Ruthenium complexes of sterically-hindered pentaarylcyclopentadienyl ligands
2021
Asato, Ryosuke | Martin, Colin J. | Gisbert, Yohan | Abid, Seifallah | Kawai, Tsuyoshi | Kammerer, Claire | Rapenne, Gwénaël
The synthesis of ruthenium complexes incorporating an overcrowded pentaarylcyclopentadienyl ligand has been investigated, and higher efficiency has been reached using chlorine-functionalised precursors when compared with their brominated counterparts. A new methodology for the preparation of chlorocyclopentadienes has been developed which is well adapted for highly sterically hindered compounds and works with either electron rich or poor systems.
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