Activation of dihydrogen by 1,4,2,5-diazadiborinine
2018
Wang, Baolin | Kinjo, Rei
Activation of dihydrogen (H2) by 1,4,2,5-diazadiborinine is reported. Under the heating condition, treatment of 1,4,2,5-diazadiborinine with H2 results in the cleavage of HH bond, to afford product 2, which was fully characterized by NMR and IR spectroscopy as well as X-ray diffraction and HRMS analysis. In the presence of borane dimethylsulfide complex (BH3·SMe2), 2 readily isomerizes to 3 under the mild reaction condition.
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