A highly efficient titanium-based olefin polymerisation catalyst with a monoanionic iminoimidazolidide π-donor ancillary ligand
2002
Kretschmer, Winfried P. | Dijkhuis, Chris | Meetsma, Auke | Hessen, Bart | Teuben, Jan H.
The titanium complex Cp[1,3-(2′,6′-Me₂C₆H₃)₂(CH₂N)₂CN]Ti(CH₂Ph)₂, with a monoanionic η¹-iminoimidazolidide ancillary ligand, is shown to be a highly efficient catalyst for olefin polymerisation when activated with the Lewis acid B(C₆F₅)₃.
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