Unique catalysis of gold nanoparticles in the chemoselective hydrogenolysis with H₂: cooperative effect between small gold nanoparticles and a basic support
2012
Noujima, Akifumi | Mitsudome, Takato | Mizugaki, Tomoo | Jitsukawa, Koichiro | Kaneda, Kiyotomi
Gold nanoparticles on hydrotalcite act as a heterogeneous catalyst for the chemoselective hydrogenolysis of various allylic carbonates to the corresponding terminal alkenes using H₂ as a clean reductant. The combination of gold nanoparticles and basic supports elicited significantly unique and selective catalysis in the hydrogenolysis.
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