Along with monitoring air pollution level and rapid economic growth in China, the government has paid attention to the environmental policy innovation (EPI) capacity of local governments. However, scholarly research has not yet clarified the ability of local governments in EPI and its related drivers and impacts. This study explores the dynamic relations between EPI, air pollution, and the economy for the first time, using the simultaneous equation model (SEM) in China during 2006–2015 across 30 provinces. To calculate EPI, this study introduces the comprehensive concept of policy innovation, consisting of invention, diffusion, and evaluation. The results show that EPI is strongly promoted by air pollution; however, promoting EPI alone cannot decrease air pollution. These results would vary among eastern and western provinces. Economic growth has a significant positive effect on EPI and can significantly reduce air pollution. This study suggests policymakers strengthen EPI in order to achieve a balance between air pollution and economic growth.

The characterization of historical mine tailings provides important information for land-management decisions, in particular when considering potential reprocessing activities or the development of an environmental protection program. In addition, outcomes from such characterization may define the scope for a more detailed investigation. The present work describes the characterization of the waste material from the Cabeço do Pião tailings impoundment performed within the project ReMinE: Improve Resource Efficiency and Minimize Environmental Footprint. The purpose of the work was to investigate alternative mine waste management options such as the extraction of valuable resources from an environmental liability. The study involved the collection of 41 samples at different locations at two different depths, physical and chemical characterization of the wastes, natural leaching tests, and potential for acid generation. The results showed that, apart from the potential instability of the dyke (with an average slope of 35°), the drained solutions flowing by percolation contain very small particles with high arsenic contents that are being incorporated into the river sediments. In addition, these very fine-grained materials are available for the transport by the wind creating secondary sources of environmental contamination. This data is fundamental for economic and environmental assessment of the two main alternatives, reprocessing or removal.

Efficient and selective removal of antibiotics from wastewater is quite important but challenging. In this work, the nitrogen-doped mesoporous carbon nanospheres (NMCN) with different pore size (from 2.67 to 4.62 nm) were successfully prepared by changing the hydrothermal condition, and their removal performance on tylosin was evaluated. The adsorption experimental data were fitted well with the pseudo-second-order kinetic model. Besides, Langmuir isotherm model could better describe the adsorption process. Notably, the NMCN with medium pore size (3.36 nm) exhibited the highest adsorption capacity (1333 mg g⁻¹), which was 24% and 14% higher than that of NMCNs with smaller and larger pore size, respectively. In order to study the adsorption mechanism, the mesoporous carbon nanospheres without N-doped was prepared, and the comparison of nitrogen adsorption-desorption isotherms was conducted. The result proved that in addition to the modified surface property, large specific surface area, and high pore volume, the pore size could precisely influence the adsorption performance of the proposed adsorbent. Furthermore, the proposed NMCN material possessed a selective adsorbing ability toward tylosin in the presence of tetracycline. Clearly, the NMCN was a promising alternative to be used as high efficient and selective adsorbent in practical environment pollution treatment, especially in large-size molecule adsorption.

A passive sampling method based on diffusive gradients in thin films (DGT) using ceria oxide (CeO₂) binding gel was developed for in situ measurement of dissolved reactive phosphorus (DRP). CeO₂-based DGT showed excellent uptake performance for DRP, and the uptake mass was consistent with the predication by DGT equation. pH (4.2~9.4) and ionic strength (0.01~500 mM) had no effects on the uptake of DRP. Filed deployment of CeO₂-DGT in reservoir water and seawater showed that the measureable concentrations of DRP were comparable to those obtained by grab sampling. CeO₂-DGT was deployed in sewage sludge, and results showed the ratios (RS) between the concentration (CDGT) by CeO₂-DGT and the concentration (CS) obtained by a traditional centrifugation method ranged from 0.23 to 0.58. This result indicated that sludge solid phase was a potential pool of DRP in sludge solution, and the DRP released from sludge solid phase could compensate partly the consumption of DRP at the interface of DGT device during the deployment. The ratios RS had positive correlation with the content of Fe (r = 0.847, p < 0.01) but were reversed with the level of Ca (r = − 0.879, p < 0.01) in sewage sludge. The proposed method provided a powerful tool for in situ measurement of DRP in natural waters and for release behavior of DRP in sludge.

The physiological and biochemical responses of Sorghum bicolor (L.) Moench. to cadmium (Cd) (30 mg kg⁻¹) and oil sludge (OS) (16 g kg⁻¹) present in soil both separately and as a mixture were studied in pot experiments. The addition of oil sludge as a co-contaminant decreased Cd entry into the plant by almost 80% and simultaneously decreased the stimulation of superoxide dismutase (SOD) and peroxidase. The decrease in glutathione reductase (GR) activity and the increase in glutathione-S-transferase (GST) activity under the influence of oil sludge indicated that its components were detoxified by conjugation with glutathione. Cd additionally activated the antioxidant and detoxifying potential of the plant enzymatic response to stress. This helped to enhance the degradation rate of oil sludge in the rhizosphere, in which the participation of the root-released enzymes in the degradation could be possible. Cd increased the extent of soil clean-up from oil sludge, mainly owing to the elimination of paraffins, naphthenes, and mono- and bicyclic aromatic hydrocarbons. The mutual influence of the pollutants on the biochemical responses of sorghum and on soil clean-up was evaluated. The results are important for understanding the antistress and detoxification responses of the remediating plant to combined environmental pollution.

A rare super-large fractured karst aquifer located in Zibo city, Shandong Province of Northern China was polluted by petroleum hydrocarbons from a petrochemical company. Over the last 30 years, it has been the focus of several remediation efforts. In this study, the contamination and natural attenuation characteristics of the petroleum hydrocarbons were elucidated using hydrogeochemical indicators (DO, DOC, Cl⁻, HCO₃⁻, pH, NO₃⁻, and SO₄²⁻), petroleum hydrocarbons elements and environmental isotopes (δ¹⁵NNO₃, δ¹⁸ONO₃, δ¹³CDIC, and δ¹³CDOC). With the aid of GIS, statistical analyses, as well as first-order decay model and electron-acceptor-limited kinetic model, the spatio-temporal evolution characteristics of the petroleum hydrocarbons were modeled. Results showed a positive natural attenuation trend over the last 3 decades where intrinsic biodegradation mechanism was found to be the most important factor driving the degradation of hydrocarbons in the aquifer system. The hydrogeochemical association between the indicators and petroleum hydrocarbons provided the evidences of biodegradation and also served as markers, highlighting the occurrence of anaerobic respiration without methanogenic activities within the heterogenous karst media. Furthermore, the mean natural attenuation rate of petroleum hydrocarbons was calculated to be 3.76 × 10⁻³/day whereby the current highest petroleum hydrocarbons concentration (361.13 μg/L) is estimated to be degraded completely in 6 years under the present hydrogeological and environmental conditions.

A combined approach based on multiple X-ray analytical techniques and conventional methods was adopted to investigate the distribution and speciation of Cr in a polluted agricultural soil, from the bulk-scale down to the (sub)micro-level. Soil samples were collected from two different points, together with a control sample taken from a nearby unpolluted site. The bulk characterization revealed that the polluted soils contained much higher concentrations of organic matter (OM) and potentially toxic elements (PTE) than the control. Chromium was the most abundant PTE (up to 5160 g kg⁻¹), and was present only as Cr(III), as its oxidation to Cr(VI) was hindered by the high OM content. According to sequential extractions, Cr was mainly associated to the soil oxidisable fraction (74%) and to the residual fraction (25%). The amount of Cr potentially bioavailable for plant uptake (DTPA-extractable) was negligible. Characterization of soil thin sections by micro X-ray fluorescence (μXRF) and field emission scanning electron microscopy coupled with microanalysis (FEGSEM-EDX) showed that Cr was mainly distributed in aggregates ranging from tens micrometres to few millimetres in size. These aggregates were coated with an aluminosilicate layer and contained, in the inner part, Cr, Ca, Zn, P, S and Fe. Hyperspectral elaboration of μXRF data revealed that polluted soils were characterised by an exogenous organic-rich fraction containing Cr (not present in the control), and an endogenous aluminosilicate fraction (present also in the control), coating the Cr-containing aggregates. Analyses by high-resolution micro X-ray computed tomography (μCT) revealed a different morphology of the soil aggregates in polluted soils compared with the control. The finding of microscopic leather residues, combined with the results of bulk- and micro-characterizations, suggested that Cr pollution was likely ascribable to soil amendment with tannery waste-derived matrices. However, over the years, a natural process of Cr stabilization occurred in the soil thus reducing the environmental risks.

The objective of this study was to evaluate the effect of salinity on the acute and sub-chronic toxicity of silver nanoparticles (AgNPs) in Persian sturgeon. This was evaluated by exposing Persian sturgeon to AgNPs in three salinities: freshwater (F: 0.4 ppt), brackish water 1 (B₁: 6 ± 0.2 ppt), and brackish water 2 (B₂: 12 ± 0.3 ppt) for 14 days, which was followed by analysis of alterations in plasma chemistry and histopathology of the gills, liver, and intestine. Values of 96-h median lethal concentration (LC₅₀) were calculated as 0.89 mg/L in F, 2.07 mg/L in B₁, and 1.59 mg/L in B₂. After sub-chronic exposures, plasma cortisol, glucose, potassium, and sodium levels illustrated no significant changes within each salinity level. In F, 0.2 mg/L AgNP caused the highest levels of alkaline phosphatase and osmolality levels. In B₁, 0.6 mg/L AgNP induced the highest level of alkaline phosphatase and elevated plasma osmolality was recorded in all AgNP-exposed treatments in comparison with the controls. The B₂ treatment combined with 0.6 mg/L AgNP significantly reduced plasma chloride level. The results showed elevating salinity significantly increased osmolality, chloride, sodium, and potassium levels of plasma in the fish exposed to AgNPs. The abundance of the tissue lesions was AgNP concentration-dependent, where the highest number of damages was observed in the gills, followed by liver and intestine, respectively. The histopathological study also confirmed alterations such as degeneration of lamella, lifting of lamellar epithelium, hepatic vacuolation, pyknotic nuclei, and cellular infiltration of the lamina propria elicited by AgNPs in the gills, liver, and intestine of Persian sturgeon. In conclusion, the stability of AgNPs in aquatic environments can be regulated by changing the salinity, noting that AgNPs are more stable in low salinity waters.

This study reports the physicochemical characterization of clover (Trifolium hybridum) and citrus (Citrus sinensis) honeys produced in Fayoum, Egypt, by evaluating the analysis of moisture content, pH, total soluble solids (TSS), electric conductivity (EC), total sugars, crude protein, ash content, total acidity, hydroxymethylfurfural (HMF), and total phenolic compounds (TPC). Antioxidant and antimicrobial activities of honey extracts and their flower extracts were determined. The results clearly indicated that ethanol gave the highest extraction yield of both clover and citrus flowers, while ethyl acetate showed the highest extraction recovery for the phenolic compounds, with TPC amounting to 338.5 and 536.4 mg gallic acid equivalent kg⁻¹ fresh weight in clover and citrus flower extracts, respectively. Honey samples have less TPC than their flowers. The results showed that the TPC of citrus honey and its flowers was higher than clover honey and its flowers, respectively. Antioxidant activity was higher in extracts obtained from citrus flower than extracts of clover flower. The same trend was noticed for honey samples. Both clover and citrus honeys showed antimicrobial effects against tested microorganisms. HPLC analysis showed that p-coumaric acid was the main phenolic component in ethanol extracts of clover and citrus honeys, contributing about 83.0% and 52.2%, respectively. In citrus and clover flower extracts, syringic acid and quercetin were the main phenolics, respectively. It would be expected that characteristics of honey samples are mainly depended on the floral origin of nectar foraged by bees.

For the first time, National Health and Nutrition Examination Survey released data on ethylene oxide (ETO) into public domain for US children aged 6–11 years, adolescents aged 12–19 years, and adults aged ≥ 20 years for 2013–2016. This study was undertaken to evaluate the associations between concentrations of ETO in whole blood and smoking, exposure to environmental tobacco smoke (ETS), and self-reported diagnosis of cancers including breast cancer. Both adolescent (29.6 vs. 49.6 pmol/g Hb, p < 0.01) and adult smokers (31.5 vs. 142.7 pmol/g Hb, p < 0.01) were found to have substantially higher adjusted levels of ethylene oxide than nonsmokers. Non-Hispanic blacks had higher levels of ethylene oxide than other race/ethnicities for children and adolescents. Non-Hispanic Asians had higher levels of ethylene oxide than other race/ethnicities for adults. Exposure to ETO measured by the number of smokers smoking inside the home (p < 0.01) and number of days smokers smoked inside the home (p = 0.03) during the prior week was found to be associated with elevated levels of ETO (p < 0.01) among US adults. Increased age was associated with elevated levels of ETO among adolescents (p = 0.02) and adults (p < 0.01) but the reverse was true for children (p = 0.04). For the general US population, levels of ETO were not found to be associated with cancers including breast cancer.