Scalable synthesis of enaminones utilizing Gold's reagents
2017
Schuppe, Alexander W. | Cabrera, James M. | McGeoch, Catherine L.B. | Newhouse, Timothy R.
Several Gold's reagents were synthesized from cyanuric chloride and N,N-dialkylformamides. These synthetic equivalents of N,N-dimethylformamide-dimethyl acetal were used in an optimized and scalable procedure for the regioselective synthesis of a variety of enaminones from ketone starting materials, whose utility was demonstrated by the stereoselective synthesis of Rawal-type dienes.
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