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Heavy Metal Pollution of Soil and Crops in Rural Gujarat, Next to an Industrial Area: A Correlation Study النص الكامل
2023
A. Salauddin and C. Sandesh
Heavy metal contamination is one of the significant concerns of environmental pollution. The present study was conducted to find out the correlation between soil and crop/food matrices grown at the exact location for Al, As, Ca, Cd, Cr, Cu, Fe, Hg, K, Mg, Mn, Ni, Na, P, Zn, and Pb elements near the industrial areas of Narol, Changodar, Vatva, Makarpura, Nandesari, and Ankleshwar in Gujarat, India. Soil samples were collected from 64 sampling sites in an industrial area. Twenty of these sites contained crop/food matrices used for the correlation study. The ranges of concentration of Cr (17-74.4 mg.kg-1), Cu (9.6-82.4 mg.kg-1), Ni (10.6-55.9 mg.kg-1), Pb (4.5- 20.7 mg.kg-1), Zn (21.5-112.4 mg.kg-1), and Al (7075-44557.5 mg.kg-1) for Soil and for crop Cr (0.3-0.6 mg.kg-1), Cu (0.3-8.6 mg.kg-1), Zn (1.1-43.5 mg.kg-1), Fe (12.6-69.4 mg.kg-1), and Al (5.8-102.2 mg.kg-1). According to the study, there is a strong correlation between the soil and crop/food matrices at the different locations, like 0.97 for Fe and Ni, 0.94 for Mg, 0.95 for Mn, and 0.55 for Pb and Zn, and very little correlation between K, P, and Ca, while a negative correlation between Al, Cr, Cu, and Na. The DTPA extractable method was used for the elemental analysis, and analysis was done using the ICP-OES instrument following microwave-assisted digestion. The results show that metal contamination transforms from soil to crop/food matrices, which represents a serious concern and requires action to address the metal contamination by industrialization.
اظهر المزيد [+] اقل [-]Adsorption and Kinetic Studies on Sequestering Effect of Porous Biodegradable Biochar Obtained from Pig-Bone on Hexavalent chromium from Aqueous Solution النص الكامل
2023
L. Vidhya, S. Vinodha, S. J. Pradeeba, B. Jeyagowri, V. Nirmaladevi and N. Nithiya
In the current research work, the authors proposed a list of tactics to eliminate Cr (VI) with the help of pig bone biochar. The Cr (VI) was adsorbed in batches onto pig bone biochar to scrutinize the adsorption data. The studies determine the impact of adsorption dose, pH, and concentration. From the results, it was inferred that the optimum pH level was 7 for the removal of metal. The study calculated the adsorption isotherms in terms of affinity and adsorption capacity by leveraging Temkin, Langmuir, and Freundlich equations. According to the reports, the Langmuir model is suitable for the adsorption data, followed by Temkin and Freundlich equations. In this model, rapid adsorption kinetic rates were observed, whereas the equilibrium state was achieved after two hours. There seems to be a perfect collation between the kinetic adsorption data and the pseudo-second-order equation. The researchers determined both Lagergren and Ho’sconstants. When biochar was characterized with SEM (Scanning Electron Microscope), EDX (Energy Dispersive X-ray spectrometer), and FTIR (Fourier Transform Infrared spectrometer), it was revealed that the Cr (VI) ions interacted with the isolated aggregates formed on the biosorbent surface. From the results, it can be understood that the pig bone biochar can be effectively used to eliminate chromium ions from an aqueous solution.
اظهر المزيد [+] اقل [-]Strategic Monitoring of Groundwater Quality Around Olusosun Landfill in Lagos State for Pollution Reduction and Environmental Sustainability النص الكامل
2023
O.J. Oyebode, F.O. Jimoh, S.M. Ajibade, S.A. Afolaluand F.A. Oyebode
As urbanization and population increase in the megacity, there is a need for engineering intervention and strategic monitoring of groundwater around landfills for environmental sustainability, pollution reduction and public health. This study evaluated water’s physical and chemical parameters in wells and boreholes near the Olusosun landfill in Lagos State to determine how they impact groundwater quality. An Atomic Absorption Spectrometer (AAS) was used to evaluate groundwater samples obtained from five locations within the dump site. Some water parameters, such as dissolved oxygen (DO), iron (Fe), lead (Pb), manganese (Mn), and magnesium (Mg), had concentrations that were higher than the WHO, NESREA, and Nigerian Standard for Drinking Water Quality (NSDWQ) standard limits in some sampling sites, with mean concentrations of 0.33 mg.L-1, 0.04 mg.L-1, 0.74 mg.L-1, and 0.74 mg.L-1, respectively. A small amount of lead was identified in the groundwater of the study area. A major source of air and groundwater pollution, the Olusosun landfill has a detrimental impact on the health of those who live there. Solid waste, groundwater interactions, and contaminated migration into the nearby neighbourhood were studied. It was observed that the degradation of waste products in dump sites releases harmful leachate into the groundwater. Even though some heavy metal concentrations in the study area are still within WHO, NESREA, and NSDWQ standard limits, investigations and further monitoring should be conducted regularly to assess the concentrations of heavy metals in groundwater.
اظهر المزيد [+] اقل [-]Topographic Gradient Differentiation and Ecological Function Zoning Based on Ecosystem Services: A Case Study of Fuping County النص الكامل
2023
Ling He, Zhe Du, Jiabo Tian and Shuqi Chen
Scientifically delineating ecological function zones is essential for national territory spatial planning and comprehensive management. In this study, we evaluated five ecosystem services, habitat quality, water yield, carbon sequestration, soil conservation, and food production, in Fuping County, China, and introduced the application of the topographic position index in exploring the topographic gradient effect of each service. We next applied the K-means clustering algorithm to identify the ecosystem services bundles and analyze the dominant type of ecosystem service in these bundles. A particle swarm optimization-support vector machine model was also constructed to identify the boundaries of ecological function zones and complete the ecological function zoning. The results are as follows: (1) In Fuping County, the high-value areas of habitat quality are distributed in the west, north, and southeast; those of soil conservation are in the northwest, northeast, and southwest; those of water yield are in the east and south; those of carbon sequestration are in the west, and those of food production is in the east. (2) The habitat quality first decreases and then increases with an increasing topographic gradient; food production and water yield decline with increasing topographic gradient; carbon sequestration and soil conservation increase with increasing topographic gradient. (3) Four types of ecosystem services bundles were identified. The dominant ecosystem functions of Type I, II, and III bundles are food production and water yield, carbon sequestration, and soil conservation, respectively. Type IV bundles generally have low levels of ecosystem services in the study area. (4) Four ecological function zones were delineated: food production zone, ecological conservation zone, potential restoration zone, and critical restoration zone. The research findings can provide a theoretical and practical basis for formulating and implementing ecological spatial management policies in the Taihang Mountains of China.
اظهر المزيد [+] اقل [-]Nesting Site Preferences of Ratufa indica indica in the Umblebyle Range Forest, Bhadravathi Division, Shimoga, Karnataka النص الكامل
2023
V. Hamsa Rekha and A. Shwetha
Malabar Giant Squirrel (Ratufa indica indica) is one of the four subspecies endemic to India (Abdulali 1952), common to northern and central Western Ghats among species Ratufa indica belonging to Subfamily Ratufinae. The study was designed to analyze the nest tree preferences of animals in the dry deciduous forests of the Umblebyle range, Shimoga, Karnataka (South India) during February, March, and April 2021, surveying 20 transects covering a distance of 47.7 km. Nest tree preferences were assessed by observing 406 dreys (nests) on 385 trees covering an area of 8350.89 ha. The nest trees came from 20 families and 41 species, with 12 tree species in the Family Fabaceae and 84 trees in the Terminalia paniculata having the highest preference. The Squirrels showed the highest preference for deciduous trees over semi-evergreen and evergreen trees. The most preferred tree height and nest height ranged between 11-20m, including 87.53% of nesting trees and 83.89% of nests, respectively. The average nest height was estimated to be 14.73 (±3.311) m, with a minimum and maximum height of 7 m and 28 m, respectively. The difference between average tree height and average nest height was 1.512m.
اظهر المزيد [+] اقل [-]An Inappropriate Rise in NO2 During the COVID-19 Pandemic in the Urban Area of Chhattisgarh, India النص الكامل
2023
A. Zeb, I. U. Khan, S. Tripathi, M. R. Sahu and A. Kumar
The COVID-19 first case was reported in India on January 30, 2020, and in Chhattisgarh on March 19, 2020, and since then a sharp surge has been noticed. The government of India imposed a nationwide lockdown on March 25, 2020, a complete suspension of human activities, viz., industry, construction, transport, academic institutions, etc., which resulted in an improvement in air quality (a decrease in PM2.5 and PM10, alteration in NO2 and an increase in O3). But the rate of cases of COVID-19 has increased sharply, and eventually, under economic pressure, the lockdown was withdrawn on June 1, 2020, which further accelerated the exponential growth of COVID-19 cases. We noticed that in the Chhattisgarh State of India, the alteration in the air quality index during the lockdown period is continuing even after the restoration of anthropogenic activities. Among PM2.5, PM10, NO2, and O3, the behavior of NO2 was found to be different than others; it was found to increase during the lockdown period but further decreased with the resumption of anthropogenic activities. We conclude that the air quality index has an insignificant impact on COVID-19 infection.
اظهر المزيد [+] اقل [-]A Survey on Deep Learning Based Crop Yield Prediction النص الكامل
2023
S. Archana and P. Senthil Kumar
Agriculture is the most important sector and the backbone of a developing country’s economy. Accurate crop yield prediction models can provide decision-making tools for farmers to make better decisions. Crop yield prediction has challenged researchers due to dynamic, noisy, non-stationary, non-linear features and complex data. The factors that influence crop yield are changes in temperature and rainfall, plant disease, pests, fertilizer, and soil quality. The paper discusses the factors affecting crop yield, explores the features utilized, and analysis deep learning methodologies and performance metrics utilized in crop yield prediction.
اظهر المزيد [+] اقل [-]Boron Isotopic Systematics and Its Significance in Natural Processes: An Overview النص الكامل
2023
Tanya Srivastava and Nishchal Wanjari
In recent years, interest in boron has expanded from microscopic to macroscopic levels, and several studies have contributed to understanding the role of boron in earth and natural processes. The boron isotopic composition provides a unique perspective into the crystallization process in granites, pegmatites, and temperature variations. Boron isotopic studies have been used as a tracer to understand geothermal systems, rivers, rock processes, reconstruction of pH and pCO2, groundwater pollution, and further help in understanding the changes which have occurred in oceans through geological time. Furthermore, boron isotopes have also been utilized to understand the genesis of ores and understanding subduction processes and as a tracer in groundwater pollution. In plants, it acts as a micronutrient. However, its deficiency and the excessive amount may inhibit the growth of plants, bacteria, and fungi and may also affect the soil and aquatic microflora. Boron maintains and regulates several metabolic pathways, and its quantity above a certain level may prove detrimental to the environment. This overview explains boron isotope variations and their implications in earth sciences and natural processes.
اظهر المزيد [+] اقل [-]Impacts of microplastics and heavy metals on the earthworm Eisenia fetida and on soil organic carbon, nitrogen, and phosphorus النص الكامل
2023
Mai, Huong | Thien, Nguyen Danh | Dung, Nguyen Thuy | Valentin, Christian
Microplastics (MPs) are increasingly being studied because they have become ubiquitous in aquatic and terrestrial environments. However, little is known about the negative effects of co-contamination by polypropylene microplastic (PP MPs) and heavy metal mixtures on terrestrial environment and biota. This study assessed the adverse effects of co-exposure to PP MPs and heavy metal mixture (Cu2+, Cr6+, and Zn2+) on soil quality and the earthworm Eisenia fetida. Soil samples were collected in the Dong Cao catchment, near Hanoi, Vietnam, and analyzed for changes in extracellular enzyme activity and carbon, nitrogen, and phosphorus availability in the soil. We determined the survival rate of earthworms Eisenia fetida that had ingested MPs and two doses of heavy metals (the environmental level — 1 × — and its double — 2 ×). Earthworm ingestion rates were not significantly impacted by the exposure conditions, but the mortality rate for the 2 × exposure conditions was 100%. Metal-associated PP MPs stimulated the activities of β-glucosidase, β-N-acetyl glucosaminidase, and phosphatase enzymes in soil. Principle component analysis showed that these enzymes were positively correlated with Cu2+ and Cr6+ concentrations, but negatively correlated with microbial activity. Zn2+ showed no correlation with soil extracellular enzyme activity or soil microbial activity. Our results showed that co-exposure of earthworms to MPs and heavy metals had no impact on soil nitrogen and phosphorus but caused a decrease in total soil carbon content, with a possible associated risk of increased CO2 emissions.
اظهر المزيد [+] اقل [-]Air pollution and agricultural labor supply: Evidence from China النص الكامل
2023
Ye, Hai-Jian | Huang, Zuhui | Chen, Shuai