Synthesis of 2-aryl-2H-tetrazoles via a regioselective [3+2] cycloaddition reaction
2016
Patouret, Remi | Kamenecka, Theodore M.
A regioselective cycloaddition reaction of arenediazonium salts with trimethylsilyldiazomethane is reported. A series of 2-aryltetrazoles were obtained in good to moderate yields with wide functional group compatibility. Furthermore, this cycloaddition reaction opens the way to build up the versatile intermediate 2-aryl-5-bromotetrazole.
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