Due to the negative health impacts, significant efforts have been directed towards investigating ultrafine particle (UFP) exposure in various indoor environments. As children spend approximately one third of their time in schools, educatory environments deserve particular attention; however, majority of past research has focused on UFP assessment in classrooms. Thus, this work aims to expand the characterization of UFP in primary schools by considering different indoor and outdoor school microenvironments and estimating inhalation doses for the respective students (6–11yrs old). Real-time UFP measurements were daily conducted (9:00–17:30) in 20 primary schools in Oporto (January–April 2014; October–February 2015) in classrooms, canteens, gyms, libraries, and concurrently outdoors. Overall, UFP concentrations showed large temporal and spatial variations. For classrooms (n = 73), median UFP (1.56 × 10³–16.8 × 10³ # cm⁻³) were lower than the corresponding levels in ambient air of schools (1.79 × 10³–24.1 × 10³ # cm⁻³). Outdoor emissions contributed to indoor UFP (indoor-to-outdoor ratios I/O of 0.0.30–0.85), but ventilation, room characteristics and its occupancy were identified as important parameters contributing to overall indoor UFP levels. Considering specific indoor school microenvironments, canteens were the microenvironment with the highest UFP levels (5.47 × 10³–36.4 × 10³ # cm⁻³), cooking conducted directly on school grounds resulted in significantly elevated UFP in the respective classrooms (p < 0.05); the lowest UFP were found in libraries (4.45 × 10³–8.50 × 10³ # cm⁻³) mostly due to the limited occupancies. Although students spend majority of their school time in classrooms (66–71%), classroom exposure was not consistently the predominant contributor to school total UFP inhalation dose (29–75%). Outdoor exposure contributed 23–70% of school dose (depending on UFP levels in ambient levels and/or conducted activities) whereas short periods of lunch break accounted for 8–40%. Therefore, when evaluating UFP exposure in educatory settings other microenvironments beyond classrooms should be an integral part of the study.

In this study, graphene aerogel (GA) was successfully prepared through a simple hydrothermal method. The resulting GA exhibited a porous network structure with a large specific surface area (350.8 m²/g), ultra-light mass and easy separation from water. The pHIEP value of the GA was estimated to be 3.5. The adsorption process and the factors that affect adsorption capacity were studied. The adsorption could be conducted in a wide pH range from 2.0 to 7.0. The maximum adsorption capacity of GA towards U(VI) at pH 4.0 and T = 298 K was 238.67 mg/g calculated from the Langmuir model. The GA had greatly rapid adsorption property for the removal of U(VI) at pH 4.0. Kinetic data showed good correlation with pseudo-second-order equation. Fourier transform infrared spectroscopy and X-ray photoelectron spectrometry characterizations showed that GA adsorbed U(VI) through chemical interaction by oxygen-containing and nitrogen-containing groups functional groups. The results show that GA has excellent application potential as an adsorbent material for removing U(VI) from aqueous solution.

Hydroxymethylfurfural (HMF) is a plant-based chemical building block that could potentially substitute petroleum-based equivalents, yet ecotoxicological data of this compound is currently limited. In this study, the effects of HMF on the reproduction and survival of Daphnia magna were assessed through validated ecotoxicological tests. The mechanism of toxicity was determined by analysis of transcriptomic responses induced by exposure to different concentrations of HMF using RNA sequencing. HMF exerted toxicity to D. magna with an EC₅₀ for effects on reproduction of 17.2 mg/l. HMF exposure affected molecular pathways including sugar and polysaccharide metabolism, lipid metabolism, general stress metabolism and red blood cell metabolism, although most molecular pathways affected by HMF exposure were dose specific. Hemoglobin genes, however, responded in a sensitive and dose-related manner. No induction of genes involved in the xenobiotic metabolism or oxidative stress metabolism pathway could be observed, which contrasted earlier observations on transcriptional responses of the terrestrial model Folsomia candida exposed to the same compound in a similar dose. We found 4189 orthologue genes between D. magna and F. candida, yet only twenty-one genes of those orthologues were co-regulated in both species. The contrasting transcriptional responses to the same compound exposed at a similar dose between D. magna and F. candida indicates limited overlap in stress responses among soil and aquatic invertebrates. The dose-related expression of hemoglobin provides further support for using hemoglobin expression as a biomarker for general stress responses in daphnids.

Road traffic is one of the major sources of atmospheric particles in urban areas. Modelling the contribution of this source to urban pollution requires reliable estimates of emission factors possibly resolved in size. In this work, size-resolved particle emission factors (EFs) of the mixed vehicle fleet were measured in the urban area of Lecce (south-eastern Italy). The approach used is based on vertical fluxes measured with eddy-covariance, counting of vehicles, and estimation of footprints. Results show that the average EF in number (range 0.009–3 μm) was 2.2*10¹⁴ #/Veh km, being dominated by ultrafine particles (Dₚ < 0.25 μm) due to exhaust emissions. EF number size distribution decreases with particle size. A reduction of more than four orders of magnitude was observed at Dₚ ≅ 0.9 μm. EF mass size distribution reaches a maximum around Dₚ ≅ 0.3 μm then decreases until Dₚ ≅ 0.9 μm. For larger particles EF in mass increases for the influence of non-exhaust emissions. Average emission factor of PM₁ was 56 mg/Veh Km and that of PM₂.₅ was 63 mg/Veh Km. A comparison of measurements taken in 2010 and 2015 in the same area shows a decreasing trend of the average total EF in number of about 56%, likely as a consequence of the increased use of new generation vehicles following more restrictive limits for particle emissions.

Recently, ground ozone has become one major airborne pollutant and the frequency of ozone-induced pollution episodes has increased rapidly across China. However, due to the lack of long-term observation data, relevant research on the characteristics and influencing factors of urban ozone concentrations remains limited. Based on ground ozone observation data during 2006–2016, we quantified the causality influence of individual meteorological factors on ozone concentrations in Beijing using a convergent cross mapping (CCM) method. The result indicated that the influence of each meteorological factor on ozone concentrations varied significantly across seasons and years. At the inter-annual scale, all-year meteorological influences on ozone concentrations were much more stable than seasonal meteorological influences. At the seasonal scale, meteorological influences on ozone concentrations were stronger in spring and autumn. Amongst multiple individual factors, temperature was the key meteorological influencing factor for ozone concentrations in all seasons except winter, when wind, humidity and SSD exerted major influences on ozone concentrations. In addition to temperature, air pressure was another meteorological factor that exerted strong influences on ozone concentrations. At both the inter-annual and seasonal scale, the influence of temperature and humidity on ozone concentrations was generally stable whilst that of other factors experienced large variations. Different from PM2.5, meteorological influences on ozone concentrations were relatively weak in summer, when ozone concentrations were the highest in Beijing. Given the generally stable meteorological influences on ozone concentrations and human-induced emissions of VOCs and NOx across seasons, warming induced notable increase in summertime biogenic emissions of VOCs and NOx can be a major driver for the increasing ozone pollution episodes. This research provides useful references for understanding long-term meteorological influences on ozone concentrations in mega cities in China.

The Talvivaara/Terrafame multi-metal mining company is Europe’s largest nickel open cast mine, it is also known for the largest wastewater leakage in the Finnish mining history and a series of other accidents. In this paleolimnological study, influences of a recently constructed treated waste water discharge pipeline into Lake Nuasjärvi were investigated by analyzing past (pre-disturbance) and present community compositions of key aquatic organism groups, including diatoms, Cladocera and Chironomidae, along spatial (distance, water depth) gradients. In addition to defining ecological changes and impacts of saline mine waters in the lake, chironomids were used to quantitatively reconstruct bottom water oxygen conditions before and after the pipe installation (in 2015). The diatom and cladoceran communities, which reflect more the open-water habitat, showed only relatively minor changes throughout the lake, but a general decrease in diversity was observed within both groups. Chironomids, which live on substrates, showed more significant changes, including complete faunal turnovers and deteriorated benthic quality, especially at the sites close to the pipe outlet, where also chironomid diversity was almost completely lost. Furthermore, the reconstructed hypolimnetic oxygen values indicated a major oxygen decline and even anoxia at the sites near the pipe outlet. The limnoecological influence of the pipe decreased at sites located counter-flow or behind underwater barriers suggesting that the waste waters currently have location-specific impacts. Our study clearly demonstrates that whereas the upper water layers appear to have generally maintained their previous state, the deep-water layers close to the pipe outlet have lost their ecological integrity. Furthermore, the current hypolimnetic anoxia close to the pipe indicates enhanced lake stratification caused by the salinated mine waters. This study clearly exhibits the need to investigate different water bodies at several trophic levels in a spatiotemporal context to be able to reliably assess limnoecological impacts of mining.

The occurrence and distribution of 168 pharmaceutically active compounds (PhACs) in the surface seawater of Jiaozhou Bay (JZB) were investigated using ultra-high-performance liquid chromatography in tandem with a triple-quadrupole mass spectrometer equipped with an electrospray ionization source (UHPLC-ESI-MS-MS). Thirty-six compounds were detected, and 17 of these compounds were first detected in seawater, including sulfabenzamide, sulphacetamide, cephalonium, desacetyl-cefotaxime, cefminox, cefotaxime, cephradine, cefazolin, carprofen, nabumetone, glibenclamide, glimepiride, glipizide, prednisone, fluoromethalone, diazepam and amantadine. The total concentration of PhACs in the surface seawater ranged from 23.6 ng/L to 217 ng/L. The compounds found at the highest mean concentrations included amantadine (24.7 ng/L), lincomycin (8.55 ng/L), carprofen (8.30 ng/L), and tetracycline (7.48 ng/L). The PhAC concentration was higher in the inner bay than in the outside of the bay. In the inner bay, the eastern district showed higher concentrations of PhACs than the western district. Input from the Licun River may be the primary source of pollution. A statistically significant positive correlation was observed between nutrients and PhACs in seawater. Phosphate can be used to indicate the distribution of PhACs in JZB. Based on the individual risk quotient (RQ) values, lincomycin and ofloxacin posed high risks to the relevant aquatic organisms in JZB, especially in the eastern parts. Regular monitoring is required to evaluate the levels of PhACs as they are constantly released into JZB.

Hexabromocyclododecanes (HBCDDs) are common chemical additives in expanded polystyrene foam (EPS). To evaluate the bioaccumulation potential of endogenous HBCDDs in EPS microparticles by earthworms, two ecologically different species of earthworms (Eisenia fetida and Metaphire guillelmi) were exposed to soil added with EPS microparticles of different particle sizes (EPS2000, 830–2000 μm and EPS830, <830 μm). To clarify the accumulation mechanisms, leaching experiments using EPS microparticles in different solutions were conducted. After exposure to EPS microparticles-amended soils (S-EPS) for 28 d, the total concentrations of HBCDDs reached 307–371 ng g−1 dw in E. fetida and 90–133 ng g−1 dw in M. guillelmi, which were higher than those in earthworms exposed to the soil that was artificially contaminated with a similar level of HBCDDs directly (ACS). The accumulation of HBCDDs in earthworms was significantly influenced by EPS microparticles' size and earthworms' species. The total concentrations of HBCDDs in earthworms' cast were significantly higher than the theoretical concentration of HBCDDs in S-EPS, which suggested that EPS microparticles can be ingested by earthworms. The release rate of HBCDDs from EPS5000 (2000–5000 μm) into water-based solutions (<1%) after a 3.5-h incubation was far lower than that into earthworm digestive fluid (7%). These results illustrated that the ingestion of EPS microparticles and consequent solubilization of HBCDDs by digestive fluid play an important role in the accumulation of HBCDDs contained in EPS microparticles in earthworms. After a 28-d incubation with the soil solution, 4.9% of the HBCDDs was accumulatively leached from the EPS5000, which indicated that HBCDDs can be released from EPS microparticles to soil environment, and then accumulated by earthworms. Moreover, similar to those exposed to ACS, the diastereoisomer- and enantiomer-specific accumulation of HBCDDs in earthworms occurred when exposed to S-EPS. This study provides more evidence for the risk of microplastics to the soil ecosystem.

The ecological risk assessment (ERA) of polycyclic aromatic hydrocarbons (PAHs) is imperative due to their ubiquity and biological effects in aquatic organisms. We evaluated the seasonal levels and ERA of 16 priority PAHs in surface water, sediment and fish from four (4) anthropogenic-impacted zones of the Lagos lagoon, Nigeria. PAHs were analysed using GC-FID and standard guidelines were utilized for the ERA. Also, we developed a sediment to water-PAHs ratio and ranking of PAHs for the ERA. The dominant fish species were Sarotherodon melanotheron (Black-Jawed Tilapia), Gerres melanopterus (Gerres), Liza falcipinnis (Sicklefin Mullet) and Pseudotolithus elongatus (Bobo Croaker) at Ilaje, Iddo, Atlas cove and Apapa zones respectively. The range of sum PAHs was 195–1006 μg L⁻¹, 302–1290 μg kg⁻¹ and 8.80–26.1 μg kg⁻¹ in surface water, sediment and fish species respectively. Naphthalene was dominant in the surface water and sediment samples while 3-ring to 4-ring PAHs were predominant in fish species across the zones and seasons. The sediment to water-PAHs ratio was greater than 1 for sum PAHs and significantly higher (p < 0.05) in the wet season for specific PAHs across the zones and seasons. On the basis of the sediment PAHs level, Apapa zone was highly polluted with frequent biological effects while the other zones were moderately polluted with occasional biological effects across the zones and seasons. Fish species from all zones were minimally contaminated in both seasons except S. melanotheron which was not contaminated. The specific PAHs identified as ecological risk factors in the lagoon and ranking based on 50–75% recurrence in the ERA were; naphthalene, acenaphthene > acenaphthylene, fluorene, pyrene and benzo[a]anthracene. We recommend that the specific PAHs identified should form the basis for the establishment of environmental quality standards for individual PAHs in coastal waters based on the UN sustainable development goal 14 (life below water).

Sediment records are widely used to infer impact of atmospheric metal deposition in alpine lakes, however, the legacy effect and catchment erosion of historical pollutants could potentially affect metal influx into lakes. Here, we collect data (including six trace metals and three lithogenic elements) from well-dated sediment cores of seven alpine lakes in southeast Tibet, which is adjacent to southwest China. This area has a documented history of preindustrial pollution. Metals such as cadmium (Cd), zinc (Zn) and arsenic (As) are found at relatively low concentrations until a clear increase is observed after 1950s across lakes. This result is consistent with accelerating atmospheric metal deposition due to socio-economic development in the region. We observe no synchronous trend across lakes in the changes of lead (Pb), copper (Cu) and silver (Ag), which show no significant increase after ∼1950 over the last two centuries in most of the study lakes. The historical trends of ²⁰⁶Pb/²⁰⁷Pb ratio reflect an important source of anthropogenic Pb associated with preindustrial mining and smelting in this study region, suggesting a substantial impact of legacy contamination from ancient mines. Furthermore, the temporal variations in these six anthropogenic metals are largely accounted for by terrigenous elements (e.g. aluminum (Al) and titanium (Ti)) in most of the study lakes, and to a lesser degree by sediment grain sizes and organic matter content, suggesting a significant role of catchment erosion in modulating sediment metal signals. In all, this study highlights the legacy effect of historical pollutants may have enhanced the forcing of catchment erosion in modulating the sediment signals of anthropogenic deposition in southeast Tibet.