Changes in potential evapotranspiration will affect the surface ecology and environment of the land. Accurate and quick estimation of potential evapotranspiration will help to analyze environmental change. In this study, in combination with the canonical correlation analysis (CCA) and k-nearest neighbor algorithm (k-NN), a new method for calculating potential evapotranspiration (CCA-k-NN) based on self-optimizing nearest neighbor algorithm was proposed, in which less meteorological data were used for estimation. By analyzing the basic principles of CCA and k-NN and according to the requirement of estimating ET₀, the CCA-k-NN method was constructed, and its basic principles and key steps were described. In this method, CCA algorithm was used to find the most relevant meteorological data for potential evapotranspiration, and the dimensionality of meteorological data for subsequent estimation of ET₀ was reduced. Then, k-NN algorithm was used to estimate ET₀. The Northwest of China was chosen as the research area to evaluate the applicability of this method. The 148 data stations in the region were divided into training datasets, testing datasets, and validation datasets. ET₀ was estimated on three datasets using the proposed method, and the estimation accuracy of the CCA-k-NN method was evaluated with FAO-56 Penman-Monteith as a reference. The results show that the CCA-k-NN method maintains a high correlation with FAO-56 Penman-Monteith (correlation coefficient is greater than 0.9) and has a good estimation accuracy. RMSE and MAE are both less than 1 mm day⁻¹, and the overall performance of NSCE is greater than 0.5, all of which reach the level of “applicable” and above. At the same time, the CCA-k-NN method has low time complexity O(n). Comparison of the results of the CCA-k-NN method with those of other empirical models showed that the CCA-k-NN method is more accurate and can be employed successfully in estimating ET₀.

17α-ethinylestradiol (EE2), the female contraceptive pill, has been detected in mediterranean coasts where seahorse populations, Hippocampus guttulatus, live. Low environmental concentrations have the potential to disrupt growth but also endocrine metabolism, and this imbalance is all the more critical in early life stage. To investigate the impact of EE2 in reared seahorses, we exposed aged 2 months and sexually undifferentiated seahorses to an environmental concentration of 21 ng/L of EE2 for a period of 30 days. EE2 exposure led to a 19% reduction in weight, but also a mortality rate of 27%. This exposure predicted demasculinization of male individuals with a late onset of secondary sexual characteristics. EE2 exposure led to an increase of the free androgen index, but significant reductions of estradiol and testosterone in males were observed. This low estrogen concentration seemed to impact the positive feedback on luteinizing hormone (LH) with a decrease in LH production. Added to this, synthetic estrogen had a negative impact on the production and the release of follicle-stimulating hormone. Contrary to all expectations, females demonstrated a significant decrease in vitellogenin, following exposure to EE2 at 21 ng/L, while no changes were detected in males. This first study on the European long-snouted seahorses confirmed the deleterious impact of the female contraceptive pill with a real impact on growth, sexual differentiation, and maturation in young immature seahorses.

As solid wastes are generated during coal mining, waste rocks can be backfilled into goaf so as to reduce geological hazards and environmental damage caused by coal mining; however, under different stress regimes, the sensitivities of factors influencing compression-induced deformation (CID) of waste rocks for backfilling (WRBs) are different. In order to control the compression-induced deformation of waste rocks for backfilling more efficiently, compression characteristics of waste rocks for backfilling under four different stress levels were tested by using a homemade loading test system for granular materials based on an orthogonal experiment. The influences of lithology, particle size distribution (PSD), lateral stress, and number of lateral loading cycles on compression-induced deformation of waste rocks for backfilling and sensitivities ranks of the four factors were analysed. The test results showed that: (1) under an axial stress of less than 10 MPa, lateral stress was considered the main factor influencing compression-induced deformation of waste rocks for backfilling; when the axial stress ranged from 10 to 20 MPa, particle size distribution was the main influencing factor; (2) under four different axial stress levels, the optimal combination of influencing factors is sandstone, a particle size distribution from 0 to 10 mm, 3 MPa lateral stress, and 7 lateral loading cycles; (3) to control the compression-induced deformation of waste rocks for backfilling, it was necessary to optimise the lateral stress under an axial stress of less than 10 MPa; while the axial stress was between 10 and 20 MPa, it was essential to optimise the particle size distribution.

Against the increasingly serious haze pollution in China, this paper is to compare the impacts of different factors on haze pollution in different regions, and understand the causes of regional inequality of haze pollution. In doing so, quantile regression and regression-based Shapley value decomposition are employed in this paper. The main results are as follows. (1) Population density and industrialization level have positive impacts on haze pollution, while economic development negatively influences haze pollution, however, the impact of environmental regulation on haze pollution is ineffective. (2) With quantile increasing, the effect of foreign direct investment on haze pollution changes from positive to negative, and the influence of energy intensity on haze pollution changes from negative to positive. (3) The decomposition results specify that the regional inequality in population density is the main cause of the regional disparities of haze pollution. The inequalities in industrialization level and regional factors are also important reasons, and the contribution of energy intensity cannot be ignored either. The regional gap of economic development is conducive to reducing the regional disparities of haze pollution.

Marine diesel engines produce a lot of exhaust gas (NO, SO₂). Based on the situation that wet scrubbing methods have been already applied to ship desulfurization and seawater is easily accessible around the ships, this paper proposed a novel AOP (advanced oxidation process) of NaClO₂ (sodium chlorite) with Cl⁻ (abundant Cl⁻ exist in seawater) to remove NO from the flue gases of marine engines. The buffer capacity of NaAC (sodium acetate), the effect of Cl⁻ concentration, and Cl⁻ promotion mechanism on NO removal were investigated. The result showed that the existence of NaAC in solution could inhibit the rapid decline of the solution pH. The addition of Cl⁻ achieved a remarkable promotion to NO removal at lower NaClO₂ concentration, which was due to the fast generation of ClO₂ from the promotion decomposition of NaClO₂ by Cl⁻ in acidic condition. Then, the thermodynamic and dynamic mechanism of the generation of ClO₂ was intensively analyzed. And the mechanism of NO removal was discussed finally.

Fertilization is an important agricultural strategy for enhancing the efficiency of phytoremediation in copper (Cu)-contaminated soils. In this study, the effects of nitrogen (N) forms, including ammonium (NH₄⁺-N) and nitrate (NO₃⁻-N), on the growth, translocation, and accumulation of Cu in the tissues of Ricinus communis L. were investigated in pot and hydroponic experiments. The results demonstrated that higher biomass and N contents in plants were obtained when N was supplied as NO₃⁻-N rather than NH₄⁺-N. Application of N increased the Cu content in the roots of R. communis, with a higher content after NH₄⁺-N (53.10–64.20 mg kg⁻¹) than NO₃⁻-N (37.62–53.75 mg kg⁻¹) treatment. On the contrary, the levels of Cu translocation factors were much higher in NO₃⁻-fed plants (0.34–0.45) than in NH₄⁺-fed plants (0.28–0.38). The suggested amount of N for fertilizer application is 225 kg hm⁻², which resulted in the highest Cu content in R. communis and optimal plant growth. As the main Cu-binding site, root cell walls accumulated less Cu in plants treated with NH₄⁺-N compared with NO₃⁻-N. Additionally, NH₄⁺-N induced a higher malondialdehyde content and more severe root damage compared with NO₃⁻-N. In the leaf, a larger number of black granules, which could be protein and starch grains involved in the detoxification of Cu in R. communis, were present after NH₄⁺-N than NO₃⁻-N treatment. These results illustrate that N forms are especially important for Cu translocation and accumulation and that immobilization and transformation of Cu in roots were improved more by NH₄⁺-N than NO₃⁻-N. In conclusion, N fertilizers containing the appropriate forms applied at suitable rates may enhance the biomass and Cu accumulation of R. communis and thereby the remediation efficiency of Cu-contaminated soils.

The aim of this study was to evaluate the therapeutic properties of Mimosa caesalpiniifolia in liver of rats exposed to cadmium under morphological, oxidative, inflammatory, and mutagenic parameters. A total of 40 Wistar rats (90 days, ~ 250 g) were distributed into eight groups (n = 5) as follows: (i) control; (ii) cadmium: cadmium chloride injection at 1.2 mg/kg; (iii) Mimosa extract: treatment with Mimosa extract at 250 mg/kg; (iv) Mimosa fraction: treatment with Mimosa acetate fraction at 62.5 mg/kg; (v) cadmium and Mimosa extract 62.5: submitted to cadmium chloride at 1.2 mg/kg injection and treatment with Mimosa extract at 62.5 mg/kg; (vi) cadmium and Mimosa extract 125: subjected to cadmium chloride at 1.2 mg/kg injection and treatment with Mimosa extract at 125 mg/kg; (vii) cadmium and Mimosa 250 extract: submitted to cadmium chloride 1.2 mg/kg injection and treatment with Mimosa extract at 250 mg/kg; (viii) cadmium treated with fraction of Mimosa acetate: submitted to cadmium chloride 1.2 mg/kg injection and treatment with acetate fraction of Mimosa extract at 62.5 mg/kg. In the animals intoxicated with cadmium and treated with fraction [62.5], increased expression of SOD-Mn reduced frequency of binucleated hepatocytes, karyolysis, and karyorrhexis, besides the antimutagenic and antioxidant action. The extract [62.5] was cytoprotective, antimutagenic, and reduced karyolysis. The extract [125] was cytoprotective, antioxidant, antifibrotic, anti-inflammatory, and reduced frequency of binucleated hepatocytes, while extract [250] was cytotoxic and mutagenic. In summary, the extract of Mimosa exerts some therapeutic properties in hepatic tissue after Cd intoxication, but only when it is administrated at intermediate doses. Probably, a high content of polyphenols in the EHM [250] and Fr-EtOAc groups exert pro-oxidant activities in the liver particularly when associated with Cd.

Compound pollution refers to two or more kinds of pollutants with different properties, a pollutant from different sources, or the simultaneous existence of two or more different types of pollutants in the same environment. In this study, we aimed to investigate the individual and combined toxicity of the insecticide imidacloprid (IMI), the herbicide acetochlor (ACT), and the fungicide tebuconazole (TBZ) to zebrafish. The acute toxicity test results showed that the 96-h LC₅₀ values of IMI, ACT, and TBZ were 276.84 (259.62–294.35) mg active ingredient (a.i.) L⁻¹, 1.52 (1.34–1.74) mg a.i. L⁻¹, and 8.16 (7.7–8.6) mg a.i. L⁻¹, respectively. The combinations of IMI, ACT, and TBZ with toxicity ratios of 1:2:2, 1:4:4, 2:4:1, and 4:1:4 displayed synergistic toxic effects on zebrafish, while the toxicity ratios of 1:1:1, 1:1:2, 2:1:2, 2:2:1, and 4:2:1 of IMI, ACT, and TBZ, respectively, exhibited antagonistic toxic effects on zebrafish. The following experiments were performed with a toxicity ratio of 1:4:4 (IMI:ACT:TBZ). The activities of four enzyme biomarkers related to oxidative stress in the liver, catalase (CAT), superoxide dismutase (SOD), glutathione S-transferase (GST), and malondialdehyde (MDA) content were evaluated in each exposure group on days 7, 14, 21, and 28. Compared with those of the control group, the activities of CAT, SOD, and GST and the MDA content were significantly altered at different time points in the individual and combined exposure groups. Additionally, the activities of CAT, SOD, and GST and the MDA content were significantly altered in the combined group compared with those of the individual group after 14 days or 21 days of exposure. Therefore, it was confirmed that combined toxicity studies are indispensable in risk assessment. Graphical abstract .

Based on a monthly field survey in 2011 of the Pearl River Estuary, the dynamics of polycyclic aromatic hydrocarbons (PAHs) in surface sediments (depth < 5 cm) were explored. The seasonal variations in PAH level and composition were investigated in this study, as well as their environmental behaviors, the role of particles, and source apportionment. The concentration of the sum of 16 priority PAHs (defined as ∑₁₆PAHs) ranged from 0.32 to 1.10 μg/g, while that of the sum of 62 PAHs (defined as ∑ₜPAHs) varied from 0.83 to 2.75 μg/g. The levels of both the ∑₁₆PAHs and ∑ₜPAHs peaked in February, although the minimum levels appeared in different months—December and August, respectively. The seasonal difference in the ∑ₜPAHs was significant (flood season, 7.69 μg/g; dry season, 10.51 μg/g). The 5-ring PAH compound (e.g., perylene) was the most abundant and was responsible for 35% of the total, which implied a terrestrial input source via the Pearl River. Sediment particles were predominantly composed of clayed sand, and sediment PAHs showed a greater tendency to be adsorbed onto the large-sized particles rather than the fine fractions. Total organic carbon (TOC) could considerably facilitate the sediment PAHs. Principal component analysis revealed that vehicle emission sources, petroleum sources, and combustion sources were the major anthropogenic contamination sources. The diagnostic ratios of various individual PAHs were also explored. These findings are particularly useful for understanding the geochemistry of organic pollutants in the complex estuarine environment.

Benzophenone-3, benzophenone-8, and 4-methylbenzylidene camphor are used in sunscreens because they can protect the skin from UV radiation. The widespread use of organic UV filters may mean that they directly or indirectly enter seawater during recreational activities or through sewage discharge. In this study, a simple and efficient method using 1-octanol:isooctane (2:8, v/v) as an extraction solvent and liquid chromatography–electrospray tandem mass spectrometry was developed to measure trace levels of organic UV filters in seawater samples. This proposed method proved to be a highly sensitive, low-cost, and green analytical tool that requires minimal sample preparation. The method was validated and it exhibited favorable performance as well as acceptable accuracy (67 to 115%), precision (2.1 to 7.3%), coefficients of determination (0.9952 < R² < 0.9987), sensitivity (limits of quantification [3.3 to 5.7 ng L⁻¹]), and an acceptable matrix effect (87 to 99%). This methodology was successfully applied to analyze seawater taken from Kenting National Park located in the Hengchun Peninsula of southern Taiwan. Benzophenone-3 was detected at all sampling sites and at a higher concentration than the other organic UV filters. The highest concentration of benzophenone-3 was 514.6 ng L⁻¹ in a sample collected from Baisha Beach.