Beckmann Rearrangement of Ketoximes Induced by Phenyl Dichlorophosphate at Ambient Temperature
2012
Chun-Wei Kuo | Min-Tsang Hsieh | Shijay Gao | Yi-Ming Shao | Ching-Fa Yao | Kak-Shan Shia
Upon treatment with phenyl dichlorophosphate (PhOP=OCl2) in acetonitrile at ambient temperature, a variety of ketoximes underwent a Beckmann rearrangement in an effective manner to afford the corresponding amides in moderate to high yields.
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