Nitration of deactivated aromatic compounds via mechanochemical reaction
2021
Wu, Jian-Wei | Zhang, Pu | Guo, Zhi-Xin
A variety of deactivated arenes were nitrated to their corresponding nitro derivatives in excellent yields under high-speed ball milling condition using Fe(NO₃)₃·9H₂O/P₂O₅ as nitrating reagent. A radical involved mechanism was proposed for this facial, eco-friendly, safe, and effective nitration reaction.
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