Copper-catalyzed oxidative C(sp³)–H/N–H coupling of sulfoximines and amides with simple alkanes via a radical process
2015
Teng, Fan | Sun, Song | Jiang, Yan | Yu, Jin-Tao | Cheng, Jiang
A copper-catalyzed oxidative C(sp³)–H/N–H coupling of sulfoximines with simple alkanes was developed. This protocol involved C(sp³)–N bond formation via a radical pathway and tolerated a series of functional groups, such as chloro, methyl and aryl, on the phenyl rings. Apart from sulfoximines, amides, saccharin and aniline also worked well to give the corresponding N-alkylated products.
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