Stereoselective Synthesis of Fluoro-homoneplanocin A as a Potential Antiviral Agent
2012
Chandra, Girish | Majik, Mahesh S. | Lee, Ji Yee | Jeong, Lak Shin
Fluoro-homoneplanocin A (4) was synthesized from d-ribose, via the enyne ring-closing metathesis of 9, the stereoselective opening of epoxide 23a with fluoride, and a simultaneous oxidation–elimination reaction. The key intermediate 8 is expected to serve as a versatile intermediate for the synthesis of carbanucleosides.
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