In this work, the synthesis of catalyst with perovskite structure and chemical formula La₁₋XCeXMnO₃ at x = 0 − 0.5 were successfully obtained by an ultrasonic-assisted hydrothermal method. Results show that the addition of Ce in La₁₋XCeXMnO₃ have not substantial effect in textural and morphological properties; however, the formation of a new crystalline phase with final composition CeOX-La₁₋XCeXMnO₃ was detected at values x > 0.3. All synthesized catalysts were tested in the soot oxidation under both, loose and tight contact in 20% O₂/N₂ or 5% O₂/N₂ atmospheres. CeOX-La₁₋XCeXMnO₃ at x = 0.3 resulted in the best catalytic activity with activation energy values of 57.9 kJ.mol⁻¹. The interaction between Ce³⁺ and Mn⁴⁺ species in this catalyst can transfer electrons generating Mn³⁺ and Ce⁴⁺. This reduction from Mn⁴⁺ to Mn³⁺ is accompanied by migration of vacancies to the surface promoting the adsorbed oxygen from the gas phase, need for balancing the chemical states. By increasing the temperature above 300 °C, the bulk oxygen migration to the surface is enhanced being the responsible for the oxygen availability. The formation of CeOX-La₁₋XCeXMnO₃ promotes a stable redox cycle allowing the reusability of this catalyst even at low oxygen pressures after three different reaction cycles.

In the French West Indies, the chlordecone (organochloride pesticide) pollution is now diffuse becoming new contamination source for crops and environment (water, trophic chain). Decontamination by bioremediation and chemical degradation are still under development but the physical limitations of these approaches are generally not taken into account. These physical limitations are related to the poor physical accessibility to the pesticides in soils because of the peculiar structural properties of the contaminated clays (pore volume, transport properties, permeability, and diffusion). Some volcanic soils (andosols), which represent the half of the contaminated soils in Martinique, contain nanoclay (allophane) with a unique structure and porous properties. Andosols are characterized by pore size distribution in the mesoporous range, a high specific surface area, a large pore volume, and a fractal structure. Our hypothesis is that the clay microstructure characteristics are crucial physico-chemical factors strongly limiting the remediation of the pesticide. Our results show that allophane microstructure (small pore size, hierarchical microstructure, and tortuosity) favors accumulation of chlordecone, in andosols. Moreover, the clay microporosity limits the accessibility of microorganisms and chemical species able to decontaminate because of poor transport properties (permeability and diffusion). We model the transport properties by two approaches: (1) we use a numerical model to simulate the structure of allophane aggregates. The algorithm is based on a cluster–cluster aggregation model. From the simulated data, we derived the pore volume, specific surface area, tortuosity, permeability, and diffusion. We show that transport properties strongly decrease because of the presence of allophane. (2) The fractal approach. We characterize the fractal features (size of the fractal aggregate, fractal dimension, tortuosity inside allophane aggregates) and we calculate that transport properties decrease of several order ranges inside the clay aggregates. These poor transport properties are important parameters to explain the poor accessibility to pollutants in volcanic soils and should be taken into account by future decontamination process. We conclude that for andosols, this inaccessibility could render inefficient some of the methods proposed in the literature.

Open municipal solid waste (MSW) combustion is a major emission source of particulate air pollution, polycyclic aromatic hydrocarbons, and more exotic hazardous organic pollutants including polychlorinated biphenyls and brominated flame retardants. However, the adverse impact of MSW combustion emission on health among the general population is unknown. Therefore, a cross-sectional study was conducted to explore the associations between potential exposure to MSW combustion-related air pollution and symptoms of adverse health effects among residents of a community adjacent to a large open landfill in Lagos, Nigeria. Using ordinal logistic regression and controlling for age, sex, and smoking, it was observed that residence for ≥ 11 years had increased odds (p < 0.05) of daily occurrence of tingling/numbness/whiteness of fingers (2.614), headaches (2.725), memory problems (2.869), tremor/cramps (2.748), and confusion (3.033) among other symptoms. These results indicate adverse health impacts of chronic exposure to MSW combustion emission.

This study aims to examine the impact of public-private partnerships (PPP) investment in energy, technological innovations (TI), economic growth (EG), exports, and foreign direct investment (FDI) on CO₂ emissions in Brazil over the period from 1984 to 2018. In doing so, we employ the Ng-Perron unit root test to examine the stationarity and autoregressive lag distributed (ARDL) model for cointegration between CO₂ emissions and its determinants. The outcomes are as follows: first, in the long run, the PPP investment in energy deteriorates the environmental quality by increasing CO₂ emissions, while TI has a significant negative effect on CO₂ emissions. It is also found that the exports and FDI degrade the environmental quality and the relationship between EG and CO₂ emissions is inverted U-Shaped, presence of the EKC hypothesis. Second, in the short run, PPP investment in the energy sector is negatively influencing, while TI has a positive association with carbon emissions. The empirical findings provide new insights for policymakers to regulate PPP investment in the energy sector for the improvement of environmental quality in Brazil. Graphical abstract

Recent developments in the nanotechnology field have created opportunities to design new biomaterials for Staphylococcus aureus biofilm eradication. These biomaterials including disinfectant-loaded nanoparticles could overcome the limitations of conventional disinfectants. The objective of this study was to assess the biocidal activity of five commercial disinfectants (DC&R®, VirkonS®, TH4++, Tek-Trol, and peracetic acid) alone and as with silver and copper nanocomposites on S. aureus biofilm at different concentrations and exposure times. Consequently, 227 samples were collected from two broiler farms, two-layer farms, and three abattoirs at El-Dakahlia Province, Egypt, during summer 2018. The samples were collected from birds as well as the surrounding environment. S. aureus strains were isolated and biofilm producers were phenotypically evaluated by Congo red agar (CRA) test. Besides, 4 biofilm-associated genes including bap, fnbA, cna, and ebps were genotypically detected by PCR technology. Out of 227 collected samples, 141 (62.1%) strains were identified as S. aureus, while 127 strains (90.1%) were S. aureus biofilm producers for all examined samples except for hand swabs of abattoir workers. The prevalence of fnbA and bap genes was 79.5% (101/127) and 20.5% (26/127), respectively but, no strains harbored cna or ebps genes. Tested nanocomposites were prepared using an aqueous solution of metal salts such as copper sulfate and silver nitrate and added to the same amount of disinfectant solution. The obtained nanocomposites were characterized by transmission electron microscopy (TEM) and zeta potential which showed spherical and elongated particles and with a surface charge of disinfectants—silver and copper nanocomposites—of 2.92 and 3.43 mV, respectively. Complete eradication of S. aureus biofilm was observed after treatment with disinfectants loaded onto silver (AgNPs) and copper (CuNPs) nanoparticles in varying concentrations as well as at different exposure times in comparing to disinfectants alone. Our results exhibited the potential applications of disinfectant nanocomposites in complete eradication of S. aureus biofilm in farms and abattoirs without developing of disinfectant resistant bacteria.

As a common environmental problem in China, trace metal accumulation and contamination in soils of greenhouse vegetable production (GVP) may pose significant health risk via oral ingestion, inhalation, and dermal contact to vegetable farmers and children playing in greenhouse fields. Thus, bioaccessibility and health risk of Cr, Ni, Cu, Zn, Cd, and Pb in GVP soils collected from 13 GVP farms or bases near industrial areas of the Yangtze River Delta, China, were investigated as a case study. The results suggested that both GVP and industrial discharges contributed a lot to accumulation or contamination especially of Zn and Cd in soil, which subsequently increased their bioaccessible concentrations. In addition, soil acidification caused by GVP also increased bioaccessible Cr and Ni concentrations in soil of the Anthrosols study area. However, the health risk assessment of metals in GVP soil through inhalation and oral ingestion considering metal bioaccessibility suggested no non-carcinogenic and carcinogenic risks to both farmers and children. In contrast, there was potential carcinogenic risk within acceptable level posed by Cr in GVP soil through dermal contact to farmers and children. This indicates that both GVP and industrial activities had limited effect on health risk of trace metals in GVP soil via ingestion, inhalation, and dermal contact. However, the carcinogenic risk posed by Cr, which mainly originated from natural sources, still cannot be negligible. Overall, the results will provide valuable information for decision-makers to develop reasonable strategies and guidelines for risk management of trace metals in GVP soil.

Once released into natural water, the environmental behavior and fate of C₆₀ could inevitably been affected by humic acid (HA), sunlight, and hydrodynamic conditions. However, the combined effects of these factors are not so clear. Therefore, in the present study, effects of HA, sunlight, and agitation intensity on generation and properties of aqu/nC₆₀ were investigated. The results indicated that HA could increase the concentration of aqu/nC₆₀ mainly through the steric hindrance effect. The higher agitation intensity led to higher concentrations of aqu/nC₆₀ and more efficient steric stabilization was formed by HA. Sunlight irradiation promoted the surface oxidization and consequently enhanced the dispersion of C₆₀. The relative order of the influence on the UV/vis concentration was sunlight > agitation intensity > HA. In addition, HA might not always enhance the dispersion of aqu/nC₆₀ due to light screening/ROS scavenging, over-coating, or chain-like bridging mechanism. Therefore, evaluating the environmental behavior and fate of C₆₀ should take these factors into account together.

Preparation of Ce₂(MoO₄)₃ nanoparticles is reported via the microemulsion method by using two different surfactants, i.e., cationic surfactant, cetyltrimethylammonium bromide (CTAB), and nonionic surfactant, Triton X-100. The water pools produced in the microemulsion systems behave as nanoreactors for reaction of the cerium (3+) and molybdate ions to produce Ce₂(MoO₄)₃ nanoparticles. The structure and morphology of the products were characterized by using Fourier-transform infrared (FT-IR) spectroscopy, energy-dispersive X-ray analysis (EDX), UV-Vis spectroscopy, X-ray diffraction (XRD), thermogravimetric analysis (TGA-DTA), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The prepared Ce₂(MoO₄)₃ nanoparticles were successfully utilized as photocatalysts to remove crystal violet from aqueous solution in which the maximum percentage of dye degradation was about 89% after 5 h under the visible light irradiation. Also, kinetic study of the photocatalytic degradation revealed that pseudo-second order model is the best one for describing kinetic of the reaction.

A useful growth process model for Ulva prolifera with light limitation considering the nutrient effect was proposed to better understand the development of macroalgae bloom. The interrelationship between light and nutrient limitation was demonstrated to obtain the mechanism. As a case study, thresholds of light and nutrients for different stages of Ulva prolifera growth were estimated using the proposed model. Limits of light intensity, nitrate, and phosphate concentration on the initial growth were found to be 40.0 W m⁻², 6.5 μmol L⁻¹, and 0.27 μmol L⁻¹, respectively. The minimal light intensity for initial growth was found to increase monotonously with decrease in the nutrient concentration. It was also observed that the minimal light intensity for growth increases as the density of Ulva prolifera increases and the nutrient concentration decreases. Similarly, the minimal nutrient concentration for initial growth increases monotonously with decrease in the light intensity. In addition, the minimal nutrient concentration for growth increases with increase in the density of Ulva prolifera and decrease in the light intensity. It was demonstrated that the phosphate limitation on the initial growth of Ulva prolifera seedling can occur in most coastal waters of the southern Yellow Sea and a tendency of approaching the phosphate limitation on the growth of the floating thalli of Ulva prolifera exists. Evidence was provided to support the argument that the macroalgae thalli from aquaculture rafts, rather than that from seedlings or spores, can contribute to the original biomass of the floating green Ulva prolifera in the southern Yellow Sea. The model presented in this study can provide new insights into the interrelationship between the light and nutrient limitation, as well as into the growth mechanism of floating seaweeds. It can also provide a more accurate prediction of seaweed growth in light- and nutrient-limited environments.

Flax (Linum usitatissimum L.), one of the oldest cultivated crops, continues to be widely grown for oil, fiber and food. Furthermore, the plants show a metal tolerance dependent on species so is ideal for research. Present study was conducted to find out the influence of copper (Cu) toxicity on plant biomass, growth, chlorophyll content, malondialdehyde (MDA) contents, proline production, antioxidative enzymes and metal up taken by L. usitatissimum from the soil grown under mixing of Cu-contaminated soil with natural soil by 0:1 (control), 1:0, 1:1, 1:2 and 1:4. Results revealed that, high concentration of Cu in the soil affected plant growth and development by reducing plant height, plant diameter and plant fresh and dry biomass and chlorophyll contents in the leaves compared with the control. Furthermore, Cu in excess causes generation of reactive oxygen species (ROS) such as superoxide radical (O–) and hydroxyl radicals (OH), which is manifested by high malondialdehyde (MDA) and proline contents also. The increasing activities of superoxidase dismutase (SOD) and peroxidase (POD) in the roots and leaves of L. usitatissimum are involved in the scavenging of ROS. Results also showed that L. usitatissimum also has capability to revoke large amount of Cu from the contaminated soil. As Cu concentration in the soil increases, the final uptake of Cu concentration by L. usitatissimum increases. Furthermore, the soil chemical parameters (pH, electrical conductivity and cation exchange capacity) were increasing to highest levels as the ratio of Cu concentration to the natural soil increases. Thus, Cu-contaminated soil is amended with the addition of natural soil significantly reduced plant growth and biomass, while L. usitatissimum is able to revoke large amount of Cu from the soil and could be grown as flaxseed and a potential candidate for phytoremediation of Cu.