Multi-Step Rearrangement Mechanism for Acetyl Cedrene to the Hydrocarbon Follower†
2017
Paknikar, S. K. | Kamounah, F. S. | Hansen, P. E. | Wadia, M. S.
Conversion of acetyl cedrene (2) to its follower (3) using acetic anhydride and polyphosphoric acid involves a multi-step cationic molecular rearrangement, which is consistent with deuteriation and 1-¹³C labeling studies of acetyl cedrene. The key step involves cyclopropylcarbinyl cation-cyclopropylcarbinyl cation rearrangement.
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