Se han estudiado emulsiones de calidad alimentaria aceite en agua estabilizadas por un palmitato de sacarosa de HLB=15. Dichas emulsiones se fabricaron a concentraciones comprendidas entre el 60 y el 80 por ciento (p/p) en peso de aceite vegetal con un 1-5 por ciento (p/p) en peso del sucroester empleado como emulsionante. Para llevar a cabo este estudio se realizaron ensayos de crecimiento del esfuerzo, flujo estacionario y cizalla oscilatoria. Todos los sistemas estudiados presentan un comportamiento tixotropico en flujo transitorio. Bajo determinadas condiciones, la cizalla puede hacer que el esfuerzo vuelva a aumentar con el tiempo tras haber alcanzado un valor pseudoestacionario. Este hecho se ha relacionado con una redistribucion de tamanos de gota como consecuencia de la cizalla. Como resultado, la cizalla provoca una intensa destruccion estructural en los sistemas estudiados, no pudiendose ajustar la ecuacion de Arrhenius a todo el intervalo de temperaturas estudiado.

Interest in both environmental impact and potential beneficial uses of produced water (PW) has increased with growth in unconventional oil and gas production, especially in semi-arid regions, e.g. the Permian Basin, the most productive tight-oil region in the USA. Characterization of PW compositional variability is needed to evaluate environmental impact, treatment, and reuse potential. Geochemical variability of PW from Guadalupian (Middle Permian) to Ordovician formations was statistically and geostatistically evaluated in the western half of the Permian Basin (Delaware Basin, Central Basin Platform, and Northwest Shelf) using the US Geological Survey’s Produced Waters Geochemical Database and the New Mexico Water and Infrastructure Data System. Mean total dissolved solids (TDS) of PW increased with depth in the Delaware Basin and Central Basin Platform to the Delaware and Wolfcamp formations (Guadalupian age). Mean TDS decreased with further increases in depth. In contrast, the mean salinity of PW was significantly higher within the shallow, younger formations (largest mean TDS in the Artesia Formation); TDS decreased with depth below Guadalupian age formations in the Northwest Shelf. Kriged contour maps of TDS and major ions illustrated spatial variability across the three geo-structural regions as a function of depth. The occurrence of meteoric waters in upper and deeper formations across the three regions was significant, and was attributed to Laramide Orogeny and Basin and Range extension uplifting and tilting effects and recent water flooding. These results quantify PW composition variability, and suggest that upon treatment, PW would support some uses such as onsite reuse and mining.

A combined simulation-optimization model was developed to minimize the freshwater footprint at multi-well hydraulic fracturing sites. The model seeks to reduce freshwater use by blending it with brackish groundwater and recovered water. Time-varying water quality and quantity mass balance expressions and drawdown calculations using the Theis solution along with the superposition principle were embedded into the optimization model and solved using genetic algorithms. The model was parameterized for representative conditions in the Permian Basin oil and gas play region with the Dockum Formation serving as the brackish water source (Texas, USA). The results indicate that freshwater use can be reduced by 25–30 % by blending. Recovered water accounted for 2–3 % of the total blend or 10–15 % of total water recovered on-site. The concentration requirements of sulfate and magnesium limited blending. The evaporation in the frac pit constrained the amount blended during summer, while well yield of the brackish (Dockum) aquifer constrained the blending during winter. The Edwards-Trinity aquifer provided the best quality water compared to the Ogallala and Pecos Valley aquifers. However, the aquifer has low diffusivity causing the drawdown impacts to be felt over large areas. Speciation calculations carried out using PHREEQC indicated that precipitation of barium and strontium minerals is unlikely in the blended water. Conversely, the potential for precipitation of iron minerals is high. The developed simulation-optimization modeling framework is flexible and easily adapted for water management at other fracturing sites.

In southern Iran’s Gareh Bygone Plain, water-supply qanats in four mixed farming communities were desiccated by over-pumping of illegal dug wells throughout the area. Emergency situations developed, resulting in city-ward migration. Since 1983, 193 million m³ of water has been supplied to those communities by floodwater spreading (FWS) to facilitate spate irrigation of sandy rangeland (2,034 ha) and artificial recharge of groundwater (ARG), of which 76 % has recharged the aquifer. This resulted in a reverse migration of the population. The irrigated area in the 2010–2011 growing season increased 13.2 fold when compared to the pre-FWS period, and year-round forage for about 700 sheep has been provided since 1991. The ARG is a logical alternative to building large dams in Iran; 420,000 km² of coarse-grained alluvium provides capacity to store 5,000 km³ of water, representing more than ten times the annual precipitation of the whole country. As the equivalent cost for building dams to accommodate that volume is estimated at US$12.5 × 10¹², the potential value of the alluvium may be realized. ARG on the recharge areas of 33,000 of the desiccated qanats eventually could rejuvenate them. As agricultural commodities absorb 19 % of the monetary value of Iran’s imports, and ARG activities could supply the water to produce them, alluvium is even more valuable than oil, which provides foreign exchange. More importantly, ARG on 140,000 km² of the alluvium could strengthen the capacity to adapt to droughts and reduce the number and impact of water-related emergency situations.

Dissolved methane concentrations in shallow groundwater are known to vary both spatially and temporally. The extent of these variations is poorly documented although this knowledge is critical for distinguishing natural fluctuations from anthropogenic impacts stemming from oil and gas activities. This issue was addressed as part of a groundwater research project aiming to assess the risk of shale gas development for groundwater quality over a 500-km² area in the St. Lawrence Lowlands (Quebec, Canada). A specific study was carried out to define the natural variability of methane concentrations and carbon and hydrogen isotope ratios in groundwater, as dissolved methane is naturally ubiquitous in aquifers of this area. Monitoring was carried out over a period of up to 2.5 years in seven monitoring wells. Results showed that for a given well, using the same sampling depth and technique, methane concentrations can vary over time from 2.5 to 6 times relative to the lowest recorded value. Methane isotopic composition, which is a useful tool to distinguish gas origin, was found to be stable for most wells, but varied significantly over time in the two wells where methane concentrations are the lowest. The use of concentration ratios, as well as isotopic composition of methane and dissolved inorganic carbon (DIC), helped unravel the processes responsible for these variations. This study indicates that both methane concentrations and isotopic composition, as well as DIC isotopes, should be regularly monitored over at least 1 year to establish their potential natural variations prior to hydrocarbon development.

Groundwater total dissolved solids (TDS) distribution was mapped with a three-dimensional (3D) model, and it was found that TDS variability is largely controlled by stratigraphy and geologic structure. General TDS patterns in the San Joaquin Valley of California (USA) are attributed to predominantly connate water composition and large-scale recharge from the adjacent Sierra Nevada. However, in smaller areas, stratigraphy and faulting play an important role in controlling TDS. Here, the relationship of stratigraphy and structure to TDS concentration was examined at Poso Creek Oil Field, Kern County, California. The TDS model was constructed using produced water TDS samples and borehole geophysics. The model was used to predict TDS concentration at discrete locations in 3D space and used a Gaussian process to interpolate TDS over a volume. In the overlying aquifer, TDS is typically <1,000 mg/L and increases with depth to ~1,200–3,500 mg/L in the hydrocarbon zone below the Macoma claystone—a regionally extensive, fine-grained unit—and reaches ~7,000 mg/L in isolated places. The Macoma claystone creates a vertical TDS gradient in the west where it is thickest, but control decreases to the east where it pinches out and allows freshwater recharge. Previously mapped normal faults were found to exhibit inconsistent control on TDS. In one case, high-density faulting appears to prevent recharge from flushing higher-TDS connate water. Elsewhere, the high-throw segments of a normal fault exhibit variable behavior, in places blocking lower-TDS recharge and in other cases allowing flushing. Importantly, faults apparently have differential control on oil and groundwater.

Variability in baseline groundwater methane concentrations and isotopic compositions was assessed while comparing free and dissolved gas sampling approaches for a groundwater monitoring well in Alberta (Canada) over an 8-year period. Methane concentrations in dissolved gas samples (n = 12) were on average 4,380 ± 2,452 μg/L, yielding a coefficient of variation (CV) >50 %. Methane concentrations in free gas samples (n = 12) were on average 228,756 ± 62,498 ppm by volume, yielding a CV of 27 %. Quantification of combined sampling, sample handling and analytical uncertainties was assessed via triplicate sampling (CV of 19 % and 12 % for free gas and dissolved gas methane concentrations, respectively). Free and dissolved gas samples yielded comparable methane concentration patterns and there was evidence that sampling operations and pumping rates had a marked influence on the obtained methane concentrations in free gas. δ¹³CCH₄ and δ²HCH₄ values of methane were essentially constant (−78.6 ± 1.3 and −300 ± 3 ‰, respectively) throughout the observation period, suggesting that methane was derived from the same biogenic source irrespective of methane concentration variations. The isotopic composition of methane constitutes a robust and highly valuable baseline parameter and increasing δ¹³CCH₄ and δ²HCH₄ values during repeat sampling may indicate influx of thermogenic methane. Careful sampling and analytical procedures with identical and repeatable approaches are required in baseline-monitoring programs to generate methane concentration and isotope data for groundwater that can be reliably compared to repeat measurements once potential impact from oil and gas development, for example, may occur.