The present work encompasses the production of biodiesel from an inexpensive waste, viz., used rice bran oil (URBO) through concurrent esterification and transesterification reactions employing the prepared waste duck bone (WDB)-derived natural hydroxyapatite (NAHAp) supported vanadium impregnated solid catalyst (VNAHAp). The optimal VNAHAp catalyst possessed 92.23 m²/g surface area which was much superior to 61.46 m²/g of the V-catalyst (VCHAp) prepared using commercially available hydroxyapatite (CHAp). The optimal (Box–Behnken design) concurrent trans/esterification reaction conditions for biodiesel (FAME) production from URBO and methanol were 5 wt.% catalyst concentration, 8:1 methanol/URBO mole ratio, and 35 wt% NH₄VO₃ loaded VNAHAp (35VNAHAp) catalyst that resulted in 99.05% FAME yield deploying a low-energy infrared radiator assisted batch reactor (LIRABR) which ensured significantly high FAME yield at milder temperature (60°C) and in shorter reaction time (30 min) compared to a conventionally heated batch reactor. The product biodiesel and its blend with commercial diesel conformed to ASTM D7467-10 specifications. The life cycle assessment (LCA) of the entire process advocated superior sustainability of the biodiesel production using 35VNAHAp catalyst in the LIRABR compared to their conventional counterparts. Valorization of two potential wastes, viz., URBO and WDB, under milder process conditions involving LIRABR and 35VNAHAp resulted in lower environmental impacts, thus rendering a sustainable biodiesel production process towards a greener earth.

Carbon storage in terrestrial ecosystems, which is the basis of the global carbon cycle, reflects the changes in the environment due to anthropogenic impacts. Rapid and effective assessment of the impact of urban expansion on carbon reserves is vital for the sustainable development of urban ecosystems. Previous studies on future scenario simulations lacked research regarding the driving factors of changes in carbon storages within urban expansion, and the economic value accounting for changes in carbon storages. Therefore, this study examined Wuhan, China, and explored the latent effects of urban expansion on terrestrial carbon storage by combining the Integrated Valuation of Ecosystem Services and Trade-offs (InVEST) and Patch-generating Land Use Simulation (PLUS) model. Based on different socioeconomic strategies, we developed three future scenarios, including Baseline Scenario (BS), Cropland Protection Scenario (CP) and Ecological protection Scenario (EP), to predict the urban built-up land use change from 2015 to 2035 in Wuhan and discussed the carbon storage impacts of urban expansion. The result shows that (1) Wuhan’s urban built-up land area expanded 2.67 times between 1980 and 2015, which is approximately 685.17 km² and is expected to continuously expand to 1349–1945.01 km² by 2035. (2) Urban expansion in Wuhan has caused carbon storage loss by 5.12 × 10⁶ t during 1980–2015 and will lead to carbon storage loss by 6.15 × 10⁶ t, 4.7 × 10⁶ t and 4.05 × 10⁶ t under BS, CP, and EP scenarios from 2015 to 2035, accounting for 85.42%, 81.74%, and 78.79% of the total carbon loss, respectively. (3) The occupation of cropland by urban expansion is closely related to the road system expansion, which is the main driver of carbon storage reduction from 2015 to 2035. (4) We expect that by 2035, the districts facing carbon loss caused by the growth of urban built-up land will expand outward around secondary roads, and the scale of outward expansion under various scenarios will be ranked as BS > CP > EP. In combination, the InVEST and the PLUS model can assess the impact of urban expansion on carbon storage more efficiently and is conducive to carrying out urban planning and promoting a dynamic balance between urban economic development and human well-being.

The objective of the current study is to investigate the natural radioactivity of some building materials, the resulting long-term external and internal effective dose equivalents (EEDE and IEDE) analysis followed by indoor radon measurements, and the assessment of some radiological risk indicators associated with radon exposure. A total of 37 samples of building materials were analyzed with a sodium iodide detector (NaI (Tl)), and the computer code RESRAD-BUILD was used for the analysis of the EEDE and IEDE of the structural elements of the houses (walls and floor). For indoor radon measurements, 140 houses were selected, and in each of them was placed 01 RADTRAK dosimeter. Inhalation dose, total dose, and some radiological risk indicators were calculated. The specific activities of ²²⁶Ra, ²³²Th, and ⁴⁰K for the overall sampled building materials were found to vary between 10 ± 2–52 ± 7, 10 ± 1–95 ± 10, and 31 ± 1–673 ± 20 Bq kg⁻¹, respectively. The dwelling types with bare brick walls, cement mortar plastered walls, and concrete floors show EEDE and IEDE values well below the recommended limits. The corresponding dwelling type contributions to the measured average indoor radon concentration (42 ± 12 Bq m⁻³) are 22%, 13%, and 16%, respectively. Inhalation dose resulting from the measured indoor radon concentrations varies from 0.35 to 3.24 mSv y⁻¹ with a mean value of 0.96 ± 0.55 mSv y⁻¹, which represents about 65% of the total dose simulated (1.49 ± 0.88 mSv y⁻¹) by the RESRAD-BUILD code. The overall analysis of indoor radon-related radiological risk indicators shows low levels of risk relative to permissible limits.

Endocrine-disrupting chemicals (EDCs) can be a major risk factor for noncommunicable illnesses, especially when children are exposed to them. The purpose of this study was to assess the urine concentrations of triclosan (TCS), methyl triclosan (MTCS), triclocarban (TCC), and 2,4-dichlorophenol (2,4-DCP) and its association with anthropometric and demographic parameters in children and adolescents aged 6–18 living in Kerman, Iran, in 2020. A GC/MS instrument was used to measure the concentrations of the analytes. TCS, MTCS, TCC, and 2,4-DCP geometric mean concentrations (µg/L) were 4.32 ± 2.08, 1.73 ± 0.88, 4.66 ± 10.25, and 0.19 ± 0.14, respectively. TCS, MTCS, TCC, and 2,4-DCP were shown to have a positive and significant association with BMI z-score and BMI (p-value < 0.01). TCS and MTCS have a positive, strong, and substantial association (p-value < 0.01, r = 0.74). There was no significant association between the waist circumference (WC) and the analytes studied. In addition, there was a close association between analyte concentration and demographic parameters (smoking, education, income, etc.) overall. In Kerman, Iran, the current study was the first to look into the association between TCS, MTCS, TCC, and 2,4-DCP analytes and anthropometric and demographic data. The levels of urinary TCS, MTCS, TCC, 2,4-DCP, and anthropometric parameters in children and adolescents are shown to have a significant association in this study. However, because the current study is cross-sectional and it is uncertain if a single experiment accurately reflects long-term exposure to these analytes, more research is needed to determine the impact of these analyses on the health of children and adolescents.

Little is known about associations between depression and serum heavy metal levels, dietary vitamin intakes. Thus, we sought to determine the nature of these associations and to predict risks of depression using marginal effects. A data set of 16,371 individuals aged ≥10 years that participated in Korea National Health and Nutrition Examination Surveys (KNHANES) conducted from 2009 to 2017 (excluding 2014 and 2015) was used to obtain information on sociodemographics, family histories, lifestyles, serum heavy metal levels, food intakes, and depression. Serum cadmium (Cd) and lead (Pb) levels were analyzed by graphite furnace atomic absorption spectrometry and mercury (Hg) levels using a mercury analyzer. Daily vitamin intakes were calculated by 24-h dietary recall. The results obtained showed that females are at higher risk of depression than males. A doubling of serum Cd was associated with a 21% increase in depression (AOR 1.21, 95% CI: 1.07–1.37, p = 0.002), whereas twofold increases in daily vitamin B1, B3 and vitamin A intakes reduced the risk of depression by 17% (0.83, 95% CI: 0.73–0.95, p = 0.005), 20% (0.80, 95% CI: 0.70–0.91, p = 0.001), and 8% (0.92, 95% CI: 0.85–0.99, p = 0.020), respectively. Interactions between heavy metals, vitamin intakes, and sex did not influence the risk of depression. The result shows that increased daily dietary vitamin intake might protect the public against depression. Further studies are needed to reduce the risks posed by heavy metals and to determine more comprehensively the effects of daily dietary vitamin intake on depression.

Dye wastewater has raised a prevalent environmental concern due to its ability to prevent the penetration of sunlight through water, thereby causing a disruption to the aquatic ecosystem. Carbon quantum dots (CQDs) are particularly sought after for their highly tailorable photoelectrochemical and optical properties. Simultaneously, graphitic carbon nitride (g-C₃N₄) has gained widespread attention due to its suitable band gap energy as well as excellent chemical and thermal stabilities. Herein, a novel boron-doped CQD (BCQD)-hybridized g-C₃N₄ homojunction (CN) nanocomposite was fabricated via a facile hydrothermal route. The optimal photocatalyst sample, 1-BCQD/CN (with a 1:3 mass ratio of boron to CQD) accomplished a Rhodamine B (RhB, 10 mg/L) degradation efficiency of 96.8% within 4 h under an 18 W LED light irradiation. The kinetic rate constant of 1.39 × 10–² min⁻¹ achieved by the optimum sample was found to be 3.6- and 2.8-folds higher than that of pristine CN and un-doped CQD/CN, respectively. The surface morphology, crystalline structure, chemical composition and optical properties of photocatalyst samples were characterized via TEM, FESEM-EDX, XRD, FTIR, UV–Vis DRS and FL spectrometer. Based on the scavenging tests, it was revealed that the photogenerated holes (h⁺), superoxide anions (∙O₂–) and hydroxyl radicals (∙OH) were the primary reactive species responsible for the photodegradation process. Overall, the highly efficient 1-BCQD/CN composite with excellent photocatalytic activity could provide a cost-effective and robust means to address the increasing concerns over global environmental pollution.

Exposure to lead among children, as well as adults, is a major global health issue. With diverse routes of exposure (e.g., food, air, and water) either environmentally or occupationally, lead among children can cause mild, moderate, to severe health complications in the later stages of life. The average blood lead level reported by CDC in 2021 is 3.5 µg/dL, and the level of blood lead toxicity is ≥ 10 μg/dL. In this study, we planned to systematically analyze the association between blood lead levels (BLLs) (≥ 10 μg/dL and < 10 μg/dL) and the risk of anemia (hemoglobin level < 11 g/dL) among Indian children aged between ≥ 1 and ≤ 18 years. An online literature search of 5 databases, PubMed, Ovid, EMBASE, Web of Science, and Google Scholar was accomplished with a search updated until 8ᵗʰ March 2021. Study designs included cohort, cross-sectional, and case–control studies that have evaluated the association of lead toxicity or exposure with anemia (Hb < 11 g/dL) reported in urban and/or rural Indian children. Meta-analysis was performed among a total of 864 children from 4 cross-sectional studies. The association between lead toxicity (BLLs ≥ 10 μg/dL) and the risk of being anemic was not statistically significant (RR = 1.15 (95% CI: 0.86–1.55, I² = 77%). The risks of bias in all included studies were low according to the Newcastle Ottawa Scale. Increased blood lead levels did not appear to be the major contributor to anemia in Indian Children. We need to focus primarily on improving the nutritional quality, fortified food supplements, and a balanced diet for children to reduce the anemia burden in India. Lead toxicity should be sought as an etiological factor only in areas of high environmental risk factors which were leaded paints, leaded batteries, a house near major road/traffic areas, and pesticide exposure.

Along with the exponential demand for energy and pollution-free-environment, layered double hydroxides (LDHs) have gained extensive explorations because of their diverse nanostructures and tunable elemental compositions. However, the applications of LDHs are hindered by their poor activity, sluggish mass transfer, and aggregation. LDHs functionalized by carbonaceous materials (CMs) (LDH-CM) are expected to overcome the above disadvantages and even generate more excellent performance. This review first analyzes the research evolvement of LDH-CM composites during the past 25 years. Next, the advantages of LDH-CM composites are highlighted, such as morphology optimization, high electrical conductivity, more stable, good heat, and mass transfer performance. Following the synthetic strategies, including chemical assembly of LDHs and CMs, direct growth of LDH on CMs (two-step nucleation and growth and surface-confined growth) and direct CM formation on LDHs are fully discussed. Then, the recent progress achieved in LDH-CM composites for the application of energy storage and environmental protection is summarized in detail. In particular, the review illustrates the reasons why these constructing strategies can improve the performance of LDH-CM composites. Finally, challenges and future research prospects of LDH-CM composites are highlighted.

The post-transition semiconducting material of pure zinc sulfide (ZnS) and various concentrations of aluminum (Al) (2.5 wt%, 5.0% wt, 7.5 wt%, and 10% calcined at 200 °C) doped ZnS nanoparticles (NPs) were synthesized by sol-gel procedure. The crystal-like nature and phase structure of the product were examined by powder XRD analysis. This analysis shows that the pure ZnS nanoparticle does not form any secondary phase. The functional group of synthesized materials was analyzed by FTIR examination. The energy gap of the materials is calculated using electro-optic analysis and the Kubelka-Munk equation varies from 3.04 nm to 3.63 nm. The photoluminescence studies show the wide emissions (blue to green) for pure ZnS and Al-doped ZnS nanomaterials. The SEM images show the spherical structure and the agglomerated nanostructures. The presence of Zn, S, and Al are confirmed by EDAX spectra. From HR-TEM studies, pure ZnS and Al-doped ZnS nanoparticles exhibit uniform particle sizes. The rate of degradation was observed using MB dye. MB dye has maximum wavelength (λₘₐₓ) of 664 nm. The dye degradation efficiency was improved as the dye ratio increased. Photocatalytic activities studies show the intensity of photocatalytic activities decreased for the maximum time interval. Doping of Al in ZnS boosts the photocatalytic activity. Hence, Al-doped ZnS appears to be better decomposing MB dye when exposed to visible light.

Studies have shown that exposure to dichlorophenols (DCPs) and their precursors might have potential neurotoxicity, which may be related to low cognitive function, but there are few large-scale, representative population data to explore the association between DCP exposure and cognitive function. We aimed to examine the relationship between urinary DCPs and cognitive function in the US older people. A total of 952 participants ≥ 60 years old from the National Health and Nutrition Examination Survey (NHANES) in two cycles (2011–2014) were enrolled. The Consortium to Establish a Registry for Alzheimer’s disease Word Learning subtest (CERAD W-L), the Animal Fluency test (AFT), and the Digit Symbol Substitution test (DSST) were used to assess cognition. Multivariate logistic regression and restricted cubic spline (RCS) were used to evaluate the relationship between DCP exposure and cognitive function. A positive association between 2,5-DCP and the risk of bad performance of DSST was observed (P for trend = 0.024) after adjusting for the covariates. Compared to the lowest quartile, OR of DSST for the highest quartile of 2,5-DCP was 1.72 (95%CI:1.03–2.87, P = 0.039). There were no significant associations between DCPs and the other tests. The RCS plot showed an inverted J-shaped relationship between 2,5-DCP, 2,4-DCP, and the DSST score. The inflection points for the curves were found at 1.531 μg/L and 0.230 μg/L, respectively. On the right side of the inflection points, the DSST score dropped sharply. In subgroup analysis, those under 70 years old, smokers, and alcohol drinkers had a higher risk of bad performance in DSST when exposed to 2,5-DCP. The higher concentration of urinary DCPs is associated with a lower score of DSST in the US older people.