Recently, research on the biological effects of microplastics (MPs) has grown exponentially. However, effects of MPs on freshwater fishes and the mechanisms of the biological effects of MPs were limited. So, the purpose of the current study was to clarify the effects of microplastics on oxidative stress response, DNA fragmentation, and proteinogram of the early juvenile stage of Nile Tilapia (Oreochromis niloticus). The fishes were assigned into four groups: one control, three MPs-exposed groups as 1 mg/L of MPs, 10 mg/L of MPs, and 100 mg/L of MPs respectively for 15 days and 15 days of recovery. The activities of superoxide dismutase, catalase, total peroxides, and oxidative stress index (OSI), as well as lipid peroxidation and DNA fragmentation, increased in groups exposed to MPs compared to the control group in a dose-dependent manner. In contrast, the activity of total antioxidant capacity decreased in groups exposed to MPs compared to the control group in a dose-dependent manner. The electrophoretic pattern of muscle proteins revealed alteration in the proteinogram in the MPs-exposed groups compared to control. After the recovery period, the activities of superoxide dismutase, catalase, total peroxides, total antioxidant capacity, lipid peroxidation, DNA fragmentation, and the electrophoretic pattern of muscle proteins returned to normal levels in 1 mg/L of MPs-exposed group. Combined with our previous work, these results suggest that MPs cause the overproduction of reactive oxygen species (ROS) and alters the antioxidants parameters, resulting in oxidative stress and DNA damage. The present study fosters a better understanding of the toxic effects of MPs on Tilapia as a freshwater model. Graphical Abstract

The fate of carbaryl in the Seto Inland Sea (west Japan) was predicted using a mass distribution model using carbaryl concentrations in river and sea water samples, degradation data, and published data. The predicted carbaryl concentrations in water in Kurose River and the Seto Inland Sea were 4.320 and 0.2134 μg/L, respectively, and the predicted concentrations in plankton, fish, and sediment were 0.4140, 2.436, and 1.851 μg/g dry weight, respectively. The carbaryl photodegradation and biodegradation rates were higher for river water (0.330 and 0.029 day⁻¹, respectively) than sea water (0.23 and 0.001 day⁻¹, respectively). The carbaryl photodegradation rates for river and sea water (0.33 and 0.23 day⁻¹, respectively) were higher than the biodegradation rates (0.029 and 0.001 day⁻¹, respectively). The hydrolysis degradation rate for carbaryl in sea water was 0.003 day⁻¹, and the half-life was 231 days. Land (via rivers) was the main source of carbaryl to the Seto Inland Sea. The model confirmed carbaryl is distributed between sediment, plankton, and fish in the Seto Inland Sea. Degradation, loss to the Open Ocean, and sedimentation are the main carbaryl sinks in the Seto Inland Sea, accounting for 43.81, 27.90, and 17.68%, respectively, of total carbaryl inputs. Carbaryl source and sink data produced by the model could help in the management of the negative impacts of carbaryl on aquatic systems and human health.

Following an increasing number of artificial electromagnetic field (EMF) sources in human surrounding, a number of research studies have been devoted to the issue of environmental EMF pollution. A particular attention has been attributed to the highly sensitive EMF zones, where people can stay for a longer period of time, which, among others, includes university campuses. Thus, the modern approach of long-term EMF monitoring has been established, carrying out cumulative field strength measurements at locations that are most visited by student population and university staff. The goal was to establish periodic and systematic EMF investigation over such highly sensitive areas, through a standardized procedure for EMF monitoring. In this paper, details about two EMF monitoring campaigns over the University of Novi Sad campus were presented, performing comparative analysis of their results. The obtained results revealed the increase (up to four times) of the cumulative field strength values, as well as the general population exposure, at specific locations. Between these two campaigns, the emergence of the new base station, as well as numerous Wi-Fi networks, was noticed in the campus. Consequently, the highest field strength values were acquired at two locations, most directly exposed to the main beams of base station’s antennas, although all obtained values were at least five times lower than the minimal reference levels prescribed by the Serbian legislation. Even though such results are acceptable, the future monitoring campaigns should be planned, particularly since the installation of new EMF sources are expected in the campus of the University of Novi Sad.

This paper proposes an effective and scientific method for the construction of a representative driving cycle for electric vehicles (EV) and takes it as a foundation for studying the energy consumption and equivalent emissions for EV. First, a test route is developed through the analysis of the topology of the Xi’an road structure and traffic flow. Second, the vehicle driving pattern data is gathered through an integrated method of chase car method and on-board method. The velocity-acceleration (V-A) grid method is used to divide speed and acceleration data into micro-states. Third, the proposed driving cycle construction method incorporates the Markov chain and Monte Carlo (MCMC) simulation method. Then, a filter process is designed to screen out the most representative driving cycle. Finally, the comparison of the simulation result and test results shows the constructed EV driving cycle is in line with reality, and estimating the EV’s energy consumption per kilometer, driving range, and equivalent emissions under official driving cycles results in large relative errors. Therefore, the construction of a real-world driving cycle for specific cities or areas is necessary to evaluate energy consumption, driving range, and equivalent emissions of EV.

The contemporary debate on globalization and gender equality has a strong impact on economic growth. The present study analyzes the impacts of globalization and gender parity on economic growth in the Organization of Islamic Cooperation (OIC) 47 member countries for the period (1991–2017), using System GMM panel data technique. The results of system GMM have also been empirically estimated by making two groups (viz., low-income and high-income OIC member countries from the World Bank data classification, 2019) to examine the robustness of globalization and gender parity on economic growth. The results reveal that there is a negative impact of globalization on economic growth in the overall sample of OIC countries. When estimated by decomposing low-income countries and high-income countries, globalization has a significantly positive impact on economic growth in the case of high-income OIC countries, whereas globalization slashes GDP in the case of low-income OIC countries. The study finds that there is a positive impact of gender parity (ratio of female to male labor force work participation) on economic growth. Moreover, foreign remittances, government expenditures, capital formation, and human capital are also becoming the causes of a significant increase in economic growth in OIC member countries.

Toxicity data on bisphenol A (BPA) effects on aquatic macrophytes remain scarce. Therefore, environmentally relevant BPA concentrations (0.03, 0.1, 0.3, 0.5, 1, and 3 μg L⁻¹) were tested on the seagrass Cymodocea nodosa different parts length increase. All plant parts, at low BPA concentrations (0.03–0.3 μg L⁻¹), elongated equally to the control, while their lengthening and elongation rates gradually decreased by increasing BPA concentrations. A gradual increase of “Toxicity index” with increasing BPA concentrations was observed but was lower for juvenile blades and higher for plagiotropic rhizomes and adult leaves. In all parts, the LOECs were 0.3 and the NOECs 0.1 μg L⁻¹ at 10th day. Juvenile blades displayed, under acute stress, lengthening inhibition at lower concentrations than the rhizomes and adult blades, but at a lower extent. The EC₅₀ values were lower for the rhizome internodes, followed by the adult blades and higher for the juvenile blades. Using as a biological “endpoint” the elongation, all C. nodosa parts and specifically the rhizomes and adult blades, followed by intermediate blades, adult sheaths, and juvenile blades, seemed to be sensitive BPA toxicity assessors. The evaluation of the relative sensitivity of the different parts to BPA toxicity could help identify the most suitable seagrass part for early diagnosis of the risk posed by BPA to seagrass meadows and could constitute a valuable tool to derive the seawater quality criteria and to be used in BPA monitoring programs for rational management of the coastal environment.

Silica-based nanocomposite syntheses employ many harmful substances, which, in turn, demand the development of new synthetic environmental-friendly routes that meet the principles of green chemistry. In this work, we present a novel magnetic adsorbent, Fe₂O₃@SiO₂ nanocomposite (Fe@SiNp), successfully obtained without surfactant, employing an electrochemical method. We characterized the nanocomposite and then applied it to remove aniline from the water medium. Characterization was carried out by vibrating-sample magnetometry (VSM), X-ray diffraction (XRD), scanning electron microscopy (SEM), and Fourier transform infrared spectroscopy (FT-IR). The parameters to the adsorptive removal of aniline were successfully optimized, which made possible to remove 71.04 ± 0.06% (126.6 ± 2.0 mg/g) from a 100 mg/L aniline solution at pH 6 and 323 K, by employing around 50 mg of Fe@SiNp, at a contact time of 40 min. The adsorption of aniline by Fe@SiNp is a spontaneous and exothermic process according to the pseudo-second-order kinetic model (r² = 1 at 20 mg/L aniline concentration) and the Freundlich isotherm model (r² = 0.9986).

The iron (Fe) (hydro)oxides deposited around rice roots play an important role in arsenic (As) sequestration in paddy soils, but there is no systematic study on the relative importance of Fe (hydro)oxides on root surface and in rhizosphere soil in limiting As bioavailability. Twenty-seven rice genotypes were selected to investigate effects of Fe (hydro)oxides on As uptake by rice in an alkaline paddy soil. Results indicated that the As content was positively correlated with the Fe content on root surface, and most of As (88–97%) was sequestered by poorly crystalline and crystalline Fe (hydro)oxides in the alkaline paddy soil. The As sequestration by Fe (hydro)oxides on root surface (IASᵣₒₒₜ 16.8–25.0 mg As/(g Fe)) was much higher than that in rhizosphere (IASᵣₕᵢzₒ 1.4–2.0 mg As/(g Fe)); therefore, in terms of As immobilization, the Fe (hydro)oxides on root surface were more important than that in rhizosphere. However, the As content in brown rice did not have significant correlation with the As content on root surface but was significantly correlated (R² = 0.43, P < 0.05) with the partition ratio (PRAₛ = IASᵣₒₒₜ/IASᵣₕᵢzₒ) of As sequestration on root surface and in rhizosphere, which suggested that Fe (hydro)oxides on root surface did not play the controlling role in lowering As uptake, and the partition ratio PRAₛ would be a better indicator to evaluate effects of Fe (hydro)oxides around roots on As uptake by rice.

Antibiotics are commonly used in intensive farming, leading to multiple antibiotic residue in livestock waste. However, the effects of multiple antibiotics on the emissions of greenhouse gas and ammonia remain indistinct. This paper selects sulfamethoxazole and norfloxacin to represent two different types of antibiotics to explore their effects on gaseous emissions. Four treatments including CK (control), SMZ (spiked with 5 mg kg⁻¹ DW sulfamethoxazole), NOR (spiked with 5 mg kg⁻¹ DW norfloxacin), and SN (spiked with 5 mg kg⁻¹ DW sulfamethoxazole and 5 mg kg⁻¹ DW norfloxacin) were composted for 65 days. Coexistence of sulfamethoxazole and norfloxacin facilitated the biodegradation of organic carbon, and significantly (p < 0.05) increased the cumulative CO₂ emission by 31.9%. The cumulative CH₄ emissions were decreased by 6.19%, 23.7%, and 27.6% for SMZ, NOR, and SN, respectively. The total NH₃ volatilization in SMZ and NOR rose to 1020 and 1190 mg kg⁻¹ DW, respectively. The individual existence of sulfamethoxazole significantly (p < 0.05) ascended the N₂O emission rate in the first 7 days due to the increase of NO₂⁻-N content. In addition, coexistence of sulfamethoxazole and norfloxacin notably dropped the total greenhouse gas emission (subtracting CO₂) by 15.5%.

Magnetron sputtering was employed for the deposition of cobalt oxide thin films on stainless steel meshes. Catalysts prepared by sputtering in inert and oxidation atmosphere were compared with those obtained by electrochemical deposition and hydrothermal synthesis. Systematic characterization using X-ray diffraction, scanning electron microscopy, N₂ physisorption, infrared spectroscopy, Raman spectroscopy, and temperature-programmed reduction by hydrogen allowed detailed monitoring of their physicochemical properties. Ethanol gas-phase oxidation was employed as a model reaction to reveal the catalytic performance of the catalysts. It was shown that the catalyst prepared by magnetron sputtering in oxidation atmosphere exhibited the best mechanical stability among all studied catalysts. Moreover, its catalytic activity was 18 times higher than that of pelletized commercial cobalt oxide.