In this work, the effect of copper and zinc on green alga Pseudokirchneriella subcapitata was evaluated through catalase activity, lipid peroxidation by TBARS essay, growth rate, and the chlorophyll-a concentration. Catalase activity increased significantly (P < 0.05) in comparison to the control at 0.1 mg L-1 copper and 0.075 mg L-1 zinc, whereas the damage to the cell membrane expressed as nmols/10(6)cell of malondialdehyde increased significantly (P < 0.05) at 0.025 mg L-1 copper and 0.1 mg L-1 zinc. On the other hand, a significant (P < 0.05) decrease in chlorophyll-a concentration was found at 0.075 mg L-1 of both metals. The results showed that catalase activity, lipid peroxidation, and chlorophyll-a concentration were more sensitive to metals than the growth rate.<br>En este trabajo, se evaluó el efecto del cobre y zinc en la alga verde Pseudokirchneriella subcapitata a través de la actividad catalasa, peroxidación lipídica por el ensayo TBARS, tasa de crecimiento y concentración de clorofila-a. La actividad catalasa aumentó significativamente (P < 0,05) en comparación al control en 0,1 mg L-1 y 0,075 mg L-1 de cobre y zinc respectivamente, mientras que el daño en la membrana celular expresado en nanomols/10(6) células de malondialdehído aumentó significativamente en 0,025 mg L-1 y 0,1 mg L-1 de cobre y zinc respectivamente. Por otra parte, hubo una disminución significativa (P < 0,05) en la concentración de clorofila-a en ambos metales a 0,075 mgL-1. Los resultados mostrados en actividad catalasa, peroxidación lipídica y concentración de clorofila-a son parámetros más sensibles que la tasa de crecimiento a los metales.

This study investigated the use of three-dimensional (3D) geological methods to provide better groundwater resource estimates for the Spring Hill area in central Victoria, Australia. Geological data were gathered in 3D geological software, which was utilised to derive fundamental dimensional parameters of the groundwater system in the study area. Mining industry software and hydrogeological methods were combined to give volumetric determinations of the basalt aquifer that were used to improve estimates of the groundwater resource. The methods reduce uncertainty about the physical attributes of the aquifer systems and greatly improve conceptual understanding of their behaviour. A simple numerical water-balance model was developed to refine the estimates of aquifer volume and fluxes to approximate observed water-level behaviour in the area. This enabled a much better comparison of groundwater resource use to the natural inputs and outputs for the area. A key conclusion was that the main issues for sustainable development and use in the study area are more to do with the physical aspects of the aquifer system, rather than simply the volume of water pumped. Visualisations of the area’s hydrogeology also provide improved hydrogeological understanding and communication for groundwater users and administrators.

Karst aquifers are characterized by high heterogeneity and spatial variability of hydrogeological parameters. Time-series analysis of rainfall and discharge (as input and output functions), including correlation, cross-amplitude, phase and coherency, was applied to the Houzhai karstic water system in Guizhou Province, southwest China, in order to study the function, hydrodynamic behavior and hydraulic properties of the aquifer system. Autocorrelation and cross-correlation of the variables showed that the degree of sensitivity of the system to the rainfall input signal decreased gradually from the upstream to the downstream sections, but the memorizing action increased gradually. Analysis of the phase function showed that there is a lag in the discharge response to the rainfall input signal. The lag time increased gradually from the upstream to the downstream sections, and the degree of the linearity upstream is higher than downstream. The quick-flow and slow-flow components were also divided in the cross-amplitude analysis. The results showed that about 60% of spring discharge in the upstream section was quick flow. The quick-flow component downstream reduced to only 5%. The main control factors of the karst-system response are the karst geomorphology and the inner origination structure of the karstic multi-medium.

The capture zone for a fully penetrating well in an aquifer with regional flow to a stream boundary under steady-state conditions was delineated using complex algebra and image well theory. Regional flow in the aquifer was allowed to take different directions relative to the stream axis. Two critical pumping rates, Q C1 and Q C2, produce three capture-zone pattern scenarios: (1) at low pumping rates (Q < Q C1) water is solely withdrawn from the aquifer and no water from the stream enters the aquifer, (2) at medium pumping rates (Q C1 < Q < Q C2) a portion of stream water enters the aquifer but it is not captured by the well, and (3) at high pumping rates (Q > Q C2) pumped water is supplied from both the aquifer and the stream with different proportions. For the second and third scenarios, the stream length interval through which stream water enters the aquifer was determined and found to be more sensitive to pumping rate as the regional flow direction approaches the stream axis. The portion of pumped water supplied by the stream was determined in the third scenario. Finally, the capture-zone asymmetry with respect to its axial line was delineated.

Crystalline aquifers of semi-arid southern India represent a vital water resource for farming communities. A field study is described that characterizes the hydrodynamic functioning of intensively exploited crystalline aquifers at local scale based on detailed well monitoring during one hydrological year. The main results show large water-table fluctuations caused by monsoon recharge and pumping, high spatial variability in well discharges, and a decrease of well yields as the water table decreases. Groundwater chemistry is also spatially variable with the existence of aquifer compartments within which mixing occurs. The observed variability and compartmentalization is explained by geological heterogeneities which play a major role in controlling groundwater flow and connectivity in the aquifer. The position of the water table within the fracture network will determine the degree of connectivity between aquifer compartments and well discharge. The presented aquifer conceptual model suggests several consequences: (1) over-exploitation leads to a drop in well discharge, (2) intensive pumping may contribute to the hydraulic containment of contaminants, (3) groundwater quality is highly variable even at local scale, (4) geological discontinuities may be used to assist in the location of drinking-supply wells, (5) modeling should integrate threshold effects due to water-table fluctuations.

Temperature distribution and heat transport are studied in a coastal aquifer at De Panne in the western Belgian coastal plain. Field observations include temperature profiles of groundwater in the dunes and temperature measurements at the water table in a profile on the shore. Freshwater–saltwater distribution is known from previous studies. These are used to constrain a density-dependent model simulating the freshwater–saltwater distribution and heat transport using the SEAWAT code. The yearly fluctuation of the groundwater temperature in the phreatic aquifer under the dunes, shore and sea, and the influence of a tidal inlet in the dunes are simulated. The observations show that seawater temperature variations determine the temperature variations on the shore whereas atmospheric temperature changes determine this in the dunes. Yearly temperature fluctuations imposed at the water table propagate mainly vertically in the aquifer with only limited lateral influence. Heat transport is mainly convection dominated. Thickness of the surficial zone is determined by the amplitude of the groundwater temperature at the water table and the groundwater flow. Establishment of a tidal inlet in the dunes results in asymmetric temperature profiles under and in the vicinity of it.

Agricultural contamination of groundwater in northwestern Mississippi, USA, has not been studied extensively, and subsurface fluxes of agricultural chemicals have been presumed minimal. To determine the factors controlling transport of nitrate-N into the Mississippi River Valley alluvial aquifer, a study was conducted from 2006 to 2008 to estimate fluxes of water and solutes for a site in the Bogue Phalia basin (1,250 km2). Water-quality data were collected from a shallow water-table well, a vertical profile of temporary sampling points, and a nearby irrigation well. Nitrate was detected within 4.4 m of the water table but was absent in deeper waters with evidence of reducing conditions and denitrification. Recharge estimates from 6.2 to 10.9 cm/year were quantified using water-table fluctuations, a Cl– tracer method, and atmospheric age-tracers. A mathematical advection-reaction model predicted similar recharge to the aquifer, and also predicted that 15% of applied nitrogen is leached into the saturated zone. With current denitrification and application rates, the nitrate-N front is expected to remain in shallow groundwater, less than 6–9 m deep. Increasing application rates resulting from intensifying agricultural demands may advance the nitrate-N front to 16–23 m, within the zone of groundwater pumping.

The analysis of pre-existing landslides and landslide-prone hillslopes requires an estimation of maximum groundwater levels. Rapid increase in groundwater levels may be a dominant factor for evaluating the occurrence of landslides. System identification—use of mathematical tools and algorithms for building dynamic models from measured data—is adopted in this study. The fluid mass-balance equation is used to model groundwater-level fluctuations, and the model is analytically solved using the finite-difference method. Entropy-based classification (EBC) is used as a data-mining technique to identify the appropriate ranges of influencing variables. The landslide area at Wushe Reservoir, Nantou County, Taiwan, is chosen as a field test site for verification. The study generated 65,535 sets of numbers for the groundwater-level variables of the governing equation, which is judged by root mean square errors. By applying cross-validation methods and EBC, limited numbers of validation samples are used to find the range of each parameter. For these ranges, a heuristic method is employed to find the best results of each parameter for the prediction model of groundwater level. The ranges for governing factors are evaluated and the resulting performance is examined.

In a 2,700-km2 area in the eastern San Joaquin Valley, California (USA), data from multiple sources were used to determine interrelations among hydrogeologic factors, reduction-oxidation (redox) conditions, and temporal and spatial distributions of nitrate (NO3), a widely detected groundwater contaminant. Groundwater is predominantly modern, or mixtures of modern water, with detectable NO3 and oxic redox conditions, but some zones have anoxic or mixed redox conditions. Anoxic conditions were associated with long residence times that occurred near the valley trough and in areas of historical groundwater discharge with shallow depth to water. Anoxic conditions also were associated with interactions of shallow, modern groundwater with soils. NO3 concentrations were significantly lower in anoxic than oxic or mixed redox groundwater, primarily because residence times of anoxic waters exceed the duration of increased pumping and fertilizer use associated with modern agriculture. Effects of redox reactions on NO3 concentrations were relatively minor. Dissolved N2 gas data indicated that denitrification has eliminated >5 mg/L NO3–N in about 10% of 39 wells. Increasing NO3 concentrations over time were slightly less prevalent in anoxic than oxic or mixed redox groundwater. Spatial and temporal trends of NO3 are primarily controlled by water and NO3 fluxes of modern land use.