Highly weathered acidic soils tend to have high phosphorus adsorption rates. Studying the differential phosphorus adsorption and desorption characteristics of these soils is of great significance to improve phosphorus utilization efficiency and reduce soil phosphorus loss in agricultural management. Erosive weathered granite soil (TL-Tillage layer, LL-Laterite layer, and SL-Sand layer) in Anji County, Zhejiang Province were selected for batch experiments and phosphorus fractionation test. The soil properties that are generally considered to have a greater impact on phosphorus adsorption and desorption are also studied. Derived from the Langmuir adsorption isotherm, the maximum absorption capacity (Qₘₐₓ) of phosphorus in TL soil was greater than that in LL and SL soil. With a pH of 4.3–5.0, the three soils have the most phosphorus adsorption. The desorption ratio (Dᵣ) in the SL soil is larger than the LL and TL soil. Six key soil property indicators can fit Qₘₐₓ and Dᵣ values well. Al-P is the main fraction in the phosphorus adsorption-desorption process. The particle size classification (PSC) method can be used to accurately calculate soil-specific surface area. The results of the soil phosphorus adsorption-desorption test can be used as an explanation of the results of artificial rainfall tests. Our results reveal the differential adsorption-desorption mechanism of eroded weathered granite soil, and provide a reference for selecting soil indicators for soil adsorption-desorption studies in different regions.

Groundwater is a primary source of living which also requires preservative measures for furture generations. Due to the lack of effective management technologies, the wastewater generated by rapid urbanization and industrialization is being disposed untreated, leading to groundwater contamination, caused by infiltration and accumulation. This problem has become more intense in major cities of India. The present work is based on determining the water quality using fuzzy index developed for the Perambalur district, Tamilnadu, India, from where 30 groundwater samples were collected from bore well as well as dug well sources. The research focusses mainly on chemical parameters like total hardness (T.H.), total dissolved solids (TDS.), potential hydrogen (pH), calcium (Ca²⁺), magnesium (Mg²⁺), potassium (K), sulphates (SO₄²⁻), total nitrates (NO₃ + NO₂), fluoride (F), bicarbonate (HCO₃), carbonate (CO₃²⁻) and chloride (Cl²⁻). These parameters were assessed for fuzzy water quality index (FWQI) model, and the index was designed concerning Mamdani fuzzy inference system. Five FIS models with different linguistic variables were developed based on triangular membership function with the implementation of 189 numbers of rules. Finally, fuzzy model was classified into five categories, such as excellent, good, poor, very poor and not-suitable. Based on the results obtained from this model, 6 samples were classified into excellent, 8 samples into good, 12 to poor, 3 to very poor and 1 to not-suitable. In connection with that, the results of proposed model were compared with the output obtained from the deterministic method.

Water treatment sludge (WTS) is abundantly produced in the world; the waste contributes to the environmental problems. Therefore, for WTS utilization, aluminum leaching was employed using hydrochloric acid in this study. Al leaching efficiency increased from 72% to 80% as hydrochloric acid concentration increased from 1 to 4 M. Decreasing the particle size and increasing the temperature increased Al leaching efficiency. The proposed kinetic model revealed that the rate-controlling step followed a series of two leaching mechanisms: initially controlled by product-layer diffusion and then by a chemically controlled reaction. For instance, at 70 °C, the initial stage is well fitted by product-layer diffusion (R² = 0.87) compared to R² = 0.60 for chemical reaction; while for the second stage, R² = 0.95 was observed via chemical reaction compared to R² = 0.74 for product-layer diffusion. The activation energies in these two stages were 9.58 kJ/mol and 10.73 kJ/mol, respectively. The proposed model was well validated by using data from literature and thus will be useful for other applications of leaching and extraction processes.

The 3-chloro-2 hydroxypropyltrimethyl ammonium chloride was successfully introduced into the β-cyclodextrin-modified chitosan to create the multicomponent adsorbent O-HTACC-g-CD. The structure of sorbent was characterized by Fourier transform infrared spectroscopy, X-ray diffraction, thermogravimetric analysis, and scanning electron microscopy. The adsorption capacity of O-HTACC-g-CD toward phenol was investigated as a function of pH, temperature, contact time as well as adsorbent dosage. The Box-Behnken response surface methodology was employed to optimize the effects of experimental parameters including adsorbent dose, pH, and time on the adsorption of phenol at 298.15 K. The obtained optimal values for adsorbent dose, pH, and time were 0.06 g, 6, and 200 min, respectively. The obtained experimental data follows the pseudo-second-order kinetic and Langmuir model. The thermodynamic parameters such as free energy change, enthalpy change, and entropy change were calculated, revealing that adsorption of phenol on O-HTACC-g-CD is a spontaneous and exothermic process. The prepared O-HTACC-g-CD displayed high adsorption capacity (39.98 mg g⁻¹) and excellent removal rate (96%) for phenol from the aqueous solution at 288.15 K. The gained removal rates of chemical oxygen demand (CODCᵣ) were in the range of 60.6–61.2%. Considerable results of sorption could be attributed to the multicomponent structure of the adsorbent with more active sites including the cavities, amino, and carboxyl functional groups which provided better sites for the phenolic pollutant to adsorb on the adsorbent via Van der Waals force, hydrogen bond, and the inclusion effect. Therefore, the results obtained strongly suggest that O-HTACC-g-CD could be an effective adsorbent for the removal of phenol and CODcᵣ from drilling wastewater.

In this article, the geographical location and availability of the most important crop residues generated in Mexico over the last 10 years (2008—2017) were determined. This study estimates the gross number of residues for the four most important cultivars in Mexico named conventional residues (CRs) such as corn, wheat, sorghum, and barley, and estimates were also made for regionally important crops identified as nonconventional residues (NCRs) such as coffee, sugarcane, and beans. The total and sustainable energy potentials (TEP and SEP) for agricultural residues were calculated, in similar way the butanol and electricity production potentials were also calculated if these residues were processed under a nonconventional biorefinery scheme; the calculated availability of crop residues was 59,059,666 t/year, thus demonstrating that Mexico could have great potential for bioenergy production. The estimated TEP was 1,787,241,249 PJ/year, and the SEP was 78,724,689 PJ/year. The production of butanol and its production cost were calculated for the main crop residues; the butanol volume ranged from 7348 to 161,610 t/day, and the volume of crops of regional importance ranged from 6461.9 to 151,389 t/day. The minimum butanol production cost was 2000 t/day of feedstock. The surplus electricity was determined for all crop residues.

The aim of this study was to recalibrate the Swiss lichen bioindication methods, developed and calibrated with air pollution data 30 years ago. Since then, levels of air pollution have considerably decreased, and the mix of pollutants has changed due to successful emission control in Switzerland and neighboring countries. In particular, there has been a change from a sulfur- and acid-dominated to a more nitrogen-dominated pollution mix of NH₃/NOₓ and ozone, resulting in increased pH levels. This allowed a recolonization and change in abundance and composition of the epiphytic lichen vegetation, indicating an improved air quality in Switzerland. The existing indices of atmospheric pollution or purity IAP₁₈ and IAPBR developed 30 years ago showed good longitudinal correlations with air pollutant levels until the end of the last century, but a growing drift was observed in some regions over the last 15 years. This called for a method recalibration with more recent air pollution data. Data from a total of 7178 trees from 22 Swiss regions grouped into 1331 homogenous plots and covering the period 1994 to 2017 were averaged by year within plots. Three pollutant-specific lichen indices were newly established, one for primary pollutants (NO₂, PM10, SO₂), one for ozone (AOT40f), and one for ammonia (NH₃). These pollutant-specific lichen indices were derived from linear regression models with lichen variables and a linear time trend variable as predictors, using time-dependent coefficients. Parameters were selected using the Lasso method. The primary pollutant lichen index showed a coefficient of determination R² of 0.86 in the model with NO₂, PM10, and SO₂ as predictor variables, whereas corresponding models with other predictor variables (i.e., NH₃, AOT40f, and meteorological variables) were of considerably lower fit. Regionalized lichen models for three larger Swiss regions revealed even better results, compared with the unified Swiss models. The best regionalized ozone and ammonia lichen indices reached an R² of 0.88 and 0.71, respectively.

China is experiencing rapid urbanization and industrialization with correspondingly high levels of air pollution. Although the harm of PM₂.₅ has been long reported, it is only quite recently that there is increasing concern in China for its possible adverse health effects on cardiovascular disease. We reviewed the epidemiologic evidence of potential health effects of PM₂.₅ on cardiovascular disease reported from recent studies in China (2013 onwards). There is clear evidence for the contribution of PM₂.₅ to cardiovascular outcomes, including mortality, ischemic heart disease, and stroke from studies based in various regions in China. This evidence adds to the global evidence that PM₂.₅ contributes to adverse cardiovascular health risk and highlights the need for improved air quality in China.

Some databases report global emissions of certain pollutants. Emissions Database for Global Atmospheric Research (EDGAR) project is one of these, which also records emissions by sources. In this study, the emissions of black and organic carbon and fine particulate matter from the EDGAR database were used as an input to process it in the Sparse Matrix Operator Kernel Emissions (SMOKE) model. We showed the spatial distribution of the fraction of black and organic carbon in particulate matter from each source in the Southern Hemisphere. Also, we extracted these ratios for several cities in the domain of analysis. The results and methodology of this study could improve the emission inventories with bottom-up methodology in areas without information located at Southern Hemisphere. Also, it could be relevant to obtain better performance in air quality modeling at the local level for decision-making on climate change and health effects.

Dechlorane Plus (DP) is an unregulated, highly chlorinated flame retardant. It has been manufactured from past 40 years but its presence in the environment was initially reported in 2006. Later, it has been found in various biotic and abiotic environmental matrices. However, little attention has been paid to monitor its presence in Asia. Many studies have reported the occurrence of DP in the environment of Asia, yet the data are scarce, and studies are limited to few regions. The objective of present review is to summarize the occurrence, distribution, and toxicity of this ubiquitous pollutant in various environmental matrices (biotic and abiotic). DP has also been reported in the areas with no emission sources, which proves its long-range transport. Moreover, urbanization and industrialization also affect the distribution of DP, i.e., high levels of DP have been found in urban areas relative to the rural. Tidal movement also incorporates in transport of DP across the aquatic system. Further, bioaccumulation trend of DP in various tissues is kidney > liver > muscle tissues, whereas, blood brain barrier resists its accumulation in brain tissues. Additionally, gender-based accumulation trends revealed high DP levels in females in comparison to males due to strong metabolism of males. Furthermore, methodological aspects and instrumental analysis used in previous studies have also been summarized here. However, data on biomagnification in aquatic ecosystem and bioaccumulation of DP in terrestrial food web are still scarce. Toxicity behavior of syn-DP and anti-DP is still unknown which might gain the interest for future studies.

Coal fly ash (FA) is a solid waste produced in coal combustion. This study focused on the removal of Cd²⁺ from wastewater by a newly synthesized adsorbent material, the low-temperature and sodium hydroxide–modified fly ash (SHM-FA). The SEM and BET analyses of SHM-FA demonstrated that the adsorbent was porous and had a huge specific surface area. The XRF, XRD, FTIR and TGA characterization showed that SHM-FA has an amorphous structure and the Si–O and Al–O in the fly ash dissolved into the solution, which improved the adsorption capacity of Cd. The results indicated that SHM-FA has desired adsorption performance. The adsorption performance was significantly affected by the dosage, starting pH, Cd²⁺ initial concentrations, and temperature, as well as adsorption time. In the optimal conditions, the removal efficiency and adsorption capacity of Cd²⁺ by SHM-FA were 95.76% and 31.79 mg g⁻¹, respectively. The experiment provided clearly explained adsorption kinetics and isotherms. And the results confirmed that the adsorption behavior was well described by the pseudo-second-order kinetic and Langmuir isotherm model, which means that the adsorption of Cd²⁺ was controlled by SHM-FA through surface reaction and external diffusion process. In addition, the recycling of SHM-FA for reuse after Cd²⁺ adsorption showed high removal efficiency up to six times of use. Therefore, it can be concluded that SHM-FA is a low-cost adsorbent for Cd²⁺ removal from wastewater.