On/off regulation of catalysis by allosteric control of metal complex nuclearity
2004
Kovbasyuk, Larisa | Pritzkow, Hans | Krämer, Roland | Fritsky, Igor O.
The nature of the allosteric metal ion M (Pd²⁺ or Pt²⁺) in complexes ML of a polytopic ligand controls uptake of additional Cu²⁺ ions; while [Cu₂Pd(L-4H)]²⁺ is a highly active catalyst for phosphodiester cleavage, [CuPt(L-4H)] is inactive.
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Bibliographic information
Chemical communications
Issue
7
Pagination
880
- 881
ISSN
1364-548X
Publisher
The Royal Society of Chemistry
Language
English
Type
Text; Journal Article
2024-02-28
MODS
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