Desymmetrization of cyclic olefins via asymmetric Heck reaction and hydroarylation
2013
Liu, Sijia | Zhou, Jianrong (Steve)
An asymmetric Heck reaction allows desymmetrization of substituted cyclic olefins in high dr and ee. A bisphosphine oxide is uniquely stereoselective for this purpose. Desymmetrization of bicyclic olefins via hydroarylation can also be realized in high ee.
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Bibliographic information
Chemical communications
Volume
49
Issue
100
Pagination
11758
- 11760
ISSN
1364-548X
Publisher
The Royal Society of Chemistry
Other Subjects
Stereoselectivity; Alkenes
Language
English
Type
Journal Article; Text
2024-02-27
MODS
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