Effect of Sodium Hydroxide/Urea/Deionised Water Solution Ratio on the Solubility of Oil Palm Empty Fruit Bunches Extracted Biocellulose
2021
Teow Yeit Haan | MAHA MOHAMMAD AL-RAJABI
Biocellulose extracted from oil palm empty fruit bunches (OPEFB) is attracting increased research interest in versatile applications as an alternative material to synthetic cellulose. Normally, biocellulose needs to undergo dissolution prior its applications. Among all explored solvents to dissolve biocellulose, aqueous sodium hydroxide (NaOH)/urea solution is gaining increased attention. OPEFB biocellulose solubility in NaOH/urea/deionised (DI) water solution has not been fully studied by researchers. This study aimed to investigate the solubility of OPEFB biocellulose in NaOH/urea/DI water solution by manipulating the NaOH/urea/DI water solution ratio and weight percentage of OPEFB biocellulose. Results indicated that increasing the NaOH/urea/DI water solution ratio increased the solubility of OPEFB biocellulose. Further increased NaOH/urea/DI water solution ratio resulted in decreased solubility. Meanwhile, increased OPEFB biocellulose weight percentage decreased the solubility of OPEFB biocellulose in NaOH/urea/DI water solution. The highest solubility of 70.89%±1.85% was exhibited by 7% NaOH/12% urea/81% DI water (w/w) solution and 1 w/v% OPEFB biocellulose. This study on OPEFB biocellulose solubility in NaOH/urea/DI water solution can promote cost-effective and wide utilisation of the abundantly available OPEFB for the synthesis of cellulose fibres, films, and hydrogels in the textile, packaging, and biomedical industries.
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