The present study aims at a detailed experimental study of a passive-type solar air heater (SAH) on the effect of coating the absorber plate with higher thermal conductive black paint under forced circulation method and studied under the climatic conditions of Chennai. Furthermore, to enhance the thermal performance index of conventional SAH, additional enhancement such as coating and staggered fins are fixed to the absorber plate of duct which simultaneously increases the turbulent intensity, kinetic energy to enhance the temperature of outlet air. Comparisons are made with a solar air heater without coating and staggered fin in order to assess the thermal performance. Experiments were conducted on a continuous basis and the flow rates of air flowing through the duct are varied. Experimental results revealed that the effect of coating improved the plate temperature to a maximum of 102 °C while the modified SAH coated with ordinary black paint and staggered fin arrangement is found as 95 °C for the flow rate of mf = 0.03 kg/s. The difference in temperature between exit and inlet of conventional SAH with coating alone is found as 13.09 °C at a flow rate of mf = 0.03 kg/s whereas the average thermal efficiency is found as 22.3%. Similarly, increasing the mass flow rate from 0.13 to 0.22 kg/s has no significant improvement in average daily thermal efficiency, whereas the temperature difference decreases. The coating of absorber plate with higher thermal conductivity paint and increased turbulence created between the duct by using staggered fin improved the temperature of exit air by 63, 64, 38 and 35% for air flow rates of 0.03, 0.04, 0.13 and 0.22 kg/s respectively. On a flat absorber with coating, the average increase in temperature is found at 6.3% compared to that of SAH coated with ordinary black paint. The hourly thermal efficiency of the conventional type SAH with coating exhibited an enhancement of about 5% in thermal efficiency as compared to that of conventional type with black paint coating alone for the same climatic condition, whereas the thermal efficiency of staggered fin SAH with coating alone is enhanced by 7.5%. With staggered fin arrangement in the absorber plate, heat absorption by the air is increased with CNT-coated absorber and excessive turbulence produced by the fins enhanced the average temperature difference from 13.5 to 20.3 °C. The cost per unit kW of conventional type SAH with CNT-doped black paint reduced from 0.01754 $ to 0.00832 $/kW while varying the flow rate from 0.031 to 0.22 kg/s.

This study presents a detailed mathematical model of the pyramid solar still which is not performed in most of the previous studies. Computer programs (in Pascal language) are developed for both studying thermal performance of the square pyramid solar still and estimating the hourly variations of the solar intensity incident on the tilted still’s covers. Comparisons between the obtained theoretical results and experimental results (from previous work) are performed to validate the proposed mathematical model. The daily productivity of the pyramid solar still (Pd) varies from 4.22 to 4.43 kg/m² day with values of the glass cover’s tilt angle of 10°–60°. Pd decreases from 3.88 to 1.52 kg/m² day with increasing the depth of the still’s water (dw) from 0.01 to 0.30 m. Values of the top losses of the still decrease from 8.8064 to 8.2304 W/m² K with increasing glass cover surface area from 0.063 to 0.125 m², which correspond to values of tilt angles of the still covers changing from 10° to 60°, respectively.

This empirical study aims to test the validity of the environmental Kuznets curve (EKC) hypothesis for China within the framework of (Narayan and Narayan Energy Policy 38(1):661–666, 2010) approach. To this end, the study employs a recently developed Fourier ARDL procedure and time-varying causality test over the period 1965–2016 to analyze the short- and long-term relationships between economic growth, economic complexity index, energy consumption, and ecological footprint. The findings of the Fourier ARDL procedure confirm the existence of cointegration among the series. Moreover, the results of this study demonstrate that energy consumption and ecological complexity increase ecological footprint in both the short- and long term. However, the short-term elasticity of economic growth is smaller than the long-term elasticity, implying that the EKC hypothesis is not valid for China. This finding is robust as it is confirmed by the time-varying causality test. The overall results illustrate that economic complexity has an increasing impact on ecological footprint, and economic growth is not effective to solve environmental problems in China. Therefore, the Chinese government should encourage a more environmentally friendly production process and cleaner technologies in exports to reduce environmental pollution.

The application of char from biomass gasification as a filling material in landfill simulation reactors was investigated to evaluate the effect of char on carbon retention and nitrogen leaching, nitrogen denitrification, and waste stabilization. Landfill simulation columns filled with fine fraction of aged refuse (AR) and solid fraction of digestate (SFD) were used, with two char application methods: embedding a char layer between AR and SFD layers and mixing char with the SFD. The experimental results show that char application increased the biodegradable organic matter content as the respiration index (RI₄) of the mixture char-SFD increased up to 37.7%, which could enhance the heterotrophic denitrification. Moreover, 12.3% of ammonia leaching was avoid by applying the SFD mixed with char. These results indicate that char from biomass gasification poses a significant enhancement on nitrogen and carbon retention which might increase the denitrification capacity of the SFD in the long run. Although high nitrogen removal rates were achieved (up to 23.1 mg N/kg-TS day), the addition of char from biomass gasification has little effect on the nitrate removal.

The spent biological activated carbon (BAC) should be disposed properly; regeneration was a better choice. Performances of thermal and ultrasonic regeneration to the BAC with various service time (3 years, 5 years, and 10 years) were compared comprehensively; the recovery of the BAC’s pore structure, variation of mechanical hardness, influence of bioactivity, and removal efficiency of typical pollutants in the reuse were examined. The results showed that thermal regeneration was an utterly regeneration, and almost all the pore structure was restored, whose recovery rate was above 90% for BAC used 3 years and disfavored by the longer BAC’s service time (83% for the BAC used 5 years). Ultrasonic regeneration could recover part of the BAC’s pores (including micropores) and the restoration mainly focused on the BAC’s surface, so the recovery rate was not influenced by the BAC’s service time, and the recovery values of specific surface areas and iodine value were kept at 120 m²/g and 200 mg/g, respectively. In addition, the ultrasonic treatment enhanced the BAC’s biological activity even with a significant decrease of the biomass on the BAC. The mechanical hardness of BAC decreased from 95 to 89% for the first regeneration and further to 79% for the second regeneration, whereas relatively lower decrease happened for the ultrasonic regeneration (less than 10% after 5 regeneration cycles). The mass losses in the thermal and ultrasonic regeneration were about 13%, 0.5%, and 25%, 3% for the first and second regeneration, respectively. The thermal-regenerated activated carbon (AC) exhibited excellent adsorption ability, good adherence of biofilm, and maintain higher removal rate for more than 2 years, which were similar with that of the fresh AC, but relatively lower removal performance was found. However, the ultrasonic regenerated BAC retained the biodegradation ability, restored the fast-adsorption ability, and the higher removal process lasted about 6 months. Taking the regeneration cost, operation, variation of the AC’s characteristics, and the removal performance in reuse, ultrasonic regeneration was more suitable for the BAC filter and better used as a regular measure to maintain the higher removal performance, whereas thermal regeneration was more applicable to the activated carbon adsorption tank.

The green roofs are structures characterized by the application of vegetation cover in the buildings, using adequate waterproofing and drainage systems. It allows the reduction of surface runoff and delay in peak flow, contributing to the mitigation of flood events in urban areas. Therefore, this study aimed to evaluate the effect of the use of vegetal coverings on the surface runoff, taking into account quantitative and qualitative aspects, using an experimental module installed in the city of Porto Alegre, Brazil. The experimental station consisted of four modules: two horizontal modules with and without vegetation cover and two modules with slopes of 15° with and without vegetation cover. It was evaluated 19 precipitation events, and it was verified the volumes drained in each module after 3, 6 and 12 h from the beginning of precipitation. The water samples were collected in order to analyse the quality of the runoff from the experimental modules. The results have shown that the use of vegetal coverings can provide better distribution of the surface runoff, as well as a decrease of the speed of excess water release with no surface runoff in the first 3 h after the onset of rainfall in the horizontal module. Additionally, it was proved the reduction in drained volumes, with the flat module with vegetation cover being capable of retaining completely precipitations with volumes of approximately 22 mm. The vegetation cover module in roofs was the one that has presented better results regarding the reduction of the flow, presenting an average retention percentage of 91.7% for the first 3 h, indicating that the slope is an important factor. The physical-chemical analysis of the water shows that for all analysed modules, it is possible to use water for non-potable uses, although the water quality of the modules with vegetation cover is lower when compared to the water coming from the module without vegetation cover.

Industrial activities such as leather tanning involve the use of highly toxic inorganic pollutants, like Chromium (Cr). This work evaluated Cr(VI) remediation by hairy roots (HR) of Brassica napus, paying close attention to the mechanisms involved and the toxicity of post-removal solutions. Results showed that these roots were capable of tolerating concentrations of up to 10 mg L⁻¹ Cr(VI), while higher concentrations were toxic for HR development. Removal efficiency was assessed through the use of synthetic solutions containing different initial Cr(VI) concentrations (2, 5, or 10 mg L⁻¹). Regardless of these initial concentrations, the highest removal efficiency values were between 80 and 90% after 24 and 48 h of treatment, using a 2.0 g inoculum. The mechanisms involved were Cr accumulation (60%) and to a lesser extent, adsorption to the root biomass (30%). A fraction of Cr(VI) was intracellularly reduced to Cr(III), which suggests reductases may have played a role. Additionally, post-removal toxicity was evaluated through two bioassays (Lactuca sativa L. and AMPHITOX test) after the removal of 10 mg L⁻¹ Cr(VI). The treated solutions showed moderate phytotoxicity for L. sativa L. and no toxicity for R arenarum. The ability of HR to remove 10 mg L⁻¹ Cr(VI) from real tannery effluents collected from a regional industry (Córdoba province, Argentina) was also determined. The high removal efficiency observed (98%) demonstrates this system can be successful in treating complex wastewaters.

Dioctyl phthalate (DOP) (200, 500, and 1000 mg kg⁻¹ bw, i.g.), Pb (Ac)₂ (50 mg L⁻¹, p.o.), and NaAsO₂ (10 mg L⁻¹, p.o.) were administered individually and as mixtures to weanling male mice for 8 weeks. It was observed that Pb, As, and DOP exposure could significantly inhibit the growth and development of mice. Compared with the Pb, As, and Pb + As groups, the activities of iNOS and TNOS were significantly increased, the levels of AChE and SOD were significantly decreased, and the level of MDA was significantly increased in the Pb + DOP-H, As + DOP-H, and Pb + As + DOP-H groups. The factorial analysis shows that the iNOS, TNOS, and AChE present synergistic effects on Pb, As, and DOP. A significant increase of escape latency and a significant decrease of original platform quadrant stops were observed between Pb + As + DOP-H and Pb + As groups. The factorial analysis shows that there was a synergistic effect on Pb, As, and DOP. Compared with that of the control group, the expression levels of caspase-3 and Bax expression in Pb + As, DOP-H, Pb + DOP-H, As + DOP-H, and Pb + As + DOP-H groups were significantly increased in the hippocampus. The expression levels of Bcl-2 expression decreased significantly and the Bax/Bcl-2 ratio increased significantly. Pathological alterations on the hippocampus were found in exposed groups. This result shows that combined exposure of Pb, As, and DOP could induce neurotoxicity, of which possible mechanism is hippocampal neuronal apoptosis. Graphical abstract This study shows that there were three components with eigenvalues greater than 1, which together explained 89.40% of total variance. The first component (PC1) showed high loadings on B-SOD, L-SOD, B-MDA, L-MDA, K-MDA, iNOS, tNOS, and AChE and accounted for 46.55% of the total variance after Varimax rotation. PC2 accounted for 23.81% of the total variance with high loadings on B-As, L-As, K-As, and K-SOD, whereas PC3 showed high loadings on B-Pb, L-Pb, and K-Pb and accounted for 19.04% of the total variance.

In this study, the immature mice were taken to assess the potential neurological toxicity of lead (Pb) and di (n-butyl) phthalates (DBP) combination exposure. Mouse administration with DBP combination with Pb exhibited longer escape latency and lower average number of crossing of the platform. Pb content in the tissues was increased, especially in the brain, after Pb exposure as compared to those without Pb exposure. The alterations of oxidative damages in tissues (MDA and SOD) and biochemical indicators in the brain (AChE, TNOS, and iNOS) were observed, as well as the synergistic effect of joint exposure. Expressions of apoptosis-related protein (bax/bcl-2 ratio and caspase-3) were significantly increased in the hippocampus, while the bcl-2 was remarkably decreased and no significant differences were observed on the bax. The results suggested that the possible mechanisms for the learning and memory ability impairments were as follows: Firstly, the combination exposure induced the occurrence of lipid peroxidation in the brain, leading to damage to the brain cells. Secondly, it destroyed the normal metabolic balance of ACh, causing nerve damage in mice. Thirdly, it induced apoptosis in mouse hippocampal cells. The overall findings revealed that Pb and DBP co-exposure greatly influenced the developmental nervous system and accompanied with synergistic toxic effect.

China is among the countries facing the most serious pollution effects of e-waste. Many studies have focused on e-waste recycling laws and regulations, recycling technologies, and the pollution situation in China. However, there is a lack of case studies from the perspective of the residents’ attitudes and opinions about e-waste recycling. Based on 474 families surveyed by questionnaire, this study, taking Zhuhai City as one example, investigated residents’ behaviors and attitudes toward e-waste disposal, and their willingness to pay (WTP) for e-waste recycling. A majority (76.4%) of respondents realized that the improper treatment of e-waste would cause serious threats to the environment and human health. Only 38.2% of respondents were willing to pay for e-waste recycling. Most respondents believed that the fee should be borne by government and manufacturers. These results imply that income level and satisfaction with management will promote WTP significantly, whereas the recovery price is a negative influence on the respondents’ WTP. The WTP values were positively correlated with environmental awareness and income at 5% and 10%, respectively. Finally, the estimated average monthly WTP value per household in Zhuhai City is 10.2 RMB ($1.6).