A stable alkyl hydride of a first row transition metal
2003
MacAdams, Leonard A. | Buffone, Gerald P. | Incarvito, Christopher D. | Golen, James A. | Rheingold, Arnold L. | Theopold, Klaus H.
Hydrogenolysis of a Cr(iii) dialkyl precursor produced a binuclear chromium complex with a bridging hydride and a bridging alkyl; this structurally characterized organometallic compound is thermally very stable and does not undergo the expected reductive elimination of alkane.
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