Silver-catalyzed efficient synthesis of enaminones from propargyl alcohols and amines
2017
Li, Mengshun | Fang, Dongmei | Geng, Feng | Dai, Xianping
Enaminones are used as the key intermediates to construct heterocyclic compounds with various bioactivities. In this study, a simple and efficient approach for the synthesis of enaminones via amination of propargyl alcohols was developed. Under the catalysis of Ag2CO3, the reaction proceeded smoothly to afford the desired products in good yields. Preliminary mechanism experiments showed that Ag2CO3 played an essential role in the procedure of the reaction.
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