Salen-Co(iii) insertion in multivariate cationic metal–organic frameworks for the enhanced cycloaddition reaction of carbon dioxide
2019
Liu, Tao Tao | Liang, Jun | Xu, Rui | Huang, Yuan-Biao | Cao, Rong
The salen-Co(iii) motif was inserted into imidazolium-functionalized multivariate cationic zirconium metal–organic frameworks (MOFs). The salen-Co(iii), as a Lewis acid site, and the Br⁻ of imidazolium, as a nucleophile, are synergistically catalytic for the enhanced cycloaddition reaction of carbon dioxide with epoxides.
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