Gluing of wood with great moisture content has challenge of water interaction with glue to give unwanted changes in glue properties and formed bond-line. Rheological measurements of polyurethane glues are sufficiently effective method to understand the polymer curing process and viscoelastic properties. Gel formation point is important parameter for a glue from the point of its application. When glue reaches the gel formation point, its viscosity drastically increases so that it could not properly wet the wood and it can result in poor bonds. One-component moisture curing polyurethane glues require water molecules for the polyadditional reaction. When water is involved in the curing reaction, it reacts with the isocyanate groups of glue and can lead to the formation of excessive carbon dioxide and thus can lead to glue penetration out of bond-line, additional backpressure. The dynamic viscoelastic parameters such as complex dynamic viscosity (ή), phase angle (δ), elastic storage modulus (G”), the viscous loss modulus (G”) of two kinds of polyurethane glues depending on added water amount (from 0.9% to 10.0%) at a constant frequency and deformation (oscillation mode) were determined using rheometer. The aim of the present study was to investigate impact of added water on rheological behavior of polyurethane glues. At the end of this study it was concluded that tested glues indicated various behavior depending on chemical composition and added water content. Gel formation point is higher in case of GlueI. However, gel formation time was higher in case of GlueII and was not dependent on added water content. Gel formation time was faster for GlueII. Nevertheless, faster formed gel is stronger than longer formed gel of GlueI.

Wood-based ash landfilling is increasing issue not only in Latvia but in the whole world as more biomass is used for energy production. Utilization of wood burning waste as fertilizer is already used worldwide, but there is lack of information about chemical composition of wood ash obtained from Latvia plants, so the aim of this study was to determine chemical composition and analyse possible utilization options of wood-based ash from Latvia plants. Therefore wood ash samples from 53 companies were collected, sieved and chemical composition of samples was determined. It was concluded that within higher capacity of furnace more coarse fraction of wood ash was observed which is less valuable as fertilizer. Wood ash is good liming material consisting alkali compounds and other biogenic elements but also heavy metals, which are pollutants and could cause environmental problems.