Sediment dredging is considered an effective restoration method to reduce internal loading of nitrogen (N) and phosphorus (P) in eutrophic lakes. However, the effect of dredging on N release from sediments to overlying water is not well understood. In this study, N exchange and regeneration across the sediment-water interface (SWI) were investigated based on a one-year simulated dredging study in Lake Taihu, China. The results showed low concentrations of inorganic N in pore water with low mobilization from the sediments after dredging. The calculated fluxes of NO3−-N from post-dredged sediments to overlying water significantly increased by 58% (p < 0.01), while those of NH4+-N dramatically decreased by 78.2% after dredging (p < 0.01). N fractionation tests demonstrated that the contents and lability of N generally declined in post-dredged sediments. Further high-throughput sequencing analysis indicated that relative abundance of the bacterial communities decreased, notably by 30% (compared with undredged sediments). The estimated abundance of Nitrospira enhanced, although the relative abundance of Thiobacillus, Sterolibacterium, Denitratisoma, Hyphomicrobium, Anaeromyxobacter and Caldithrix generally declined after dredging. Therefore, dredging reduced N mobilization from the sediments, which primarily due to decreases in N mobility, in organic matter (OM) mineralization potential and in the bacterial abundance of post-dredged sediments. Overall, to minimize internal N pollution, dredging is capable of effectively reducing N release from sediments. In addition, the negative side effect of dredging on removal of NO3−-N and NO2−-N from aquatic ecosystems should be paid much more attention in future.

The sulfentrazone dechlorination using bimetallic nanoparticles of Fe/Ni was studied. Different variables that could influence the sulfentrazone conversion were investigated, such as nitrogen atmosphere, pH and dosage of the nanoparticles and initial concentration of sulfentrazone. The best results were obtained using controlled pH (pH 4.0) and 1.0 g L⁻¹ of nanomaterials, resulting in 100 % conversion in only 30 min. Kinetic studies were also conducted, evaluating the influence of different nanoparticle dosages (1.0 to 4.0 g L⁻¹), system temperatures (20 to 35 °C) and nickel levels in the composition of the nanomaterials (0.025 to 0.10 gNi/gFe). The mechanism of sulfentrazone conversion has changed due a direct reduction on the catalytic activity sites and indirect reduction by atomic hydrogen. Both mechanisms have followed pseudo-first order models. The conversion rate improved when the dosage of the nanomaterials, system temperature and nickel content in the composition of the nanocomposites were increased. Finally, the conversion products were elucidated by mass spectrometry and toxicity assays were performed using Daphnia Similis. The results showed that the dechlorination product is less toxic than sulfentrazone.

The CO2 and CH4 fluxes at the water–air interface were measured in shrimp (Marsupenaeus japonicus) monoculture ponds (S) with feed supply and shrimp-sea cucumber (Apostichopus japonicus) polyculture ponds (SS) without feed supply. During farming seasons of the whole year, cumulated CO2–C fluxes were −5.69 g m−2 (S) and 11.23 g m−2 (SS), respectively. The cumulated CO2 emissions from S and SS did not differ significantly. The cumulated CH4–C emissions from S (0.57 g m−2) were significantly higher than those from SS (0.068 g m−2). S absorbed C from the atmosphere with a mean absorption rate of −5.12 g m−2, whereas SS emitted C to the atmosphere with a mean emission rate of 11.30 g m−2. Over 20-year horizon, the compressive global warming potentials (cGWPs) were 33.55 (S) and 47.71 (SS), respectively, indicating both feeding and no-feeding mariculture ponds could promote global warming.

Along with the rapid socioeconomic development, air pollution in China has become a severe problem. One component of air pollution, in particular, PM2.5 has aroused wide public concern because of its high concentration. In this study, data were collected from over 900 monitoring sites of the newly constructed PM2.5 monitoring network in China. The interpolation methods were used to simulate the PM2.5 exposure level of China especially in rural areas, thus reflecting the spatial variation of PM2.5 pollution. We calculated the health benefit caused by PM2.5 in China in 2014 based on Environmental Benefits Mapping and Analysis Program (BenMAP), assuming achievement of China National Ambient Air Quality Standard (No. GB3095-2012). By reducing the annual average concentration of PM2.5 to the annual Grade II standard (35 μg/m3), the avoided deaths for cardiovascular disease, respiratory disease and lung cancer could reach 89,000 (95% CI, 8000–170,000), 47,000 (95% CI, 3000–91,000) and 32,000 (95% CI, 6000–58,000) per year using long term health function, respectively. The attributable fractions of cardiovascular disease, respiratory disease and lung cancer to all cause were 42%, 22% and 15%, respectively. The total economic benefits for rolling back the concentration of PM2.5 to the level of 35 μg/m3 were estimated to be 260 (95%CI: (73, 440) billion RMB and 72 (95%CI: (45, 99) billion RMB using willingness to pay (WTP) and human capital (HC) methods, respectively, which account for 0.40% (95%CI: (0.11%, 0.69%) and 0.11% (95%CI: (0.07%, 0.15%) of the total annual Gross Domestic Product (GDP) of China in 2014.

This study aimed to apply an inverse-dispersion calculation method (IDM) to estimate the emission rate of volatile organic compounds (VOCs) for the complicated industrial area sources, through a case study on a petroleum refinery in Northern China. The IDM was composed of on-site monitoring of ambient VOCs concentrations and meteorological parameters around the source, calculation of the relationship coefficient γ between the source's emission rate and the ambient VOCs concentration by the ISC3 model, and estimation of the actual VOCs emission rate from the source. Targeting the studied refinery, 10 tests and 8 tests were respectively conducted in March and in June of 2014. The monitoring showed large differences in VOCs concentrations between background and downwind receptors, reaching 59.7 ppbv in March and 248.6 ppbv in June, on average. The VOCs increases at receptors mainly consisted of ethane (3.1%–22.6%), propane (3.8%–11.3%), isobutane (8.5%–10.2%), n-butane (9.9%–13.2%), isopentane (6.1%–12.9%), n-pentane (5.1%–9.7%), propylene (6.1–11.1%) and 1-butylene (1.6%–5.4%). The chemical composition of the VOCs increases in this field monitoring was similar to that of VOCs emissions from China's refineries reported, which revealed that the ambient VOCs increases were predominantly contributed by this refinery. So, we used the ISC3 model to create the relationship coefficient γ for each receptor of each test. In result, the monthly VOCs emissions from this refinery were calculated to be 183.5 ± 89.0 ton in March and 538.3 ± 281.0 ton in June. The estimate in June was greatly higher than in March, chiefly because the higher environmental temperature in summer produced more VOCs emissions from evaporation and fugitive process of the refinery. Finally, the VOCs emission factors (g VOCs/kg crude oil refined) of 0.73 ± 0.34 (in March) and 2.15 ± 1.12 (in June) were deduced for this refinery, being in the same order with previous direct-measurement results (1.08–2.65 g VOCs/kg crude oil refined).An inverse-dispersion calculation method was applied to estimate VOCs emission rate for a petroleum refinery, being 183.5 ton/month (March) and 538.3 ton/month (June).

Microplastics, degraded and weathered polymer-based particles, and manufactured products ranging between 50 and 5000 μm in size, are found within marine, freshwater, and estuarine environments. While numerous peer-reviewed papers have quantified the ingestion of microplastics by marine vertebrates, relatively few studies have focused on microplastic ingestion by freshwater organisms. This study documents microplastic and manufactured fiber ingestion by bluegill (Lepomis macrochirus) and longear (Lepomis megalotis) sunfish (Centrarchidae) from the Brazos River Basin, between Lake Whitney and Marlin, Texas, USA. Fourteen sample sites were studied and categorized into urban, downstream, and upstream areas. A total of 436 sunfish were collected, and 196 (45%) stomachs contained microplastics. Four percent (4%) of items sampled were debris on the macro size scale (i.e. >5 mm) and consisted of masses of plastic, metal, Styrofoam, or fishing material, while 96% of items sampled were in the form of microplastic threads. Fish length was statistically correlated to the number of microplastics detected (p = 0.019). Fish collected from urban sites displayed the highest mean number of microplastics ingested, followed by downstream and upstream sites. Microplastics were associated with the ingestion of other debris items (e.g. sand and wood) and correlated to the ingestion of fish eggs, earthworms, and mollusks, suggesting that sunfish incidentally ingest microplastics during their normal feeding methods. The high frequency of microplastic ingestion suggest that further research is needed to determine the residence time of microplastics within the stomach and gut, potential for food web transfer, and adverse effects on wildlife and ecosystemic health.

Open burning of electronic waste (e-waste) releases various metals and organohalogen compounds in the environment. Here we investigated the interplay of metals (Cu, Pb, Zn, Fe, Co, and Sr) and bromine (Br) in the formation of dioxin-related compounds (DRCs), including polychlorinated dibenzo-p-dioxins/furans (PCDD/Fs) and dioxin-like polychlorinated biphenyls (DL-PCBs), as well as non-regulated DRCs such as polybrominated dibenzo-p-dioxins/furans (PBDD/Fs) and their monobrominated PCDD/Fs in soils sampled from open burning e-waste sites at Agbogbloshie in Accra, Ghana. The predominant DRCs were PBDFs, PCDFs, PCDDs, and DL-PCBs. Statistical analyzes, X-ray absorption spectroscopy, and the PCDF/PCDD ratio suggested possible formation paths of PCDD/Fs and DL-PCBs by catalytic behaviors of copper chlorides (CuCl, CuCl2, and Cu2(OH)3Cl) and thermal breakdown of polyvinyl chloride. Predominant formation of brominated furans may be derived from electron transfer from intermediates of PBDE to copper, Cu(II) → Cu(I). Lead chloride also contributed to generate DRCs and may become highly bioaccessible through the open burning of e-waste. The main zinc species (ZnCl2 and ZnS) suggested a possible relationship to generate DRCs and specific zinc source such as tire burning. Cu, Pb, Zn, and Br contained in various e-wastes, wires/cables, plastics, and tires strongly influenced generation of many DRCs.

The organohalogenated contaminants (OCs) including 12 organochlorine pesticides (OCPs), 7 indicator polychlorinated biphenyls (PCBs) and 7 polybrominated diphenyl ethers (PBDEs) were determined in soils collected from Kenya, Eastern Africa. The total OCPs fell in the range of n.d–49.74 μg kg⁻¹ dry weight (dw), which was dominated by DDTs and endosulfan. Identification of pollution sources indicated new input of DDTs for malaria control in Kenya. The total PCBs ranged from n.d. to 55.49 μg kg⁻¹ dw, dominated by penta- and hexa-PCBs, probably associated with the leakage of obsolete transformer oil. The soils were less contaminated by PBDEs, ranging from 0.19 to 35.64 μg kg⁻¹ dw. The predominant PBDE congeners were penta-, tri- or tetra-BDEs, varying among different sampling sites. Risk assessment indicated potential human health risks posed by OCs in soils from Kenya, with PCBs as the most contributing pollutants. The local authorities are recommended to make best efforts on management of OC pollution, particularly from DDTs and PCBs to meet the requirement of Stockholm Convention.