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The Modeling of Nitrogen Mass Transport in CoCr Alloys
2016
Petraitienė, Akvilė
The kinetics of plasma nitriding of CoCr alloy below temperatures of nitrides formation and mechanisms of nitrogen penetration are analyzed by proposed kinetic modeling in this article. Proposed nitrogen diffusion model is based on the trapping – detrapping (TD) model and developed taking into account the effect of the concentration dependent diffusivity of nitrogen, nitrogen adsorption on the surface of alloy and surface swelling process. The model indicates the influence of chromium atoms to nitrogen atoms diffusivity. The model consists of time and depth dependent diffusion, which is described by a partial differential equation, and it is solved by using Crank – Nicolson finite difference method. By fitting of experimental nitrogen depth profiles, it is shown that nitrogen diffusion coefficient varies with nitrogen concentration according to Einstein-Smoluchowski relation. Nitrogen depth profiles in plasma nitrided medical grade CoCr alloy (ISO 5831 – 12) at T = 400 °C for 1, 4 and 20 hours calculated on the basis of this model are in good agreement with experimental nitrogen profiles. Furthermore, the swelling process is showed and analyzed, derived the dependency of swelling rate on nitriding duration – the swelling rate is inversely proportional to the square root of nitriding duration. The obtained diffusion coefficient value and the swelling process rates satisfy the experimental data form Ref. The derived model explains physical processes during plasma nitriding and allows obtaining nitrogen depth profiles for any requisite nitriding duration.
اظهر المزيد [+] اقل [-]Disparity in Discolouration of Thermally Modified Wood Exposed to Solar and Artificial Ultraviolet Irradiation
2016
Cirule, Dace | Kuka, Edgars | Antons, Andis
Artificial weathering is a widely used method for predicting wood behaviour during its service life. A study was carried out to compare the colour change of thermally modified aspen (Populus tremula L.) and grey alder (Alnus incana (L.) Moench) wood during natural solar and artificial ultra violet (UV) irradiation. Thermally modified wood specimens were exposed for 30 h to artificial UV irradiation at two different intensities, i.e.1.36 W m⁻² at 340 nm and 0.68 W m⁻² at 340 nm, as well as to solar irradiation outdoors and indoors. After 2.5, 5 and 10 h exposure, colour parameters and reflectance spectra (360–740 nm) were determined. Colour was expressed in accordance with the CIELAB colour model as colour parameters L*, a*, b*. The total colour change ΔEab was calculated from colour parameter differences ΔL*, Δa*, Δb*. The colour changes caused by solar and artificial UV irradiation had a similar pattern for both thermally modified hardwood species under study. Changes in the individual colour parameters in the course of the experiment altered their direction, which implies that discolouration of thermally modified wood is a complicated and dynamic process with various and different chemical transformations in wood chromophores. Colour and reflectance changes had similar trends for different intensities of the same type of irradiation, but they differed for various irradiation types – natural solar or artificial UV irradiation. Greater discolouration was detected for the specimens exposed to both solar irradiations - outdoors and indoors. The results suggest that the fluorescent lamps of the UVA-340 type, which only imitate well the sunlight UV spectrum from 290 nm to 365 nm, do not fully simulate the changes in thermally modified wood induced by solar radiation.
اظهر المزيد [+] اقل [-]Analysis of the non Isothermal Distributed Activation Energy Model for Biomass Pyrolysis by Fuzzy Gaussian Distribution
2016
Dhaundiyal, Alok | Singh, Suraj B.
The main aim of this paper is to fuzzify the kinetic parameters, which have crisp nature, in order to obtain the realistic and accurate results. In the present study, the variance, upper limit of ‘dE’ and the frequency factor are assumed to be fuzzy numbers. The Gaussian distribution is considered as the distribution function, f (E), of Distributed Activation Energy Model (DAEM). The membership and the non-membership functions are evaluated by the trapezoidal fuzzy number. Thermo-analytical data has been found experimentally with the help of TGA/DTG analysis. The approximated solution of DAEM is obtained with the help of asymptotic expansion.
اظهر المزيد [+] اقل [-]The modeling of nitrogen mass transport in CoCr alloys
2016
Petraitiene, A., Aleksandras Stulginskis Univ., Akademija, Kauno reg. (Lithuania). Centre of Mathematics, Physics and Information Technologies
The kinetics of plasma nitriding of CoCr alloy below temperatures of nitrides formation and mechanisms of nitrogen penetration are analyzed by proposed kinetic modeling in this article. Proposed nitrogen diffusion model is based on the trapping – detrapping (TD) model and developed taking into account the effect of the concentration dependent diffusivity of nitrogen, nitrogen adsorption on the surface of alloy and surface swelling process. The model indicates the influence of chromium atoms to nitrogen atoms diffusivity. The model consists of time and depth dependent diffusion, which is described by a partial differential equation, and it is solved by using Crank – Nicolson finite difference method. By fitting of experimental nitrogen depth profiles, it is shown that nitrogen diffusion coefficient varies with nitrogen concentration according to Einstein-Smoluchowski relation. Nitrogen depth profiles in plasma nitrided medical grade CoCr alloy (ISO 5831 – 12) at T = 400 °C for 1, 4 and 20 hours calculated on the basis of this model are in good agreement with experimental nitrogen profiles. Furthermore, the swelling process is showed and analysed, derived the dependency of swelling rate on nitriding duration – the swelling rate is inversely proportional to the square root of nitriding duration. The obtained diffusion coefficient value and the swelling process rates satisfy the experimental data form Ref. The derived model explains physical processes during plasma nitriding and allows obtaining nitrogen depth profiles for any requisite nitriding duration.
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