Novel and facile synthesis of 1-benzazepines via copper-catalyzed oxidative C(sp³)–H/C(sp²)–H cross-coupling
2017
Wang, Rui | Jin, Ruo-Xing | Qin, Zi-Yang | Bian, Kang-Jie | Wang, Xi-Sheng
A novel and facile synthetic strategy for the construction of 1-benzazepines has been developed via copper-catalyzed oxidative C(sp³)–H/C(sp²)–H cross-coupling directly from two inert C–H bonds. This transformation represents an atom- and step-economical way to synthesize biologically important seven-membered benzo-heterocycles compared with the known methods.
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