Synthesis of α,β-Disubstituted Acrylates via Galat Reaction
2019
Xavier, Tania | Condon, Sylvie | Pichon, Christophe | Le Gall, Erwan | Presset, Marc
Galat reactions between aldehydes and substituted malonic acids half oxyester were found to be efficiently catalyzed by morpholine in refluxing toluene. This transformation allows the stereoselective synthesis of diverse α,β-disubstituted acrylates in moderate to good yields. This method constitutes an attractive alternative to existing methods in terms of scope and eco-compatibility.
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