouse gases (turning point, $74,280) and sustainability (turning point, $112,505). The finding that the turning point of carbon emissions is higher than that of total greenhouse gases indicates why introducing initiatives designed to curb growth of carbon emissions in the respective OECD economies is important.

The present study aimed to assess the level of metal ions [chromium (Cr), copper (Cu), iron (Fe), manganese (Mn), nickel (Ni), and zinc (Zn)] in the serum of patients with fixed orthodontic appliances. One hundred samples (32 males, 68 females) were collected from patients undergoing fixed orthodontic treatment for different periods. A reference (control) group (24 males, 16 females) who had no appliances was used to properly evaluate the changes in the level of these elements in orthodontic appliance users. The element concentrations were measured using inductively coupled plasma mass spectrometry (ICP-MS). Higher concentrations of metal ions (except for Cr) were found in the serum of the orthodontic group. Bivariate scatter plot showed a highly significant (p < 0.001) correlation between Ni and other elements. The duration of orthodontic treatment increased significantly the Ni levels whereas the bracket type was found to have no significant impact on altering the concentration level of metal ions. The results of the SEM-EDS showed a high variation in the level of metal ions in the brackets and wires. In conclusion, fixed orthodontic appliances increased serum levels of Ni, Zn, Mn, Fe, and Cu but did not change Cr levels.

Phosphorus (P), an essential element for living cells, is present in different soluble and adsorbed chemical forms found in soil, sediment, and water. Most species are generally immobile and easily adsorbed onto soil particles. However, P is a major concern owing to its serious environmental effects (e.g., eutrophication, scale formation) when found in excess in natural or engineered environments. Commercial chemicals, fertilizers, sewage effluent, animal manure, and agricultural waste are the major sources of P pollution. But there is limited P resources worldwide. Therefore, the fate, effects, and transport of P in association with its removal, treatment, and recycling in natural and engineered systems are important. P removal and recycling technologies utilize different types of physical, biological, and chemical processes. Moreover, P minerals (struvite, vivianite, etc.) can precipitate and form scales in drinking water and wastewater systems. Hence, P minerals (e.g., struvite, vivianite etc.) are problems when left uncontrolled and unmonitored although their recovery is beneficial (e.g., slow release fertilizers, sustainable P sources, soil enhancers). Sources like wastewater, human waste, waste nutrient solution, etc. can be used for P recycling. This review paper extensively summarizes the importance and distribution of P in different environmental compartments, the effects of P in natural and engineered systems, P removal mechanisms through treatment, and recycling technologies specially focusing on various types of phosphate mineral precipitation. In particular, the factors controlling mineral (e.g., struvite and vivianite) precipitation in natural and engineered systems are also discussed.