Gas-Phase Kinetics Measurements for Underwater Explosives.

Fontiin, Authur

Gas-Phase Kinetics Measurements for Underwater Explosives.

1997

Fontiin, Authur

To aid in the development of boron-enhanced fluoronitramino explosives, the kinetics of individual reactions are measured over wide temperature ranges. The following rate expressions, in cu cm/ molecule/s, were obtained. For BO2 + H2 (right arrow) HOBO + H k(500-1250 K) = 3.6x10(exp -11)exp(-4198 K/T), for BO + CO2 (right arrow) BO2 + CO k(780-1200 K) <2.7x10(exp -14), for BO2 + CO (right arrow) BO + CO2 k(1000 K) < 6.0x10(exp -14), for BO + O2 (right arrow) BO2 + O k(300-960 K) = 7.9x10(exp -12)exp(161 K/T).

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AGROVOC Keywords

explosions nitrogen oxides reaction kinetics temperature

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Other Subjects

*underwater explosions; Pe61153n; Physical chemistry; Inorganic chemistry; Phase; Fluoro-nitramino; Nitramino; *fluorine; *boron; Carbon dioxide.; *reaction kinetics; Marine engineering; *gas flow; *explosives; Molecules

Language

English

License

http://handle.dtic.mil/100.2/ADA315459APPROVED FOR PUBLIC RELEASE

Source

RENSSELAER POLYTECHNIC INST TROY NY DEPT OF CHEMICAL ENGINEERINGDTIC AND NTIS

Corporate Author

RENSSELAER POLYTECHNIC INST TROY NY DEPT OF CHEMICAL ENGINEERING

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Gas-Phase Kinetics Measurements for Underwater Explosives.

1997

AGROVOC Keywords

Bibliographic information