A new generation of ecocatalysts$^{\text{®}}$—from Invasive Alien Species to sustainable and biosourced glyceryl fatty esters
2024
Lasbleiz, Arthur | Pelissier, Franck | Renault, Jean-Hugues | Grison, Claire M. | Legrand, Yves-Marie | Grison, Claude
A new generation of ecocatalysts$^{\text{®}}$ derived from Invasive Alien Species (IAS) (Fallopia japonica and Arundo donax) was used as starting material for the preparation of novel biosourced catalysts. The preparation of these ecocatalysts$^{\text{®}}$ is a new way to support the management of IAS. These catalysts were characterized by microwave plasma atomic emission spectrometry (MP-AES) and X-ray powder diffraction (XRPD), which revealed basic properties. After calculating Pearson’s correlations to evaluate the relative importance of reaction parameters, a design of experiments (DoE) was implemented to synthesize glyceryl caprylate and oleate with a high selectivity. These molecules constitute emollients and non-ionic emulsifiers of high industrial interest. The ecocatalysts$^{\text{®}}$ were efficient and recyclable for the transesterification of methyl and ethyl fatty esters, leading to high yields (66–83%). These ecocatalysts$^{\text{®}}$ are an alternative to usual base catalysts previously reported for the transesterification of methyl caprylate, methyl oleate and ethyl caprylate with glycerol, which are often non-recyclable, not systematically selective and require questionable preparation conditions.
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