Heterometallic Al₆Zn₁₂ nano-plate with π-conjugated ligand: synthesis and nonlinear absorption properties
2021
Wang, San-Tai | Liu, Chen-Hui | Zheng, Chan | Li, De-Jing | Fang, Wei-Hui | Zhang, Jian
Presented herein is the synthesis, structure, and optical properties of the aluminum(iii)–zinc(ii) heterometallic compound AlOC-57. This compound was found to form a large unit cell (approximately sixteen thousand atoms) and a three-shell nano-plate structure. Based on the Z-scan patterns, the third-order nonlinear optical response of the heterometallic nano-plate was mainly attributed to its nonlinear absorption (reverse saturable absorption).
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