Total synthesis of (±)-maistemonine and (±)-stemonamide
2011
Chen, Zhi-Hua | Zhang, Yong-Qiang | Chen, Zhi-Min | Tu, Yong-Qiang | Zhang, Fu-Min
The first total synthesis of polycyclic Stemona alkaloid maistemonine has been achieved. The efficient approach features a stereoselective intramolecular Schmidt reaction, a ketone–ester condensation, and a Reformatsky reaction. Additionally, another Stemona alkaloid stemonamide was divergently synthesized from a common intermediate.
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