Intermolecular Aminotrifluoromethylation of Alkenes by Visible-Light-Driven Photoredox Catalysis
2013
Yasu, Yusuke | Koike, Takashi | Akita, Munetaka
Intermolecular aminotrifluoromethylation of alkenes catalyzed by [Ru(bpy)₃]²⁺ under visible light irradiation has been explored. The present photocatalytic protocol achieves highly efficient and regioselective difunctionalization of C═C bonds, leading to a variety of β-trifluoromethylamines. The reaction is applied to “late-stage aminotrifluoromethylation” of steroid and amino acid scaffolds.
Show more [+] Less [-]AGROVOC Keywords
Bibliographic information
This bibliographic record has been provided by National Agricultural Library