This study reports the first evidence of the quantification of two dominant perfluorinated compounds (PFCs), namely perfluorooctanesulfate (PFOS) and perfluorooctannoate (PFOA), in surface sediment samples (0–5cm; n=13) from the Ganges (Hugli) River including Sundarban wetland, India using HPLC–MS/MS. The concentrations of PFOA exhibited a wide range of concentrations from <0.5 to 14.09ng/gdry wt, whereas the concentration of PFOS was always below the detection limit of <0.5ng/g drywt. A consistent enrichment of PFOA was recorded in all the five sites of Sundarban (mean value 11.61±1.86) whereas it was of moderate concentration or below the detection level in the seven sites along with the lower stretch of the Ganges (Hugli) River estuary (mean value 5.96ng/gdry wt±5.36). Wastewater and untreated effluents are likely the major causes of accumulation of PFCs in sediments. The present paper could be used as baseline study to assess future monitoring programs of the ecosystem.

Our current view about the relationship between metals and bacteria in marine sediments might be biased because most studies only use ex situ approaches to quantify metals. The aim of the present research was to compare ex situ and in situ methods of metal measurement (DET and DGT – diffusive equilibration or diffusive gradients in thin-films) and relate the results with two commonly used microbiological variables (bacterial biomass and bacterial diversity as revealed by DGGE). No previous studies have used such in situ approaches in microbial ecology. For biomass and most of the investigated trace metals (Ag, Cd, Sn, Cr, Ni, Cu, Pb, and Al) no significant correlations were found. The exceptions were Fe, Mn, Co, and As which behave like micronutrients. For bacterial diversity, no relevant relationships were found. We conclude that in situ methods are more adapted tools for microbial ecologists but that ex situ approaches are still necessary.

Mercury and PCBs are used by non-governmental organizations and federal agencies to inform seafood safety recommendations. Pollution dynamics suggest recommendations on the national scale may be too large to be accurate. We tested softshell and hardshell blue crab, white and pink shrimp, oysters, clams, spot, and mullet from fishers in each of the three North Carolina fishery districts. We measured mercury using EPA method 7473 and PCBs using a commercially available ELISA kit. Over 97% of samples were below the Environmental Protection Agency levels of concern for both mercury and PCBs. Mercury and PCBs have different spatial dynamics, but both differ significantly by water body, suggesting that seafood safety recommendations should occur by water body instead of at the national scale. This finding supports previous research suggesting that differences in water chemistry, terrestrial influence, and flushing time in a particular water body control the contaminant load in locally resident species.

In recent years, the shipping of environmentally hazardous cargo has increased considerably in the Baltic proper. In this study, a large number of hypothetical oil spills with an idealized, passive tracer are simulated. From the tracer distributions, statistical measures are calculated to optimize the quantity of tracer from a spill that would stay at sea as long as possible. Increased time may permit action to be taken against the spill before the oil reaches environmentally vulnerable coastal zones. The statistical measures are used to calculate maritime routes with maximum probability that an oil spill will stay at sea as long as possible. Under these assumptions, ships should follow routes that are located south of Bornholm instead of the northern routes in use currently. Our results suggest that the location of the optimal maritime routes depends on the season, although interannual variability is too large to identify statistically significant changes.

The residual levels of organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) were determined in surface sediments collected from Candarli Gulf. Total concentrations of OCPs and PCBs in sediments ranged from 10.2 to 57.3 and 2.8 to 205ngg⁻¹dwt, respectively. DDTs in sediments were derived from the aged and weathered agricultural soils in 61% of the sampling stations while 39% of the sites originated from the recent DDT inputs. Their concentrations appeared to be relatively low by global standards and only sediments receiving the impact from the Bakircay River and petrochemical industry approached the sediment quality guidelines for PCBs and DDTs. Based on ERL/ERM guidelines, DDT and PCBs posed ecological risk to the bottom-dwelling consumers.

Marine waters from six sites around Hong Kong with varying levels of sewage pollution were examined for noroviruses (NoVs) by PCR cloning and sequencing of a highly-variable N-terminal region of the VP1 capsid gene, at the ORF1-ORF2 junction of NoV. Phylogenetic analysis of genogroups GI- and GII-specific PCR clones obtained from different marine sites indicated that human NoV GI.1 and GII.4 strains are the most prevalent genotypes circulating in Hong Kong waters. GI- and GII-specific TaqMan-based real-time PCR assays targeting the ORF1-ORF2 junction of NoVs were used to quantify NoV particles in marine water samples in parallel with total Escherichia coli counts which were enumerated on TBX medium. No correlation of any significance between NoV and E. coli counts was observed which highlighted the inadequacy in using E. coli as a fecal indicator to predict the level of NoVs in marine waters to protect public health.

Concentrations of seven metals (Al, Cd, Cu, Fe, Pb, Ni, Zn) were determined in 256 surface sediment samples, collected between May 2006 and November 2009, from 15 stations at the mouth of the Itata River and its adjacent marine zone (central-southern Chile) as part of an environmental monitoring program. The objectives of the work were to: (i) establish baseline metal concentrations in the sediments of the area and (ii) identify tendencies in the spatial and temporal distribution of the metals in these marine sediments. Concentrations were highest in the north zone of the Itata River mouth (stations E2C, E13C) for all the metals and at the stations farthest offshore from the mouth (E4, E6) for Cu, Fe, Pb, and Ni. The ranges in those concentrations were lower than those reported in other studies performed along the Chilean coast and lower than those observed in most other coastal systems around the world. Based on results of the indices used (geoaccumulation index, enrichment factor), the coastal sediments were not measurably elevated above natural levels.

A deep-sea trawl survey of the Northern Gulf of Mexico has documented the abundance and diversity of human-generated litter and natural detrital plant material, from the outer margin of the continental shelf out to the Sigsbee abyssal plain. Plastics were the most frequently encountered type of material. Litter and debris were encountered more frequently in the eastern than in the western GoM. Land-derived plant material was located primarily within the head of the Mississippi Canyon, whereas ocean-derived plant material was spread evenly throughout the NE GoM. Human discards were principally from ships offshore. Some of the material was contained in metal cans that sank to the sea floor, probably in order to conform to international agreements that prohibit disposal of toxic material and plastics. The Mississippi Canyon was a focal point for litter, perhaps due to topography, currents or proximity to shipping lanes.

Aliağa Bay is one of the most important maritime zones of Turkey where shipping activity, shipbreaking industry, steel works and petrochemical complexes exist together. Concentrations of heavy metals and organic carbon in sediment of the Aliağa Bay were investigated to evaluate an environmental risk assessment from metals contamination in 2009–2010. Comparison of the metal concentrations with average shale and Mediterranean background levels revealed that most of the samples from the Aliağa were polluted with Hg, Cd, Pb, Cr, Cu, Zn, Mn and Ni. It was found that Hg, Pb, Cu, Zn and Ni levels in Aliağa Bay exceeded the PEL values. Sediments, contaminated with Pb, Cr, Cu, Zn and Ni were considered as heavily polluted per the SQG.

Simulation models have been widely adopted in fisheries for management strategy evaluation (MSE). However, in catchment management of water quality, MSE is hampered by the complexity of both decision space and the hydrological process models. Empirical models based on monitoring data provide a feasible alternative to process models; they run much faster and, by conditioning on data, they can simulate realistic responses to management actions. Using 10years of water quality indicators from Queensland, Australia, we built an empirical model suitable for rapid MSE that reproduces the water quality variables’ mean and covariance structure, adjusts the expected indicators through local management effects, and propagates effects downstream by capturing inter-site regression relationships. Empirical models enable managers to search the space of possible strategies using rapid assessment. They provide not only realistic responses in water quality indicators but also variability in those indicators, allowing managers to assess strategies in an uncertain world.